CAS: 434-64-0; 1,2,3,4,5-Pentafluoro-6-(Trifluoromethyl)Benzene

上下游产品

perfluoro(methylcyclohexane) 2,3,4,5,6-pentachloro-1-(trifluoromethyl)benzene Hexafluorobenzene BromotrifluoromethanePentafluorobenzoic acid perfluoro-para-cymene Perfluorpentaaethylmethylbenzol 3-C6F4CH(CN)24-CF3-C6F4CH(CN)2

Nbu4N+[cu(2,3,4,5,6-Pentafluorophenyl)(Cf3)3]-以 1,2-二氯乙烷 作为反应溶剂,以90%的收率获得产物八氟甲苯
参考文献:铜介导的芳烃三氟甲基化中的关键中间体[nbu4N] [cu(ar)(cf3)3]:合成,表征和c(sp2)-Cf3还原消除
标题:铜介导的芳烃三氟甲基化中的关键中间体[nbu4N] [cu(ar)(cf3)3]:合成,表征和c(sp2)-Cf3还原消除
摘要:描述了稳定的芳基[三(三氟甲基)]铜(iii)配合物[N Bu 4 N] [cu(ar)(cf 3)3]的合成,表征和c(sp 2)-Cf 3还原消除.机械研究,包括动力学研究,温度,溶剂和芳基对位取代基的影响研究以及dft计算,均表明c(sp 2)-Cf 3的还原消除是通过协调一致的碳进行的.碳键形成途径.
DOI:10.1002/anie.201904041

专利信息

专利号:US-9610572-B2
优先权日:2012-11-15
标 题 :Ruthenium complexes, method of their production and their usage
发明人：GRELA KAROL; CZARNOCKI STEFAN
权利人:APEIRON SYNTHESIS SPÓLKA AKCYJNA; APEIRON SYNTHESIS SPOLKA AKCYJNA
摘要:The invention concerns the ruthenium complexes of the formula 1: n nacting as pre(catalysts) in the reaction of metathesis of olefins, as well as a method for their production, and their usage.

专利号:US-10676423-B2
优先权日:2017-02-21
标题 :Structure and synthesis of highly fluorinated amino acid derivatives
发明人：WEAVER JIMMIE DEAN; TEEGARDIN KIP ALLEN; ARORA AMANDEEP
权利人:UNIV OKLAHOMA STATE
摘要:Methods of synthesizing polyfluorinated amino acid derivatives are disclosed, along with polyfluorinated amino acid derivatives produced from said methods, as well as compositions containing same. The synthesis methods utilize an oxazolone and a perfluoroarene to produce the polyfluorinated amino acid derivatives.

专利号:US-10974236-B2
优先权日:2016-11-10
标 题 :Use of ruthenium complexes in olefin metathesis reaction
发明人：SKOWERSKI KRZYSZTOF; GAWIN RAFAL; CHWALBA MICHAL PAWEL
权利人:APEIRON SYNTHESIS SA
摘要:The invention relates to the use of ruthenium complexes, which are homogeneous catalysts and/or precatalysts of the olefin metathesis reaction, which lead to the production of alkenes containing an internal (non-terminal) double Câ•?C bond.

专利号:WO-9714698-A1
优先权日:1995-10-18
标题:Synthesis of perfluoroaryl-substituted compounds
发明人：FRAZIER KEVIN A
权利人:DOW CHEMICAL CO
摘要:Perfluoroaryl-substituted compounds are prepared from perfluoroaryl compounds, particularly tris pentafluorophenyl borane is prepared from hexafluorobenzene. The method comprises contacting a perfluoroaryl compound with an organomagnesium reagent in the presence of a catalyst to form a perfluoroaryl magnesium compound, and contacting the perfluoroaryl magnesium compound with a trihalide element to form a tris perfluoroaryl-substituted compound.

专利号:WO-2015131100-A1
优先权日:2014-02-28
标题:Ligand-controlled c(sp3)-h arylation and olefination in synthesis of unnatural chiral alpha amino acids
发明人：YU JIN-QUAN
权利人:SCRIPPS RESEARCH INST
摘要:The use of ligands to tune the reactivity and selectivity of transition metal-catalysts for C(-sp3)-H bond functionalization is a central challenge in synthetic organic chemistry. Herein, we report a rare example of catalyst-controlled C(sp3)-H arylation using pyridine and quinoline derivatives: the former promotes exclusive monoarylation, whereas the latter activates the catalyst further to achieve diarylation. Successive application of these ligands enables the sequential diarylation of a methyl group in an alanine derivative with two different aryl iodides, affording a wide range of β-Ar-p-Ar ' -cc-amino acids with excellent levels of diastereoselectivity (d.r. > 20:1). Both configurations of the β-chiral center can be accessed by choosing the order in which the aryl groups are installed. The use of a quinoline derivative as a ligand also enables C(sp3)-H olefination of a protected alanine.

专利号:US-5026929-A
优先权日:1990-02-08
标题:Synthesis of highly fluorinated aromatic compounds
发明人：MARSELLA JOHN A; PEZ GUIDO P; COUGHLIN ANNE M
权利人:AIR PROD & CHEM
摘要:A process is disclosed for making a highly fluorinated aromatic compound by contacting a perfluorocycloalkane, such as perfluorodecahydronaphthalene, with a complex of a metal from Groups IA and IIA of the Periodic Table and an organic electron acceptor. The reaction is carried out in an organic solvent and under reducing conditions which are relatively moderate. Best results are obtained using a perfluorocycloalkane having 2-4 condensed rings and a complex of either sodium or lithium and benzophenone thereby making a perfluorinated condensed ring aromatic compound such as perfluoronaphthalene or perfluorophenanthrene.