685-73-4 + 58-86-6 + 50-99-7 + 3458-28-4 + 6556-12-3 + 9034-32-6 + 57-48-7 + 59-23-4 + 3615-41-6 = 67-47-0 + 78-98-8 + 96-26-4 + 144-62-7 + 50-21-5 + 123-76-2 反应条件:1.1C:H2So4,S:H2O,1 H,100°C 标题:Catalytic Transformation Of Biomass-Derived Hemicellulose Sugars By The One-Pot Method Into Oxalic,Lactic,And Levulinic Acids Using A Homogeneous H2So4 Catalyst 作者:By Sobus,Natalia And Czekaj,Izabela 参考文献:Catalysts 日期:2023 卷标:13(2) 页码:349]
58-86-6 + 50-99-7 + 9034-32-6 = 67-47-0 + 144-62-7 + 110-15-6 反应条件:1.1R:H2So4,24 H,Rt 标题:Organic Acid Pretreatment Of Oil Palm Trunk Biomass For Succinic Acid Production 作者:By Bukhari,Nurul Adela Et Al 参考文献:Waste And Biomass Valorization 日期:2020 卷标:11(10) 页码:5549-5559]
9004-34-6 = 67-47-0 + 498-07-7 + 78797-67-8 + 141-46-8 + 50-99-7 反应条件:1.1 5 Mbar,370 °C -> 765 °C 标题:The Interplay Between Chemistry And Heat/mass Transfer During The Fast Pyrolysis Of Cellulose 作者:Westerhof,R. J. M.; Oudenhoven,S. R. G.; Marathe,P. S.; Engelen,M.; Garcia-Perez,M.; Et Al 参考文献:Reaction Chemistry & Engineering 日期:2016 卷标:1(5) 页码:555-566
1,6-脱水-β-D-葡萄糖置于sulfo Modified Mil-101Cr体系中,用 四氢呋喃,水 作为反应溶剂,化学反应 24.0H,以28%的收率获得产物5-羟甲基糠醛 参考文献:Selective Glucose Conversion To 5-Hydroxymethylfurfural (5-Hmf) Instead Of Levulinic Acid With Mil-101Cr Mof-Derivatives 标题:Selective Glucose Conversion To 5-Hydroxymethylfurfural (5-Hmf) Instead Of Levulinic Acid With Mil-101Cr Mof-Derivatives 摘要:Mofs在催化生物质转化方面也取得了进展,在低沸点溶剂中通过葡萄糖生产5-Hmf时产量增加. DOI:10.1039/c6Nj01399F
专利号:US-11008298-B2 优先权日:2019-05-24 标 题:Synthesis of 5-hydroxymethylfurfural 发明人:MOSIER NATHAN SCOTT; OVERTON JONATHAN CHRISTOPHER 权利人:PURDUE RESEARCH FOUNDATION 摘要:The present disclosure relates to a novel and improved synthesis of 5-hydroxymethylfurfural (HMF) from a glucose source. The synthesis of 5-hydroxymethylfurfural (HMF) is carried out by reacting a mixture comprising a Brønsted acid, a Lewis acid, water, dimethyl sulfoxide (DMSO), acetonitrile, and a glucose source.
专利号:US-10662452-B2 优先权日:2016-09-05 标 题 :Strain of meyerozyma guilliermondii and its use in methods of catalytic synthesis of 2,5-dihydroxymethylfuran 发明人:LI NING; LI YANMEI; ZONG MINHUA 权利人:UNIV SOUTH CHINA TECH 摘要:A yeast strain and a method for the synthesis of 2,5-dihydroxymethylfuran using this strain are disclosed. The yeast strain is Meyerozyma guilliermondii SC 1103, which has been maintained in the China Center for Type Culture Collection (CCTCC, Wuhan, P.R. China) with an access No. of M2016144. The method for the synthesis of 2,5-dihydroxymethylfuran using this strain is described as follows: after pre-cultivation and cultivation, Meyerozyma guilliermondii SC 1103 cells are added into the buffer solutions containing 5-hydroxymethylfurfural and glucose; the biocatalytic reaction is conducted under designated conditions, thus affording 2,5-dihydroxymethylfuran. This disclosure has many advantages such as good selectivity, mild reaction conditions, environmental friendliness, high efficiency, and good yield.
