CAS: 14381-51-2; 3-Bromobenzene-1,2-Diol

相似化合物

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Sodium 2-Bromo-6-Fluorophenolate 以 丙酮 用作溶剂,化学反应 0.66H,反应生成3-溴邻苯二酚
参考文献:带有双(μ-氧代)双铜(III)物种的2-氟酚盐的选择性正羟基加氢脱氟
标题:带有双(μ-氧代)双铜(III)物种的2-氟酚盐的选择性正羟基加氢脱氟
摘要:双(μ-氧代)双铜(III)物种[cu Iii 2(μ-O)2(m-Xyl Mean)] 2+(1)促进2-氟酚盐的亲电子邻羟基化-脱氟,得到相应的儿茶酚,反应不是accomplishable用(η 2:η 2-O 2)亚铜(II)络合物.同位素标记研究表明,进入的氧原子源自bis(μ-Oxo)单元.在分子内竞争中,与其他邻位取代基(例如氯或溴)选择性发生邻羟基化-脱氟.
Doi:10.1002/anie.201405060

专利信息

专利号:US-9981887-B1
优先权日:2017-01-10
标题 :Synthesis of phenylethynylbenzenes
发明人：LASKOSKI MATTHEW; KELLER TEDDY M
权利人:US NAVY
摘要:A method of: reacting a dihydroxybenzene with bromine to form a bromodihydroxybenzene; reacting the bromodihydroxybenzene with trifluoromethanesulfonyl chloride or trifluoromethanesulfonic anhydride to form a bromotrifluoromethanesulfonatobenzene; and reacting the bromotrifluoromethanesulfonatobenzene with phenylacetylene to form a phenylethynylbenzene.

专利号:US-7723498-B2
优先权日:2004-06-04
标题:Directed evolution of recombinant monooxygenase nucleic acids and related polypeptides and methods of use
发明人：WOOD THOMAS K; VARDAR GONUL
权利人:UNIV CONNECTICUT
摘要:The present invention relates to novel monooxygenase nucleic acids and polypeptides created using mutagenesis, DNA shuffling, or both, in a single iteration or multiple iterations, and methods for their creation and use. The monooxygenase enzymes of the present disclosure have particular utility as biocatalysts in industrial chemical redox reactions, such as the oxidation of aromatic hydrocarbons, for example, toluene, benzene, or nitrobenzene, into industrially desirable products. The systems and processes of the present invention are especially useful for the coupled synthesis and recovery of catechols, methylcatechols, resorcinols, methylresorcinols, hydroquinones, methylhydroquinones, hydroxybenzenes, cresols, nitrobenzenes, and nitrohydroxyquinones.

专利号:WO-2018132445-A1
优先权日:2017-01-10
标题 :Synthesis of phenylethynylbenzenes

专利号:CN-109468332-B
优先权日:2018-11-29
标题 :Application of the gene encoding bromocatechol 1,2 dioxygenase in the synthesis of 2-bromomuconic acid

专利号:CN-109468332-A
优先权日:2018-11-29
标题:Application of the 1,2 dioxygenase encoding gene of bromine catechol in synthesis 2- bromine muconic acid

专利号:CN-115340876-A
优先权日:2022-06-10
标 题 :A kind of 2-position-asymmetric ester group rigid group substituted triphenylene-like discotic liquid crystal and its synthesis method and application