二糠基二硫置于三丁基膦,水体系中,用 N,N-二甲基甲酰胺 用作溶剂,化学反应 1.5H,反应生成硫代乙酸糠酯
参考文献:A Preparative Scale Reduction Of Alkyl Disulfides With Tributyl Phosphine And Water
标题:A Preparative Scale Reduction Of Alkyl Disulfides With Tributyl Phosphine And Water
摘要:A Series Of Alkyl Disulfides Has Been Shown To Be Reduced By Tributyl Phosphine At Room Temperature. The Resulting Thiols Were Then Acylated In The Same Pot And Isolated In Good Yields. This Sequence Is Convenient And Is A Practical Option For The Preparation Of Gram Quantities Of Thiol Or Thioester From The Corresponding Disulfide.
Doi:10.1080/00397919908085777