CAS: 827-54-3; 2-Vinylnaphthalene

• 英文名称2-Vinylnaphthalene
• 中文名称2-乙烯基萘
• IUPAC名称2-vinylnaphthalene
• 其它别名2-Ethenyinaphthalene; 2-Vinylnaphthalene; 2-Vinyl-Naphthalene; 2-Vinylnaphthalene, Optical Grade, ; Hzd8Li91N1; Beta-Vinylnaphthalene; Nap
• CAS编号827-54-3
• MFCD编号:MFCD00004125
• EINECS号:212-573-6
• 分子式:C12H10
• 分子量:154.21
• 产品CID: 1817598
• 产品分类有机原料→分子砌块→芳环类化合物→萘类化合物

• 相似结构搜索
• InChIKey: KXYAVSFOJVUIHT-UHFFFAOYSA-N
• InChI=1S/C12H10/c1-2-10-7-8-11-5-3-4-6-12(11)9-10/h2-9H,1H2…
• 计算化学: 氢键受体数0.0氢键供体数0.0可旋转键数1.0

相似化合物

物理性质

• 熔点64-68 °C
• 沸点270.9±7.0 °C at 760 mmHg
• 闪点115.528±8.89 °C
• 密度1.0±0.1 g/cm3
• PSA:0.0
• LogP:3.4828
• 折射率1.657
• 蒸汽压0.0±0.3 mmHg at 25°C
• 敏感性1. 常温常压下稳定，避免强氧化剂 热接触2. 存在于烟气中。
• 外观形态白色至淡米色结晶粉末
• 储存条件-20°C, sealed storage, away from moisture
• 产品应用该化合物用作合成各种共聚物,如聚苯乙烯磺酰胺-CO-2-乙烯-氯化萘,聚(2-乙烯-汞酸)-甲苯-聚苯酯.

MSDS等安全信息

• GHS符号GHS08
• 危险类别急性毒性 类别4(吸入)
  急性毒性 类别4(经皮)
  急性毒性 类别4(经口)
  特定目标器官毒性 - 单次接触 类别3
  皮肤腐蚀/刺激 类别2
  严重眼刺激 类别2
• 警示词Danger
• 危险描述H332 |吸入有害.
  H312 |皮肤接触有害.
  H302 |吞咽有害.
  H335 |可能引起呼吸道刺激.
  H315 |造成皮肤刺激.
  H319 |造成严重眼刺激.
  H371 |可能损害器官.
• 防范说明P260-P264-P270-P405-P501
• UN编号NONH for all modes of transport
• 危险品标志Xi:Irritant;
• 安全声明S26-S36
• 危险类别码R20/22,R36/38
• WGK Germany3

欧盟法规

上下游产品

合成工艺路线路线简述

• 合成目标产物 2-Vinylnaphthalene 主要起始原料 2-Ethynyl-Naphthalene
• 580-13-2 = 827-54-3
  反应条件:1.1 Reagents: Triethylamine Catalysts: Palladium Diacetate,Tri-O-Tolylphosphine Solvents: Acetonitrile; 50 Psi,Rt -> 60 °C; 16 H,60 °C
  标题:Model Guided Development Of A Simple Catalytic Method For The Synthesis Of Unsymmetrical Stilbenes By Sequential Heck Reactions Of Aryl Bromides With Ethylene
  作者:Barlow,Helen; Et Al
  参考文献:Advanced Synthesis & Catalysis 日期:2018 卷标:360(14) 页码:2678-2690]
  
  1779-49-3 + 66-99-9 = 827-54-3
  反应条件:1.1 Reagents: Sodium Hydride Solvents: Dimethylformamide; 0 °C; Overnight,Rt
  标题:Selective 5-Hydroxytryptamine 2C Receptor Agonists Derived From The Lead Compound Tranylcypromine: Identification Of Drugs With Antidepressant-Like Action
  作者:Cho,Sung Jin; Et Al
  参考文献:Journal Of Medicinal Chemistry 日期:2009 卷标:52(7) 页码:1885-1902]
  
  1779-49-3 + 66-99-9 = 827-54-3
  反应条件:1.1 Reagents: Potassium Carbonate Solvents: Tetrahydrofuran; 10 H,75 °C
  标题:Carboxylation Of Styrenes With Cbr4 And Dmso Via Cooperative Photoredox And Cobalt Catalysis
  作者:Song,Cai-Xia; Et Al
  参考文献:Rsc Advances 日期:2017 卷标:7(19) 页码:11233-11243]
  
