CAS: 638-53-9; Tridecanoic Acid

该化合物是一种直链饱和脂肪酸,配有化学公式C13H26O2.其特点是长的疏水碳氢化合物尾料,由13个碳原子组成,以及一个碳酸碳本体功能组(COOH),这一结构既具有疏水特性,又具有水利特性,又具有水利特性,形成三十二硝酸亚虫本体.它一般是一种白色的,在室内温度下是蜡状的固体,与较短链脂肪酸相比熔点相对较高.三十二硝酸存在于各种天然脂肪和油中,特别是一些动物脂肪和植物油中.它被用于生产表面活性剂,润滑剂和食品工业中的一种调味剂.此外,它还被用于合成酯和其他化学衍生物.由于其长的碳链,三十二硝酸在水中溶解,但在有机溶剂中溶解,这是脂肪酸的一个常见特征.

结构式图片

相似化合物

112-70-9 1731-88-0 28267-29-0

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

CAS号51323-71-8 Methanesulfonic... | CAS号201230-82-2 carbon monoxide | CAS号124-22-1 十二胺 | CAS号57393-50-7 1-diazo-2-tride... | CAS号10486-19-8 十三醛 | CAS号1120-36-1 1-十四烯 | CAS号10544-72-6 四氧化二氮 | CAS号2067-33-6 5-溴戊酸 | CAS号38841-98-4 辛基氯化镁 | CAS号112-41-4 1-十二烯 | CAS号6064-90-0 二十一烷酸甲酯 | CAS号142674-35-9 3-tridecanoylox... | CAS号4202-38-4 十二烷基异氰酸酯 | CAS号1731-88-0 十三烷酸甲酯 | CAS号26536-12-9 十三烷酸甘油三酯 | CAS号2345-27-9 2-十四酮 | CAS号629-50-5 正十三烷 | CAS号6005-99-8 苯正十三烷基酮 | CAS号10486-19-8 十三醛 | CAS号123-01-3 正十二烷基苯

合成工艺路线路线简述

    1-十四烯置于potassium Permanganate,硫酸,溶剂黄146体系中,用 二氯甲烷,水 作为反应溶剂,化学反应 21.0H,以83%的收率获得产物十三酸
    参考文献:Carboxylic Acids From The Oxidation Of Terminal Alkenes By Permanganate: Nonadecanoic Acid
    标题:Carboxylic Acids From The Oxidation Of Terminal Alkenes By Permanganate: Nonadecanoic Acid
    摘要:
    DOI:10.15227/orgsyn.060.0011

    海关参考信息

    专利信息


    专利号:US-3872168-A
    优先权日:1972-10-02
    标题:Synthesis of acids and amides
    发明人:COLLMAN JAMES P; WINTER STANLEY R; KOMOTO ROBERT G
    权利人:TRUSTEES OF THE LELAND STAMFOR
    摘要:Synthesis of acids R1COOH and amides R1CONR2R3 wherein R1 is attached to the carbonyl group by an aliphatic carbon atom and R2 and R3 are hydrogen or organic groups of a primary or secondary amine, by forming an alkyl or acyl intermediate (R1Fe(CO) 4 or R1COFe(CO) 4) and treating the intermediate with a suitable cleaving agent and, in the case of amides, also with ammonia or an amine.

    专利号:US-9643915-B2
    优先权日:2013-03-15
    标题:Methods for the synthesis of sphingomyelins and dihydrosphingomyelins
    发明人:ONICIU DANIELA CARMEN; HECKHOFF STEFAN; OSWALD BENOIT; REBMANN PETER; PEER ANDREAS; GONZALEZ MIGUEL; SAUTER PATRIK
    权利人:CERENIS THERAPEUTICS HOLDING SA
    摘要:The present invention includes methods for the synthesis of sphingomyelins and dihydrosphingomyelins. The present invention also includes methods for the synthesis of sphingosines and dihydrosphingosines. The present invention further includes methods for the synthesis of ceramides and dihydroceramides.

    专利号:US-9708354-B2
    优先权日:2013-03-15
    标 题:Methods for the synthesis of sphingomyelins and dihydrosphingomyelins
    发明人:ONICIU DANIELA CARMEN; HECKHOFF STEFAN; OSWALD BENOIT; REBMANN PETER; PEER ANDREAS; GONZALEZ MIGUEL; SAUTER PATRIK
    权利人:CERENIS THERAPEUTICS HOLDING SA
    摘要:The present invention includes methods for the synthesis of sphingomyelins and dihydrosphingomyelins. The present invention also includes methods for the synthesis of sphingosines and dihydrosphingosines. The present invention further includes methods for the synthesis of ceramides and dihydroceramides.

