CAS: 33401-74-0; (S)-Ethyl 3-Hydroxy-3-Phenylpropanoate
该化合物是一种具有立体特性(3S)-氢氧配置和苯丙基丙酸主干基特征的手性酯化合物;这一光学活性中间体因其在不对称合成中的作用而受到重视,特别是在对等选择性至关重要的制药和精细化学应用中所发挥的作用而受到重视;氢氧基和酯功能组的存在增强了其作为进一步衍生的构件的效用,使复杂的分子能够合成具有较高的立体化学纯度;其明确界定的手性中心确保催化和声学测量反应的一贯性能;该复合体通常具有较高的化学和光学纯度,因此适合于需要精确立体化学控制的研究和工业过程.
- 英文名称(S)-Ethyl 3-Hydroxy-3-Phenylpropanoate
- 中文名称(S)-3-羟基-3-苯基丙酸乙酯
- IUPAC名称ethyl (S)-3-hydroxy-3-phenylpropanoate
- 其它别名(S)-(-)-3-羟基-3-苯基丙酸乙酯; (-)-Ethyl (S)-3-Hydroxy-3-Phenylpropionate
- CAS编号33401-74-0
- MFCD编号:MFCD00216721
- EINECS号:877-864-8
- FDA UNII编号:3S4J5C6Q4Z
- 分子式:C11H14O3
- 分子量:194.23
- 产品CID: 1329598
- 产品分类有机原料→分子砌块→芳环类化合物→苯类化合物
物理性质
MSDS等安全信息
欧盟法规
C&L通报上下游产品
CAS号94-02-0 苯甲酰乙酸乙酯 | CAS号1006696-15-6 ethyl (3S)-3-ph... | CAS号4704-31-8 癸酸乙烯酯 | CAS号5764-85-2 3-羟基-3-苯基丙酸乙酯 | CAS号100-52-7 苯甲醛 | CAS号623-48-3 碘代醋酸乙酯 | CAS号146452-39-3 ethyl 2-chloro-... | CAS号146452-40-6 ethyl 2-chloro-... | CAS号36567-72-3 (S)-3-羟基-3-苯基丙酸 | CAS号75-03-6 碘乙烷 | CAS号36615-45-9 (S)-3-羟基-3-苯基丙酸甲酯 | CAS号82248-59-7 盐酸托莫西汀 | CAS号96854-34-1 (S)-1-苯基-1,3-丙二醇 | CAS号614-19-7 DL-β-苯丙氨酸 | CAS号114133-37-8 (S)-3-(甲基氨基)-1-苯基丙醇 | CAS号114247-09-5 R-氟西汀合成工艺路线路线简述
3-羟基-3-苯丙酸置于吡啶,盐酸,乙醇,Sodium Nitrite体系中,化学反应生成(S)-(-)-3-羟基-3-苯基丙酸乙酯
参考文献:所述的397.瓦尔登翻转反应p-Toluenesulphinic和p乙基甲苯磺酸酯d-β羟基-β-苯基
标题:所述的397.瓦尔登翻转反应p-Toluenesulphinic和p乙基甲苯磺酸酯d-β羟基-β-苯基
摘要:
Doi:10.1039/jr9350001663
海关参考信息
- 2902600000-乙苯
2905121000-正丙醇
2905399001-1,3-丙二醇
2906210000-苄醇 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-6303796-B1
优先权日:1998-02-26
标题:β-diketone compounds β-diketone compounds coordinated to metal, method of organic synthesis with these, and catalyst
发明人：YAMAGUCHI MASAHIKO; SATO MASAYUKI
权利人:CHISSO CORP
摘要:The present invention provides a novel β-diketone compound represented by formula (3): n [wherein X represents (CH 2 ) n ; n represents an integer of 2-20; and the CH 2 of X may be replaced by an oxygen atom, a hetero ring, or an aromatic ring, but oxygen atoms are not sequentially arranged in X], and a metal-coordinated β-diketone compound in which a metal is coordinated with the β-diketone compound. The compound of the present invention can be easily synthesized, and serves as a catalyst for asymmetric synthesis which can provide high asymmetric yield and chemical yield.
专利号:KR-20040104076-A
优先权日:2003-06-03
标题 :Alcohol dehydrogenase-producing microorganisms for the synthesis of optically active ethyl 3-hydroxy-3-phenylpropionate from ethyl benzoylacetate
专利号:EP-1067127-A1
优先权日:1998-02-26
标题:Novel beta-diketone compounds, beta-diketone compounds coordinated to metal, method of organic synthesis with these, and catalyst
专利号:WO-9943668-A1
优先权日:1998-02-26
标题:NOVEL β-DIKETONE COMPOUNDS, β-DIKETONE COMPOUNDS COORDINATED TO METAL, METHOD OF ORGANIC SYNTHESIS WITH THESE, AND CATALYST
专利号:EP-1067127-B1
优先权日:1998-02-26
标题 :Novel beta-diketone compounds, beta-diketone compounds coordinated to metal, method of organic synthesis with these, and catalyst
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📌 第三方产品分析报告
合成参考文献
摘要:Zaidlewicz, M.; Pakulski, M. M., Science of Synthesis: Stereoselective Synthesis, (2011) 2, 85.
摘要:Brown, J. M.; Nguyen, B. N., Science of Synthesis: Stereoselective Synthesis, (2011) 1, 317.
摘要:Wu, X.; Xiao, J., Science of Synthesis: Water in Organic Synthesis, (2012) 1, 282.
摘要:Cuenca, A. B.; Fernández, E., Science of Synthesis: N-Heterocyclic Carbenes in Catalytic Organic Synthesis, (2016) 1, 335.
摘要:Llopis, Q.; Ayad, T.; Phansavath, P.; Ratovelomanana-Vidal, V., Science of Synthesis: Catalytic Reduction in Organic Synthesis, (2018) 2, 124.
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