  1779-49-3 + 66-99-9 = 827-54-3
  反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane; 23 °C; 15 Min,23 °C1.2 Solvents: Tetrahydrofuran; 2 H,23 °C1.3 Reagents: Ammonium Chloride Solvents: Water
  标题:The Synthesis Of α-Azidoesters And Geminal Triazides
  作者:Klahn,Philipp; Et Al
  参考文献:Angewandte Chemie 日期:2014 卷标:53(30) 页码:7913-7917]
  
  83813-73-4 = 827-54-3
  反应条件:1.1 Reagents: Tripotassium Phosphate Catalysts: [bis(Bicyclo[2.2.1]Hept-2-Yl)Phosphine]Chloro[2-[(Dimethylamino-Kn)Methyl]Ferroc... Solvents: 1,4-Dioxane,Water; 17 H,100 °C
  标题:Direct Vinylation And Difluorovinylation Of Arylboronic Acids Using Vinyl- And 2,2-Difluorovinyl Tosylates Via The Suzuki-Miyaura Cross Coupling
  作者:Goegsig,Thomas M.; Et Al
  参考文献:Journal Of Organic Chemistry 日期:2008 卷标:73(9) 页码:3404-3410]
  
  482649-91-2 + 66-99-9 = 827-54-3
  反应条件:1.1 Reagents: Butyllithium,Hexamethyldisilazane; 2 H,0 °C; 2 H,0 °C1.2 Reagents: Dibromobenzene; -78 °C; -78 °C -> Rt; Overnight,Rt1.3 Reagents: Hydrochloric Acid Solvents: Water
  标题:Pinacolboratamethylenetriphenylphosphonium Iodide,A New Methylene Transfer Reagent
  作者:Quntar,Abed Al-Aziz; Et Al
  参考文献:Synthetic Communications 日期:2002 卷标:32(16) 页码:2575-2579]
  
  3487-44-3 + 66-99-9 = 827-54-3
  反应条件:1.1 Solvents: Tetrahydrofuran; 24 H,Rt
  标题:The Rapid,Living,Anionic Polymerization Of 2-Vinylnaphthalene At Ambient Temperature: Characterization Of An N-Butyllithium/tetrahydrofuran System In 1,2,3,4-Tetrahydronaphthalene
  作者:Natori,Itaru; Et Al
  参考文献:Journal Of Applied Polymer Science 日期:2015 卷标:132(17) 页码:41901/1-41901/7]
  
  2949-26-0 = 827-54-3
  反应条件:1.1 Reagents: Zinc,Water Catalysts: Zinc Iodide Solvents: Dimethylformamide; 12 H,90 °C
  标题:Zinc Salt-Catalyzed Reduction Of α-Aryl Imino Esters,Diketones And Phenylacetylenes With Water As Hydrogen Source
  作者:Shen,Guoli; Et Al
  参考文献:Organic & Biomolecular Chemistry 日期:2021 卷标:19(16) 页码:3601-3610]
  
  2554-06-5 + 580-13-2 = 827-54-3
  反应条件:1.1 Reagents: Tetrabutylammonium Fluoride Catalysts: Palladium Diacetate,X-Phos Solvents: Tetrahydrofuran; 25 °C; 24 H,67 °C1.2 Solvents: Water; 25 °C
  标题:Pd-Catalyzed Vinylation Of Aryl Halides With Inexpensive Organosilicon Reagents Under Mild Conditions
  作者:Yang,Chu-Ting; Et Al
  参考文献:Chemistry - A European Journal 日期:2018 卷标:24(41) 页码:10324-10328]
  
  2554-06-5 + 580-13-2 = 827-54-3
  反应条件:1.1 Reagents: Tetrabutylammonium Fluoride Catalysts: Palladium Bromide,2-(Di-Tert-Butylphosphino)Biphenyl Solvents: Tetrahydrofuran; 3 H,50 °C
  标题:Vinylation With Inexpensive Silicon-Based Reagents: Preparation Of 3-Vinylquinoline And 4-Vinylbenzophenone
  作者:Denmark,Scott E.; Et Al
  参考文献:Organic Syntheses 日期:2009 卷标:86 页码:274-286]
  
  2554-06-5 + 580-13-2 = 827-54-3
  反应条件:1.1 Catalysts: Tetrabutylammonium Fluoride,Palladium Bromide,2-(Di-Tert-Butylphosphino)Biphenyl Solvents: Tetrahydrofuran; 3 H,50 °C
  标题:2,4,6,8-Tetraethenyl-2,4,6,8-Tetramethylcyclotetrasiloxane
  作者:Denmark,Scott E.; Et Al
  参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2007 卷标:1 页码:1-3]
  