    专利号:US-5723619-A
    优先权日:1997-01-13
    标 题 :Method for the synthesis of deoxypyridinoline
    发明人:HATCH ROBERT P
    权利人:BAYER AG
    摘要:Disclosed is a method for the chemical synthesis of deoxypyridinoline (DPD). The synthesis involves the preparation of a protected 3-hydroxypyridinium starting with a Nα-protected lysine and a 5,6-epoxy-2-N-protected-O-protected-(2S)-2-aminohexanoate with subsequent deprotection to provide the desired DPD.

    专利号:US-9957355-B2
    优先权日:2013-06-12
    标 题 :Device and method for synthesis of a polymer under separation of a gaseous substance
    发明人:ZHU NING; STAMMER ACHIM; CLAUSS JOACHIM; KORY GAD
    权利人:BASF SE
    摘要:The invention relates to a device for synthesis of a polymer under separation of a gaseous substance. Said device comprises a reaction chamber ( 1 ), which has a top section ( 11 ), a middle section ( 12 ) and a bottom section ( 13 ), an inlet opening ( 2 ) which is arranged in the middle section ( 12 ), a first outlet opening ( 3 ) which is arranged in the bottom section ( 13 ), a second outlet opening ( 4 ) which is arranged in the top section ( 11 ), a first return opening ( 51 ), which is arranged in the bottom section ( 13 ), a second outlet opening ( 52 ), which is arranged under the top section ( 11 ), a distribution device ( 6 ), which is arranged between the top section ( 11 ) and the middle section ( 12 ), and a removal device ( 7 ) which is arranged to be movable along the top section ( 11 ). The invention further relates to a method for synthesis of a polymer which can be carried out in said device.

    专利号:US-7767425-B2
    优先权日:2001-11-16
    标 题:Enzymatic synthesis of sugar acrylates
    发明人:BOECKH DIETER; HAUER BERNHARD; HAERING DIETMAR
    权利人:BASF AG
    摘要:A process is described for the enzymatic synthesis of sugar acrylates, and a process is described for preparing polymeric sugar acrylates, the polymers obtainable by this process and their use for preparing, for example, cosmetics, drugs, laundry detergents, thickeners, protecting colloids, superabsorbents and textile sizes.
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    主要参考文献

    [参考文献]: Jin X, Et, Al. Undecanoic Acid, Lauric Acid, And N-Tridecanoic Acid Inhibit Escherichia Coli Persistence And Biofilm Formation. J Microbiol Biotechnol. 2020 Oct 13.
    [参考文献]: Bashar Amer, Et Al. Direct Derivatization Vs Aqueous Extraction Methods Of Fecal Free Fatty Acids For Gc-Ms Analysis. Lipids. 2015 Jul;50(7):681-9.
    [参考文献]: Jacqueline C Lieblein-Boff, Et Al. Exploratory Metabolomic Analyses Reveal Compounds Correlated With Lutein Concentration In Frontal Cortex, Hippocampus, And Occipital Cortex Of Human Infant Brain. Plos One. 2015 Aug 28;10(8):E0136904.
    [参考文献]: Janclei P Coutinho, Et Al. Use Of Multivariate Statistical Techniques To Optimize The Separation Of 17 Capsinoids By Ultra Performance Liquid Chromatography Using Different Columns. Talanta. 2015 Mar:134:256-263.
    [参考文献]: Jonathan Y Bernard, Et Al. The Association Between Linoleic Acid Levels In Colostrum And Child Cognition At 2 And 3 Y In The Eden Cohort. Pediatr Res. 2015 Jun;77(6):829-35.

    合成参考文献


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    摘要:Rawat, V. K.; Mita, T., Science of Synthesis: Knowledge Updates, (2024) 3, 294.
    参考文献:10.1002/(sici)1099-1573(199906)13:4<329::aid-ptr458>3.0.co;2-u|10.1002/(sici)1099-1573(199906)13:4<329::aid-ptr458>3.3.co;2-l
    摘要:Hashem FA, Saleh MM. Antimicrobial components of some cruciferae plants (Diplotaxis harra Forsk. and Erucaria microcarpa Boiss.). Phytother Res. 1999 Jun;13(4):329–32. doi: 10.1002/(sici)1099-1573(199906)13:4<329::aid-ptr458>3.0.co;2-u.
    参考文献:10.1007/s00253-011-3331-2
    摘要:Haddouche R, Poirier Y, Delessert S, Sabirova J, Pagot Y, Neuvéglise C, Nicaud JM. Engineering polyhydroxyalkanoate content and monomer composition in the oleaginous yeast Yarrowia lipolytica by modifying the ß-oxidation multifunctional protein. Appl Microbiol Biotechnol. 2011 Sep;91(5):1327–40. doi: 10.1007/s00253-011-3331-2.
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