CAS: 137-42-8; Metam-Sodium

该化合物是化学化合物,是水中可溶解的黄黄色晶状固体,可以有效应用于农业环境;Metham 钠,通过水解释放甲基异硫氰酸盐(MITC),这是一种具有生物杀灭特性的化合物,能够有效防治各种害虫,包括杂草,线虫和土壤传播的病原体;其应用通常用于各种作物的种植前处理,帮助为耕种土壤做好准备;然而,由于甲胺钠对人类和环境的潜在毒性,处理它十分重要;在使用过程中,适当的保护设备和遵守安全准则至关重要;此外,许多区域都对其使用加以管制,以减轻与化学品接触和环境影响有关的风险.

结构式图片

欧盟法规

《欧盟PIC法规》统一分类与标签REACH注册ECHA物质OtherC&L通报欧盟生物杀灭剂法规欧盟《生物杀灭剂法规》REACH预注册废弃物危险特性清单"欧盟管控危险化学品"工作场所安全标识要求ECHA物质

上下游产品

CAS号75-15-0 二硫化碳 | CAS号74-89-5 氨基甲烷 | CAS号100-01-6 对硝基苯胺 | CAS号2438-90-6 N,N'-dimethylth... | CAS号65872-41-5 氨噻肟酸 | CAS号556-61-6 异硫氰酸甲酯 | CAS号636-04-4 N-苯基硫代苯甲酰胺 | CAS号14598-03-9 6-phenylpropior... | CAS号2757-10-0 (E)-N-Methyl-3-... | CAS号120189-50-6 6-phenyl-3-meth... | CAS号13037-11-1 Carbamodithioic... | CAS号1630-99-5 N-methyl-1,3-di...

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    海关参考信息

    专利信息


    专利号:US-7435855-B2
    优先权日:2004-06-18
    标题:Process for the continuous synthesis of methylamines
    发明人:BOSCH MARCO; EBERHARDT JAN KURT; ROETTGER RODERICH; KRUG THOMAS; MELDER JOHANN-PETER
    权利人:BASF SE
    摘要:Process for the continuous synthesis of methylamines by reaction of methanol and/or dimethyl ether with ammonia in the presence of a heterogeneous catalyst, wherein the catalyst used is a shaped body which comprises a microporous material and at least one organosilicon compound as binder and can be produced by a process comprising the stepsn (I) preparation of a mixture comprising the microporous material, the binder, a pasting agent and a solvent, (II) mixing and densification of the mixture, (III) shaping of the densified mixture to give a shaped body, (IV) drying of the shaped body and (V) calcination of the dried shaped body.

    专利号:US-7651968-B2
    优先权日:2005-12-12
    标 题:Shaped body comprising a microporous material and at least one silicon-containing binding agent method for production and use thereof as catalyst in particular in a method for continuous synthesis of methylamines
    发明人:BOSCH MARCO; EBERHARDT JAN; ROETTGER RODERICH
    权利人:BASF SE
    摘要:A process for producing a shaped body comprising a microporous material and at least one silicon-comprising binder, which comprises the stepsn (I) preparation of a mixture comprising the microporous material, the binder and a lubricant, (II) mixing and densification of the mixture, (III) shaping of the densified mixture to give a shaped body and (IV) calcination of the shaped body,n nwherein a silicone resin having a softening point of ≧30° C. is used as binder,n nshaped bodies which can be produced by this process, their use as catalyst, in particular in organic synthesis and very particularly preferably in a process for preparing methylamines.

    专利号:US-4502994-A
    优先权日:1982-12-09
    标题 :Enantiomeric synthesis of 3-amino-4-carbamoyloxymethyl-2-azetidonone-1-sulfate
    发明人:WEI CHUNG-CHEN; WEIGELE MANFRED
    权利人:HOFFMANN LA ROCHE
    摘要:A novel enantiomeric synthesis from ascorbic acid of (3S,4S)-3-amino-4-carbamoyloxymethyl-2-azetidinone-1-sulfate, an intermediate for an antibiotic compound.

