CAS: 118612-00-3; N,N-Dimethylbenzenaminium Tetrakis(Perfluorophenyl)Borate

Ammonium Tetrakis(Pentafluorophenyl)Borate,N,N-二甲基苯胺 以 水 用作溶剂,化学反应 5.0H,以96.2%的收率获得n,N-二甲基苯铵四(五氟苯基)硼酸盐
参考文献:Novel Tetraaryl Borate Compound And Method For Producing Same
标题:Novel Tetraaryl Borate Compound And Method For Producing Same
摘要:本发明涉及一种新型四芳基硼酸盐化合物及其制备方法,以及使用该四芳基硼酸盐化合物作为中间体制备四芳基硼酸盐化合物的方法.根据本发明,可以提供一种具有高热稳定性且可以在工业上安全处理的四芳基硼酸盐化合物及其制备方法.同时,还可以提供一种通过将四芳基硼酸盐化合物进一步与胺化合物反应制备用作金属茂催化剂共催化剂的四芳基硼酸盐化合物的方法.

专利信息

专利号:US-6479599-B1
优先权日:1997-04-04
标题:Catalyst system for high yield synthesis of polyolefins
发明人：PEIL KEVIN P; WILSON DAVID R
权利人:BP CHEM INT LTD
摘要:This invention relates to a supported metallocene catalyst system for the high yield synthesis of polyolefins, to methods of preparation of the catalyst system, to polymerization processes which use the catalyst system and to polyolefin polymers produced by the polymerization processes.

专利号:US-8933181-B2
优先权日:2006-10-06
标题:Branched polymers and methods for their synthesis and use
发明人：MOURI HIROSHI; LUO STEVEN; KURASCH JESSICA; ROBERTSON CHRISTOPHER G; WARREN SANDRA
权利人:MOURI HIROSHI; LUO STEVEN; KURASCH JESSICA; ROBERTSON CHRISTOPHER G; WARREN SANDRA; BRIDGESTONE CORP
摘要:Branched polymers including multi-branched polymers, functionalized branched polymers, star-branched polymers, and dendigraft polymers. Methods for the synthesis of branched polymers and method for the use of branched polymers in tire components are also included.

专利号:US-7833926-B2
优先权日:2005-07-01
标题 :Arylphenoxy catalyst system for producing ethylene homopolymer or copolymers of ethylene and α-olefins
发明人：WOO TAE WOO; OK MYUNG AHN; HAHN JONG SOK; LEE MAL-OU; KANG SANG OOK; KO SUNG-BO; KIM TAE-JIN; KIM SUNG-KWAN
权利人:SK ENERGY CO LTD
摘要:The present invention relates to an arylphenoxy catalyst system producing an ethylene homopolymer or copolymers of ethylene and α-olefins, and a method of producing an ethylene homopolymer or copolymers of ethylene and α-olefins having a high molecular weight under a high temperature solution polymerization condition using the same. The catalyst system includes a group IV arylphenoxy-based transition metal catalyst and an aluminoxane cocatalyst or a boron compound cocatalyst. In the transition metal catalyst, a cyclopentadiene derivative and arylphenoxide as fixed ligands are located around the group IV transition metal, arylphenoxide is substituted with at least one aryl derivative and is located at the ortho position thereof, and the ligands are not crosslinked to each other. The catalyst includes an environmentally-friendly raw material, synthesis of the catalyst is economical, and thermal stability of the catalyst is excellent. It is useful for producing an ethylene homopolymer or copolymers of ethylene and α-olefins having various physical properties in commercial polymerization processes.

专利号:US-8168556-B2
优先权日:2007-10-25
标 题 :Racemoselective synthesis of ansa-metallocene compounds, ansa-metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo- and copolymers
发明人：SCHULTE JOERG; SELL THORSTEN; THORN MATTHEW GRANT; WINTER ANDREAS; DIMESKA ANITA
权利人:SCHULTE JOERG; SELL THORSTEN; THORN MATTHEW GRANT; WINTER ANDREAS; DIMESKA ANITA; LUMMUS NOVOLEN TECHNOLOGY GMBH
摘要:A metallocene compound with the 4- and 7-positions on the indenyl moiety possessing large aromatic substituents is prepared in accordance with a method which produces substantially 100 percent racemic isomer. Advantageously, polymerization catalysts including the metallocene of the invention provide superior olefin polymerization results.

专利号:US-2004241251-A1
优先权日:2001-05-04
标 题:Random or block co-or terpolymers produced by using of metal complex catalysts
发明人：THIELE SVEN K H; MONROY VICTOR M; WILSON DAVID R
摘要:Random or block co- or terpolymers produced by using metal complex catalysts in a reaction of one conjugated diene monomer with one aromatic Random or block co- or terpolymers produced by using metomers with one aromatic α-olefin or terpolymers of one conjugated diene monomer with one aromatic α-olefin and one aliphatic α-olefin by using metal complexes comprising metals of group 3 to 10 of the Periodic System of the Elements in combination with activators and optionally a support material. More particularly the metal complexes used for the synthesis of co- or terpolymer are lanthanide metals. Even more particularly diene monomer(s) and aromatic α-olefin monomer(s) such as, but not limited to, butadiene and styrene or isoprene and styrene are copolymerized giving random or block copolymers or butadiene, styrene and isoprene are terpolymerized giving random or block terpolymers using metal complexes comprising lanthanide metals in combination with activators and optionally a support material. Preferably random co- or terpolymers are formed.

专利号:US-9663594-B2
优先权日:2014-05-15
标 题 :Synthesis of aryl coupled bis phenoxides and their use in olefin polymerization catalyst systems with activator-supports
发明人：HLAVINKA MARK L
权利人:CHEVRON PHILLIPS CHEMICAL CO LP; CHEVRON PHILIPS CHEMICAL COMPANY LP
摘要:Disclosed herein are methods of making bis(phenol) ligand compounds and transition metal bis(phenolate) compounds. The transition metal bis(phenolate) compounds can be used as components in catalyst systems for the polymerization of olefins.