专利号:US-5525325-A 优先权日:1989-03-06 标 题 :Expanded porphyrins: large porphyrin-like tripyrroledimethine-derived macrocycles 发明人:SESSLER JONATHAN L; HEMMI GREGORY W; MURAI TOSHIAKI 权利人:REGENTS UNIVERSITY OF TEXAS BO 摘要:The present invention involves a novel tripyrrole dimethine-derived 'expanded porphyrin' (texaphyrin), the synthesis of such compounds, their analogs or derivatives and their uses. These expanded porphyrin-like macrocycles are efficient chelators of divalent and trivalent metal ions. Metal complexes of these compounds are active as photosensitizers for the generation of singlet oxygen and thus potentially for inactivation or destruction of human immunodeficiency virus (HIV-1), mononuclear or other cells infected with such virus and tumor cells as well. A variety of texaphyrin derivatives have been produced and many more are readily obtainable. Various metal (e.g., transition, main group, and lanthanide) complexes with the texaphyrin and texaphyrin derivatives of the present invention have unusual water solubility and stability which render them particularly useful. These metallotexaphyrin complexes have optical properties making them unique as compared to existing porphyrin-like or other macrocycles. For example, they absorb light strongly in a physiologically important region (i.e. 690-880 nm). These complexes also form long-lived triplet states in high yield and act as efficient photosensitizers for the formation of singlet oxygen. These properties, coupled with their high chemical stability and appreciable solubility in polar media such as water, add to their usefulness.
专利号:US-9533892-B2 优先权日:2011-09-02 标 题 :Flame spray synthesis of monoclinic Lu2O3 nanoparticles 发明人:BAKER COLIN C; KIM WOOHONG; VILLALOBOS GUILLERMO R; SANGHERA JASBINDER S; AGGARWAL ISHWAR D 权利人:BAKER COLIN C; KIM WOOHONG; VILLALOBOS GUILLERMO R; SANGHERA JASBINDER S; AGGARWAL ISHWAR D; US NAVY 摘要:A nanoparticle containing monoclinic lutetium oxide. A method of: dispersing a lutetium salt solution in a stream of oxygen gas to form droplets, and combusting the droplets to form nanoparticles containing lutetium oxide. The combustion occurs at a temperature sufficient to form monoclinic lutetium oxide in the nanoparticles. An article containing lutetium oxide and having an average grain size of at most 10 microns.
专利号:US-6946114-B2 优先权日:2000-09-05 标题:Lanthanide-promoted rhodium catalysts and process for producing synthesis gas 发明人:ALLISON JOE D; SWINNEY LARRY D; NIU TIANYAN; RICKETSON KEVIN L; WANG DAXIANG; RAMANI SRIRAM; STRAGUZZI GLORIA I; MINAHAN DAVID M; WRIGHT HAROLD A; HU BAILI 权利人:CONOCOPHILLIPS CO 摘要:Lanthanide-promoted rhodium-containing supported catalysts that are active for catalyzing the net partial oxidation of methane to CO and H 2 are disclosed, along with their manner of making and high efficiency processes for producing synthesis gas employing the new catalysts. A preferred catalyst comprises highly dispersed, high surface area rhodium on a granular zirconia support with an intermediate coating of a lanthanide metal and/or oxide thereof and is thermally conditioned during catalyst preparation. In a preferred syngas production process a stream of methane-containing gas and O 2 is passed over a thermally conditioned, high surface area Rh/Sm/zirconia granular catalyst in a short contact time reactor to produce a mixture of carbon monoxide and hydrogen.
专利号:US-5256399-A 优先权日:1989-03-06 标题:Aromatic pentadentate expanded porphyrins in magnetic resonance imaging 发明人:SESSLER JONATHAN L; HEMMI GREGORY W; MURAI TOSHIAKI 权利人:UNIV TEXAS 摘要:The present invention involves a novel tripyrrole dimethine-derived 'expanded porphyrin' (texaphyrin), the synthesis of such compounds, their analogs or derivatives and their uses. These expanded porphyrin-like macrocycles are efficient chelators of divalent and trivalent metal ions. Metal complexes of these compounds are active as photosensitizers for the generation of singlet oxygen and thus potentially for inactivation or destruction of human immunodeficiency virus (HIV-1), mononuclear or other cells infected with such virus and tumor cells as well. A variety of texaphyrin derivatives have been produced and many more are readily obtainable. Various metal (e.g., transition, main group, and lanthanide) complexes with the texaphyrin and texaphyrin derivatives of the present invention have unusual water solubility and stability which render them particularly useful. These metallotexaphyrin complexes have optical properties making them unique as compared to existing porphyrin-like or other macrocycles. For example, they absorb light strongly in a physiol n This invention was made in part with government support under the National Science Foundation Presidential Young Investigator Award (1986) to J. L. Sessler, grant CHE-8552768. The government has certain rights in the invention.
专利号:US-8877942-B2 优先权日:2009-10-09 标 题:2,2′-disubstituted dipyrrin compounds, synthesis thereof and methods of use thereof 发明人:FILATOV MIKHAIL; CHEPRAKOV ANDREI; VINOGRADOV SERGEI A; LEBEDEV ARTEM Y 权利人:FILATOV MIKHAIL; CHEPRAKOV ANDREI; VINOGRADOV SERGEI A; LEBEDEV ARTEM Y; UNIV PENNSYLVANIA 摘要:The present invention relates to 2,2′-di-substituted dipyrrins. The invention also relates to methods for the preparation of 2,2′-disubstituted dipyrrins, and to the use of 2,2′-disubstituted dipyrrins in, for example, sensing, imaging and laser applications.
专利号:CN-108793980-A 优先权日:2018-07-10 标题 :A method for preparing alumina-based solid solution ceramic powder by combustion synthesis of water mist