磷酸,碳酸氢铵 以 水 作为反应溶剂,化学反应生成 磷酸二氢铵 参考文献:Slow And Controlled-Release Polymeric Fertilizer With Multiple Nutrients,Preparing Process For The Same And The Use Method Of The Same 标题:Slow And Controlled-Release Polymeric Fertilizer With Multiple Nutrients,Preparing Process For The Same And The Use Method Of The Same 摘要:这项发明涉及一种具有多种营养元素的缓释聚合物肥料,其通用公式如下:其中n,M和m在描述中有定义.本发明的聚合物肥料是一种环境友好的缓释肥料.其缓慢和可控释放作用在于自降解和水解.该发明还涉及肥料的制备过程以及在农业中的使用方法.
专利信息
专利号:US-2008112874-A1 优先权日:2006-08-31 标 题:Method for producing calcium phosphate powders using an auto-ignition combustion synthesis reaction 发明人:BURKES DOUGLAS E; MOORE JOHN J; AYERS REED A 权利人:BURKES DOUGLAS E; MOORE JOHN J; AYERS REED A 摘要:A method for making high purity, multiphasic calcium phosphate powders using an Auto-Ignition Combustion Synthesis (AICS) reaction of a calcium salt, a phosphate salt and a fuel is provided. In the method provided, energy released from the AICS reaction between the calcium salt, phosphate salt and fuel ignites at temperatures much lower than the actual phase transformation temperatures and reaches a high temperature rapidly enough for synthesis of the desired product to occur, without the requirement for coprecipitation, an external heat source for calcination and/or additional steps for removing undesired precursors from the desired final product.
专利号:US-12017206-B2 优先权日:2021-09-30 标 题 :Preparation method of Cu—Pd—CeO2/γ—Al2O3@NP catalyst and synthesis method of benzopyrazine compounds 发明人:FENG FENG; LI XIAONIAN; GUO LINGLING; SUN YANXIA; LU CHUNSHAN; ZHANG QUNFENG; Jin Jiatong; XU XIAOLIANG 权利人:UNIV ZHEJIANG TECHNOLOGY 摘要:A preparation method of Cu—Pd—CeO 2 /γ-Al 2 O 3 @NP catalyst and a synthesis method of benzopyrazine compounds. The preparation method of the Cu—Pd—CeO 2 /γ-Al 2 O 3 @NP catalyst comprises the following steps: (1) preparing a CeO 2 /γ-Al 2 O 3 carrier; (2) preparing a CeO 2 /γ-Al 2 O 3 @NP carrier; (3) preparing the Cu—Pd—CeO 2 /γ-Al 2 O 3 @NP catalyst by impregnation method. A one-pot method for synthesizing benzopyrazine compounds of formula (III) includes using an o-nitroaniline compound of formula (I) and an aliphatic diol compound of formula (II) as raw materials, carrying out the one-pot synthesis of the benzopyrazine compound of formula (III) under solvent-free condition and under the combined action of the Cu—Pd—CeO 2 /γ-Al 2 O 3 @NP catalyst prepared by the method and an alkali. The Cu—Pd—CeO 2 /γ-Al 2 O 3 @NP catalyst increases the number of basic sites by doping N and P, and meanwhile loads CeO 2 to assist in the extraction of protons, thereby improving the dehydrogenation activity and product selectivity.
专利号:US-9174846-B2 优先权日:2009-09-18 标题 :Ferric phosphate and methods of preparation thereof 发明人:BECK LARRY W; SOLTANI MAHROKH; WANG LIYA 权利人:BECK LARRY W; SOLTANI MAHROKH; WANG LIYA; A123 SYSTEMS LLC 摘要:High-purity crystalline ferric phosphate material with desirable characteristics for use in synthesis of nano-sized LFP cathode material are described. The ferric phosphate dihydrate material has as disclosed herein has a molar ratio of phosphorous to iron is from about 1.001 to about 1.05, a surface area of from about 25 m 2 /g to about 65 m 2 /g, and is substantially free of metallic or magnetic impurities. Methods of synthesizing high-purity crystalline ferric phosphate material with desirable characteristics for use in synthesis of nano-sized LFP cathode material are also described. In some embodiments, one or more magnetic traps are used during the reaction process and/or after the formation of the final product to remove magnetic impurities. In some embodiments, a synthetic method of ferric phosphate using multiple steps is described, wherein the intermediate of the synthesis is isolated and purified to improve the purity of the ferric phosphate material. In some embodiments, an iron compound is added to an aqueous solution of phosphoric acid. The solution pH and temperature are controlled to ensure the complete dissolution of the iron compound. The desired iron phosphate crystalline material can be obtained with high purity and high crystalline phase purity by controlling the pH and temperature of the solution.
专利号:US-2017349928-A1 优先权日:2014-12-31 标 题:Methods for activating natural energy metabolism for improving yeast cell-free protein synthesis 发明人:JEWETT MICHAEL CHRISTOPHER; ANDERSON MARK J; STARK JESSICA CAROL; HODGMAN CHARLES ERIC 权利人:UNIV NORTHWESTERN 摘要:Disclosed are compositions, methods, and kits for enhanced synthesis of a biological macromolecule in vitro using cell-free protein synthesis. The compositions, methods, and kits include or utilize: a cell-free extract; a phosphate-free energy source; and a phosphate source, and typically do not include an exogenous nucleoside triphosphate or an exogenous nucleoside diphosphate.