  3112-85-4 + 1592-38-7 = 827-54-3
  反应条件:1.1 Reagents: Sodium Hydride; 23 H,135 °C
  标题:(E)-Specific Direct Julia-Olefination Of Aryl Alcohols Without Extra Reducing Agents Promoted By Bases
  作者:Yao,Chuan-Zhi; Et Al
  参考文献:Chemical Communications (Cambridge 日期:2015 卷标:51(36) 页码:7729-7732]
  
  3112-85-4 + 1592-38-7 = 827-54-3
  反应条件:1.1 Reagents: Potassium Hydroxide Catalysts: 2,9-Dimethyl-1,10-Phenanthroline,Nickel Bromide Solvents: 1,4-Dioxane; 24 H,140 °C
  标题:Base Metal-Catalyzed Direct Olefinations Of Alcohols With Sulfones
  作者:Waiba,Satyadeep; Et Al
  参考文献:Acs Omega 日期:2019 卷标:4(4) 页码:7082-7087]
  
  580-13-2 = 827-54-3
  反应条件:1.1 Reagents: Tetrabutylammonium Fluoride Catalysts: Palladium Diacetate,2-(Di-Tert-Butylphosphino)-2′-Methyl-1,1′-Biphenyl Solvents: Tetrahydrofuran; 24 H,25 °C1.2 Solvents: Water; 25 °C
  标题:Pd-Catalyzed Vinylation Of Aryl Halides With Inexpensive Organosilicon Reagents Under Mild Conditions
  作者:Yang,Chu-Ting; Et Al
  参考文献:Chemistry - A European Journal 日期:2018 卷标:24(41) 页码:10324-10328]
  
  = 827-54-3
  反应条件:1.1 Catalysts: Di-μ-Chlorobis[(1,2,5,6-η)-1,5-Cyclooctadiene]Dirhodium,1,1-Bis(Diphenylphosphino)Ferrocene Solvents: Chlorobenzene; 6 H,130 °C
  标题:Sulfur-Controlled And Rhodium-Catalyzed Formal (3 + 3) Transannulation Of Thioacyl Carbenes With Alk-2-Enals And Mechanistic Insights
  作者:Wu,Qiuyue; Et Al
  参考文献:Organic & Biomolecular Chemistry 日期:2021 卷标:19(14) 页码:3173-3180]
  
  2554-06-5 + 612-55-5 = 827-54-3
  反应条件:1.1 Reagents: Tetrabutylammonium Fluoride Catalysts: Palladium Diacetate,X-Phos Solvents: Tetrahydrofuran; 25 °C; 24 H,67 °C1.2 Solvents: Water; 25 °C
  标题:Pd-Catalyzed Vinylation Of Aryl Halides With Inexpensive Organosilicon Reagents Under Mild Conditions
  作者:Yang,Chu-Ting; Et Al
  参考文献:Chemistry - A European Journal 日期:2018 卷标:24(41) 页码:10324-10328]
  
  13170-43-9 + 4469-45-8 = 827-54-3
  反应条件:1.1 Reagents: Zinc Iodide Solvents: Benzene
  标题:Selective Deprotection Of Acetals With Me3Sich2Mgcl. Peterson-Type Olefination Of Acetals
  作者:Chiang,Chao-Cheng; Et Al
  参考文献:Journal Of Organic Chemistry 日期:2000 卷标:65(15) 页码:4694-4697]
  
  2065-66-9 + 66-99-9 = 827-54-3
  反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane; -78 °C; -78 °C -> Rt; 30 Min,Rt; Rt -> -78 °C1.2 Solvents: Tetrahydrofuran; -78 °C; -78 °C -> Rt; 2 H,Rt
  标题:Synthesis And Photoluminescent Properties Of Conjugated Aryl-Vinyl Dioctyl 2,6-Dimethylbenzofuro[5,6-B]Furan-3,7-Dicarboxylate Derivatives
  作者:Bosiak,Mariusz J.; Et Al
  参考文献:Dyes And Pigments 日期:2013 卷标:99(3) 页码:803-811]
  
  2065-66-9 + 66-99-9 = 827-54-3
  反应条件:1.1 Reagents: Potassium Carbonate Solvents: Dimethylacetamide; 15 Min,Rt1.2 3 H,70 °C
  标题:Synthesis And Photophysical Properties Of Aza[n]Helicenes
  作者:Upadhyay,Gourav M.; Et Al
  参考文献:Journal Of Organic Chemistry 日期:2016 卷标:81(17) 页码:7751-7759]
  