专利号:US-2025059149-A1 优先权日:2023-07-05 标题 :Microreactor and method for continuous flow synthesis of 2,5-furandicarboxylic acid 发明人:YU CHAO; HE JIALUN; CHEN XIAO; LI YINGGUO; JIANG DANFENG 权利人:UNIV JIANGSU SCIENCE & TECH 摘要:Disclosed is a microreactor for continuous flow synthesis of 2,5-furandicarboxylic acid, the microreactor includes a first container, a collection device, an injection pump, a first flow pump, a second flow pump, a first microreactor substrate, ion exchange resin adsorption pipes, activated carbon adsorption pipes, a second microreactor substrate, an oxygen source, a first T-connector, a second T-connector, and a third T-connector; where the first container is connected to the first T-connector via the first flow pump, the injection pump is connected to the first T-connector, the third T-connector is connected to the first T-connector and the first microreactor substrate, respectively, the first microreactor substrate is connected to the ion exchange resin adsorption pipes, the activated carbon adsorption pipes, the second T-connector, and the second microreactor substrate in sequence, and the oxygen source is connected to the second T-connector. Further disclosed is a method for continuous flow synthesis of 2,5-furandicarboxylic acid.
专利号:US-2024368099-A1 优先权日:2022-01-18 标 题:Methods for the synthesis of di(hydroxymethyl)tetrahydrofuran and its application in polyesters and polyurethanes 发明人:SPIEGELBERG BRIAN; BRANDT ADRIAN; BECK HORST; KUX ALEXANDER; TIN SERGEY; DE VRIES JOHANNES GERARDUS 权利人:HENKEL AG & CO KGAA 摘要:The present invention relates to the synthesis of di(hydroxymethyl)tetrahydrofuran (DHMTHF) and the preparation of trans-enriched mixtures of DHMTHF. The invention further refers to polyester polyols which are obtained by reaction of cis/trans DHMTHF mixtures with a dicarboxylic acid. The invention further relates to polyurethanes and compositions containing a polyester polyol comprising DHMTHF, in particular to such polyurethane-containing (adhesive) compositions.
专利号:US-10266565-B2 优先权日:2011-04-12 标 题 :Peptide mimetic ligands of polo-like kinase 1 polo box domain and methods of use 发明人:BURKE JR TERRENCE R; LIU FA; LEE KYUNG S; PARK JUNG-EUN 权利人:BURKE JR TERRENCE R; LIU FA; LEE KYUNG S; PARK JUNG EUN; THE US SECRETARY DEPARTMENT OF HEALTH & HUMAN SERVICES 摘要:Novel compounds are provided that bind to polo-like kinases through the polo-box domain. In certain embodiments, the novel compounds are PEGylated peptides. The PEGylated peptides in accordance with the invention demonstrate high PBD-binding affinity. In certain embodiments, the PEGylated peptides have also achieved activities in whole cell systems. The invention also provides compounds that bind polo-like kinases through the polo-box domain and possess reduced anionic charge. Further provided are methods of design and/or synthesis of the PEGylated peptides and methods of use thereof. The invention provides methods of use of the compounds and methods of synthesis of the compounds.
专利号:US-9359318-B2 优先权日:2010-08-06 标 题:Process for the synthesis of 2,5-furandicarboxylic acid 发明人:BORSOTTI GIAMPIETRO; DIGIOIA FRANCESCA 权利人:BORSOTTI GIAMPIETRO; DIGIOIA FRANCESCA; NOVAMONT SPA 摘要:Process for the synthesis of 2,5-furandicarboxylic acid through the oxidation of -hydroxymethylfurfural in a flow of oxygenor a compound containing oxygen, catalyzed by a supported catalyst containing a metal of the platinum group, carried out in aqueous solution in which the pH is maintained higher than 7 and lower than 12 through the addition of a weak base.
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