专利号:US-9401507-B2 优先权日:2012-08-07 标题:Methods for the colloidal synthesis of lithium iron phosphate 发明人:PAOLELLA ANDREA; CHANDRAMOHAN GEORGE; PRATO MIRKO; POVIA MAURO; GENOVESE ALESSANDRO; MANNA LIBERATO; CINGOLANI ROBERTO 权利人:FOND ST ITALIANO TECNOLOGIA 摘要:Methods for producing lithium iron phosphate or lithium manganese phosphate or lithium iron manganese phosphate, by colloidal synthesis are provided. Such methods include the operation of reacting a lithium salt, an iron(II) halide (and/or a manganese(II) halide) and a phosphorus compound, which, under the reaction conditions, is capable of releasing the phosphate ion, in the presence of an organic surfactant or a mixture of organic surfactants including an alkylamine or alkenylamine, in which the surfactant or mixture of surfactants is capable of dissolving the lithium salt and the iron halide (and/or the manganese halide), where used, in an organic solvent, which is liquid at room temperature, in which the surfactant or mixture of surfactants is soluble, the reaction being performed at a temperature not lower than 250° C.
专利号:US-8586241-B2 优先权日:2008-08-26 标 题:Synthesis of LIFEPO4 under hydrothermal conditions 发明人:BRAMNIK KIRILL; HIBST HARTMUT; LAMPERT JORDAN KEITH 权利人:BRAMNIK KIRILL; HIBST HARTMUT; LAMPERT JORDAN KEITH; BASF SE 摘要:The present invention relates to a process for the preparation of compounds of general Formula (I) L a-b M 1 b Fe 1-c M 2 c P d-e M 3 e O x (I), wherein Fe has the oxidation state +2 and M 1 , M 2 , M 3 , a, b, c, d, e and x are: M 1 : Na, K, Rb and/or Cs, M 2 : Mn, Mg, Al, Ca, Ti, Co, Ni, Cr, V, M 3 : Si, S, F a: 0.8-1.9, b: 0-0.3, c: 0-0.9, 15 d: 0.8-1.9, e: 0-0.5, x: 1.0-8, depending on the amount and oxidation state of Li, M 1 , M 2 , P, M 3 , wherein compounds of general Formula (I) are neutrally charged, comprising the following steps (A) providing a mixture comprising at least one lithium-comprising compound, at least one iron-comprising compound, in which iron has the oxidation state +3, and at least one M 1 -comprising compound, if present, and/or at least one M 2 -comprising compound, if present, and/or least one M 3 -comprising compound, if present, and at least one reducing agent which is oxidized to at least one compound comprising at least one phosphorous atom in oxidation state +5, and (B) heating the mixture obtained in step (A) at a temperature of 100 to 500° C. and at an autogeneous pressure to reduce Fe to oxidation state +2 and to obtain a compound of general Formula (I).
参考标题:Direct Transformation Of Glycerol To Propanal Using Zirconium Phosphate‐supported Bimetallic Catalysts 作者:Honghui Gong,Chuan Zhou,Yan Cui,Sheng Dai,Xiuge Zhao,Ruihan Luo,Pengfei An,Huan Li,Haifeng Wang,Zhenshan Hou |发布日期:2020.9.18 摘要:Transformation Of Glycerol To Propanal (Pa) Provides A Feasible Route Towards The Sustainable Synthesis Of High Value‐added Chemicals. In This Work, Zirconium Phosphate (Zrp) Was Studied As Support And Ru And Co As Metal Sites For Glycerol Hydrogenolysis In A Continuous‐flow Reactor. It Was Found That Zrp‐supported Co−o Species Had A Moderate Selectivity To Pa (49.5 %) In Glycerol Hydrogenolysis. Notably
合成参考文献
参考文献:10.1007/s00101-010-1693-y 摘要:Kronabel DB. [Nitrous oxide production by the German Armed Forces in the 20th century : History of medicine and pharmacy in the Armed Forces]. Anaesthesist. 2010 Mar;59(3):248–9. doi: 10.1007/s00101-010-1693-y. 参考文献:10.3390/ijms12063821 摘要:Maity JP, Lin TJ, Cheng HP, Chen CY, Reddy AS, Atla SB, Chang YF, Chen HR, Chen CC. Synthesis of brushite particles in reverse microemulsions of the biosurfactant surfactin. Int J Mol Sci. 2011;12(6):3821–30. 参考文献:10.1186/1742-4690-8-60|10.1186/1742-4690-8-s2-p42 摘要:Kula A, Guerra J, Knezevich A, Kleva D, Myers MP, Marcello A. Characterization of the HIV-1 RNA associated proteome identifies Matrin 3 as a nuclear cofactor of Rev function. Retrovirology. 2011 Jul 20;8():60. 参考文献:10.1016/j.ijpharm.2011.07.005 摘要:Al-Kattan A, Girod-Fullana S, Charvillat C, Ternet-Fontebasso H, Dufour P, Dexpert-Ghys J, Santran V, Bordère J, Pipy B, Bernad J, Drouet C. Biomimetic nanocrystalline apatites: Emerging perspectives in cancer diagnosis and treatment. International Journal of Pharmaceutics. 2012 Feb;423(1):26–36. doi: 10.1016/j.ijpharm.2011.07.005. 参考文献:10.1007/s00253-005-0212-6 摘要:Zhong Z, Xu Z, Peng L, Huang L, Fang X, Cen P. Tandem repeat mhBD2 gene enhance the soluble fusion expression of hBD2 in Escherichia coli. Applied Microbiology and Biotechnology. 2005 Dec 02;71(5):661–7. doi: 10.1007/s00253-005-0212-6.