  580-13-2 = 827-54-3
  反应条件:1.1 Reagents: Potassium Acetate Catalysts: Phenothiazine,Stereoisomer Of Di-μ-Chlorobis[2-[1-(Hydroxyimino-Kn)Ethyl]Phenyl-Kc]Dipalladium Solvents: Dimethylacetamide; 24 H,30 Psi,105 °C
  标题:Low Pressure Vinylation Of Aryl And Vinyl Halides Via Heck-Mizoroki Reactions Using Ethylene
  作者:Smith,Craig R.; Et Al
  参考文献:Tetrahedron 日期:2010 卷标:66(5) 页码:1102-1110]
  
  13603-65-1 = 827-54-3
  反应条件:1.1 Reagents: Triphenylphosphine Catalysts: 2146105-72-6 Solvents: Chloroform; 4 H,90 °C
  标题:Deoxydehydration Of Vicinal Diols And Polyols Catalyzed By Pyridinium Perrhenate Salts
  作者:Morris,Danny S.; Et Al
  参考文献:Catalysis Science & Technology 日期:2017 卷标:7(23) 页码:5644-5649]
  
  156635-83-5 = 827-54-3
  反应条件:1.1 Reagents: Sodium Carbonate,Hantzsch Ester Solvents: Dimethyl Sulfoxide; 1.5 H,Rt
  标题:Hantzsch Ester As A Photosensitizer For The Visible-Light-Induced Debromination Of Vicinal Dibromo Compounds
  作者:Chen,Wenxin; Et Al
  参考文献:Chemistry - A European Journal 日期:2016 卷标:22(28) 页码:9546-9550]
  
  75927-49-0 + 580-13-2 = 827-54-3
  反应条件:1.1 Reagents: Water,Tripotassium Phosphate Catalysts: Palladium Diacetate,2-Dicyclohexylphosphino-2′,6′-Dimethoxybiphenyl Solvents: 1,4-Dioxane; 24 H,80 °C
  标题:Interrogating Pd(Ii) Anion Metathesis Using A Bifunctional Chemical Probe: A Transmetalation Switch
  作者:Molloy,John J.; Et Al
  参考文献:Journal Of The American Chemical Society 日期:2018 卷标:140(1) 页码:126-130]
  
  580-13-2 = 827-54-3
  反应条件:1.1 Reagents: Magnesium,Lithium Chloride Solvents: Tetrahydrofuran; 0 °C; 2 H,0 °C -> Rt; Rt -> 0 °C1.2 Catalysts: Iron Chloride (Fecl3) Solvents: Tetrahydrofuran; 3 H,0 °C1.3 Reagents: Ammonium Chloride Solvents: Water
  标题:Iron-Catalyzed Cross-Coupling Of Alkenyl Acetates
  作者:Gaertner,Dominik; Et Al
  参考文献:Angewandte Chemie 日期:2015 卷标:54(36) 页码:10545-10549]
  
  580-13-2 = 827-54-3
  反应条件:1.1 Reagents: Zinc,Lithium Iodide Catalysts: Dichloro[1,1′-(1,3-Propanediyl)Bis[1,1-Diphenylphosphine-Kp]]Nickel Solvents: Dimethyl Isosorbide; 8 H,65 °C1.2 Reagents: Ammonium Chloride Solvents: Water
  标题:Nickel-Catalyzed Reductive Cross-Coupling Of Aryl Bromides With Vinyl Acetate In Dimethyl Isosorbide As A Sustainable Solvent
  作者:Su,Mincong; Et Al
  参考文献:Organic Letters 日期:2022 卷标:24(1) 页码:354-358]
  
  1592-38-7 = 827-54-3
  反应条件:1.1 Reagents: Potassium Tert-Butoxide Catalysts: Platinum Solvents: Toluene; 15 H,Reflux
  标题:Direct Olefination Of Alcohols With Sulfones By Using Heterogeneous Platinum Catalysts
  作者:Siddiki,S. M. A. Hakim; Et Al
  参考文献:Chemistry - A European Journal 日期:2016 卷标:22(17) 页码:6111-6119]
  