    专利号:WO-2025056767-A1
    优先权日:2023-09-15
    标题 :Process for the preparation of enantiomerically enriched aliphatic amines
    发明人:BOU HAMDAN FARHAN; GODINEAU EDOUARD; SMEJKAL TOMAS; DUMEUNIER RAPHAEL; BOUSSEMGHOUNE MOHAMED ABDELOUAHAB; BLUM MATHIAS
    权利人:SYNGENTA CROP PROTECTION AG
    摘要:The present invention relates to a process for the preparation of enantiomerically enriched cyclobutylamines of formula (I) from α-tertiary cyclobutanones and reacting said enantiomerically enriched cyclobutylamines to enantiomerically enriched cyclobutylamides. Such compounds are useful intermediates in the synthesis of microbiocidal thiazole compounds.

    专利号:US-2016073631-A1
    优先权日:2013-03-04
    标 题 :Process for the preparation of dihydropyrrole derivatives
    发明人:EL QACEMI MYRIEM; SMITS HELMARS; CASSAYRE JEROME YVES; MULHOLLAND NICHOLAS PHILLIP; RENOLD PETER; GODINEAU EDOUARD; PITTERNA THOMAS
    权利人:SYNGENTA PARTICIPATIONS AG; SYNGENTA LTD
    摘要:The present invention provides stereoselective processes for the preparation of compounds of formula (I) n n n n n n n n n n n n wherein n P is phenyl, naphthyl, a 6-membered heteroaryl group containing one or two nitrogen atoms as ring members, or a 10-membered bicyclic heteroaryl group containing one or two nitrogen atoms as ring members, and wherein the phenyl, naphthyl and heteroaryl groups are optionally substituted; n R 1 is chlorodifluoromethyl or trifluoromethyl; n R 2 is optionally substituted aryl or optionally substituted heteroaryl; n n is 0 or 1; n including the process comprising n (a-i) reacting a compound of formula II n n n n n n n n n n n n n n n n wherein P, R 1 and R 2 are as defined for the compound of formula I; n with nitromethane in the presence a chiral catalyst to give a compound of formula III n n n n n n n n n n n n n n n n wherein P, R 1 and R 2 are as defined for the compound of formula I; and n (a-ii) reductively cyclising the compound of formula III to give the compound of formula I. n n n n n The invention also provides intermediates useful for processes for the synthesis of compounds of formula (I).

    专利号:US-9233920-B2
    优先权日:2010-06-11
    标题 :Process for the preparation of dihydropyrrole derivatives
    发明人:EL QACEMI MYRIEM; SMITS HELMARS; CASSAYRE JEROME YVES; MULHOLLAND NICHOLAS PHILLIP; RENOLD PETER; GODINEAU EDOUARD; PITTERNA THOMAS
    权利人:EL QACEMI MYRIEM; SMITS HELMARS; CASSAYRE JEROME YVES; MULHOLLAND NICHOLAS PHILLIP; RENOLD PETER; GODINEAU EDOUARD; PITTERNA THOMAS; SYNGENTA PARTICIPATIONS AG; SYNGENTA LTD
    摘要:The present invention provides stereoselective processes for the preparation of compounds of formula (I) wherein P is phenyl, naphthyl, a 6-membered heteroaryl group containing one or two nitrogen atoms as ring members, or a 10-membered bicyclic heteroaryl group containing one or two nitrogen atoms as ring members, and wherein the phenyl, naphthyl and heteroaryl groups are optionally substituted; R 1 is chlorodifluoromethyl or trifluoromethyl; R 2 is optionally substituted aryl or optionally substituted heteroaryl; n is 0 or 1; including the process comprising (a-i) reacting a compound of formula II wherein P, R 1 and R 2 are as defined for the compound of formula I; with nitromethane in the presence a chiral catalyst to give a compound of formula III Wherein P, R 1 and R 2 are as defined for the compound of formula I; and (a-ii) reductively cyclizing the compound of formula III to give the compound of formula I. The invention also provides intermediates useful for processes for the synthesis of compounds of formula (I).
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    合成参考文献


    摘要:World Review of Pest Control., 9(119), 1970
    摘要:Residue Reviews., 10(97), 1965 []
    摘要:Chemistry of Pesticides, Melnikov, N.N., New York, Springer-Verlag New York, Inc., 1971, -(213), 1971
    摘要:Pesticide Chemicals Official Compendium, Association of the American Pesticide Control Officials, Inc., 1966., -(1047), 1966
    摘要:Farm Chemicals Handbook., -(C196), 1991
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