  1592-38-7 = 827-54-3
  反应条件:1.1 Reagents: Potassium Tert-Butoxide Catalysts: 1,10-Phenanthroline,Ferrous Chloride Solvents: Toluene; 24 H,120 °C
  标题:Iron-Catalyzed Direct Julia-Type Olefination Of Alcohols
  作者:Landge,Vinod G.; Et Al
  参考文献:Journal Of Organic Chemistry 日期:2020 卷标:85(15) 页码:9876-9886]
  
  3487-44-3 + 66-99-9 = 827-54-3 [标题:Reaction Conditions
  标题:Donor-Acceptor Bicyclopropyls As 1,6-Zwitterionic Intermediates: Synthesis And Reactions With 4-Phenyl-1,2,4-Triazoline-3,5-Dione And Terminal Acetylenes
  作者:Potapov,Konstantin V.; Et Al
  参考文献:Journal Of Organic Chemistry 日期:2020 卷标:85(23) 页码:15562-15576]
  
  612-55-5 + 1112-55-6 = 827-54-3
  反应条件:1.1 Reagents: Potassium Fluoride Catalysts: Palladium Solvents: Dimethylformamide; 5 H,2 Bar,130 °C
  标题:Supported Palladium Nanoparticles As Heterogeneous Ligand-Free Catalysts For The Hiyama C-C Coupling Of Vinylsilanes And Halobenzenes Leading To Styrenes
  作者:Grirrane,Abdessamad; Et Al
  参考文献:Journal Of Catalysis 日期:2013 卷标:302 页码:49-57]
  
  2949-26-0 = 827-54-3
  反应条件:1.1 Reagents: Potassium Hydroxide,Water Solvents: Tetrahydrofuran,Water; Rt
  标题:Selenium Vacancy Promotes Transfer Semihydrogenation Of Alkynes From Water Electrolysis
  作者:Ling,Yangfang; Et Al
  参考文献:Acs Catalysis 日期:2021 卷标:11(15) 页码:9471-9478]
  
  2949-26-0 = 827-54-3
  反应条件:1.1 Reagents: Potassium Hydroxide,Water Catalysts: Palladium Solvents: 1,4-Dioxane; 25 °C
  标题:Unveiling Subsurface Hydrogen Inhibition For Promoting Electrochemical Transfer Semihydrogenation Of Alkynes With Water
  作者:Hao,Qi; Et Al
  参考文献:Chinese Journal Of Catalysis 日期:2022 卷标:43(12) 页码:3095-3100]
  
  83813-73-4 + 627906-96-1 = 827-54-3
  反应条件:1.1 Reagents: Tripotassium Phosphate Catalysts: [bis(Bicyclo[2.2.1]Hept-2-Yl)Phosphine]Chloro[2-[(Dimethylamino-Kn)Methyl]Ferroc... Solvents: 1,4-Dioxane,Water; 17 H,100 °C
  标题:Direct Vinylation And Difluorovinylation Of Arylboronic Acids Using Vinyl- And 2,2-Difluorovinyl Tosylates Via The Suzuki-Miyaura Cross Coupling
  作者:Goegsig,Thomas M.; Et Al
  参考文献:Journal Of Organic Chemistry 日期:2008 卷标:73(9) 页码:3404-3410]
  
  580-13-2 = 827-54-3
  反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Water,Polyethylene Glycol; 5 Min,Rt1.2 Catalysts: Palladium Diacetate; 3 H,140 °C
  标题:Mechanistic Studies On The Pd-Catalyzed Vinylation Of Aryl Halides With Vinylalkoxysilanes In Water: The Effect Of The Solvent And Naoh Promoter
  作者:Gordillo,Alvaro; Et Al
  参考文献:Journal Of The American Chemical Society 日期:2013 卷标:135(37) 页码:13749-13763]
  
  13170-43-9 + 4469-45-8 = 827-54-3 [标题:Reaction Conditions
  标题:Synthesis Of Alkenes By Peterson Alkenation
  作者:Ager,D. J.
  参考文献:Science Of Synthesis 日期:2010 卷标:47 页码:85-104]
  
  2065-66-9 + 66-99-9 = 827-54-3
  反应条件:1.1 Reagents: Potassium Carbonate Solvents: 1,4-Dioxane; 12 H,Reflux
  标题:Visible Light And Triselenium Dicyanide (Tsd): New Horizons In The Synthesis Of Organic Selenocyanates
  作者:Anghinoni,Joao M.; Et Al
  参考文献:Chemistry - A European Journal 日期:2023 卷标:29(59)

海关参考信息

• 2901210000-乙烯
  2902300000-甲苯
  2902500000-苯乙烯
  2902902000-精萘
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