CAS: 591-31-1; 3-Methoxybenzaldehyde

上下游产品

CAS号59184-17-7 acetic acid,(3-... | CAS号100-83-4 间羟基苯甲醛 | CAS号74-88-4 碘甲烷 | CAS号766-85-8 3-碘苯甲醚 | CAS号201230-82-2 carbon monoxide | CAS号54308-43-9 2-(3-methoxyphe... | CAS号6971-51-3 3-甲氧基苄醇 | CAS号1711-05-3 3-甲氧基苯甲酰氯 | CAS号1527-89-5 3-甲氧基苯腈 | CAS号2398-37-0 间溴苯甲醚 | CAS号604-53-5 1,1'-联萘 | CAS号6839-11-8 3-methoxy-α-(1-... | CAS号109251-88-9 (3-methoxypheny... | CAS号109673-21-4 3-methoxybenzon... | CAS号110192-19-3 1,2,3,4-tetrahy... | CAS号3189-22-8 7-甲氧基吲哚 | CAS号5071-96-5 3-甲氧基苄胺 | CAS号588-05-6 3-(2-氨基乙基)苯酚 | CAS号4920-80-3 3-甲氧基-2-硝基苯甲酸 | CAS号42923-77-3 6-甲氧基-1,2,3,4-四氢异喹啉

间甲基苯甲醚置于氧气,2,6-Lutidinium Perchlorate体系中,用 乙腈 作为反应溶剂,20.0 °C,101.33 Kpa 条件下,反应 12.0H,以50%的收率获得产物3-甲氧基苯甲醛
参考文献:烷基芳烃选择性电化学氧化为羰基化合物
标题:烷基芳烃选择性电化学氧化为羰基化合物
摘要:已经开发了一种用于苄基 C(Sp 3)-H 键氧化的有效电化学方法.各种甲基芳烃,甲基杂芳烃和苄基(杂)亚甲基可以在未分割的电池中以中等至极好的收率转化为所需的芳醛和芳酮,使用 O 2作为氧源,高氯酸镥作为电解质.在循环伏安法研究,18 O 标记实验和自由基捕获实验的基础上,提出了一种可能的单电子转移机制用于电氧化反应.
DOI:10.1021/acs.Orglett.1C02651

专利信息

专利号:US-5861532-A
优先权日:1997-03-04
标 题:Solid-phase synthesis of N-alkyl amides
发明人：BROWN EDWARD G; NUSS JOHN M
权利人:CHIRON CORP
摘要:Methods for solid phase synthesis of N-alkyl amides comprise reductive amination of carbonyl compounds using a reducing agent and an amine-containing linker bound to a solid support. The methods afford high yields of linker-bound, monoalkylated amines, and subsequent coupling with acid derivatives provide derivatized N-substituted amides in excellent yields after cleavage from the solid-phase. Compositions useful in solid phase synthesis are also described.

专利号:US-9242925-B2
优先权日:2011-08-29
标题:Versatile and stereospecific synthesis of γ,δ-unsaturated amino acids by Wittig reaction
发明人：JUGE SYLVAIN; BAYARDON JEROME; REMOND EMMANUELLE; ONDEL-EYMIN MARIE-JOELLE
权利人:JUGE SYLVAIN; BAYARDON JEROME; REMOND EMMANUELLE; ONDEL-EYMIN MARIE-JOELLE; CENTRE NAT RECH SCIENT; UNIV BOURGOGNE
摘要:The γ,δ-unsaturated α-amino acids of general formula (I). Also, a versatile process for the stereospecific synthesis of said compounds of formula (I), involving a Wittig reaction. Further, intermediate products of general formulae (II) and (III), as shown below, which are involved in the synthesis of compounds (I). n n n n n n n n n n n n Compounds of general formula (I) may be useful as therapeutic substances, or as reagents or intermediates for fine chemistry.

专利号:WO-2009033499-A1
优先权日:2007-09-13
标 题 :Total synthesis of enantiopure desogestrel
发明人：TIETZE LUTZ FRIEDJAHN; KRIMMELBEIN IIGA KRISTINE
权利人:UNIV GOETTINGEN GEORG AUGUST; TIETZE LUTZ FRIEDJAHN; KRIMMELBEIN IIGA KRISTINE
摘要:The present invention relates to a total synthesis of desogestrel and derivatives thereof, and to intermediate compounds of this synthesis.

专利号:US-6201120-B1
优先权日:1997-11-20
标题:Synthesis of 11-aryl-5,6-dihydro-11H-dibenz[b,e]azepines
发明人：MOUSSA ADEL M; LOMBARDY RICHARD J; HAIDER REEM M; SUN MINGHUA
权利人:PHARM ECO LAB INC
摘要:Disclosed is a three step synthesis of 11-aryl-5,6-dihydro-11H-dibenz[b,e]azepines from a 2-aminobenzophenone represented by the following structural formula:and a starting material represented by the following structural formula:Phenyl Ring A, Phenyl Ring B and Phenyl Ring C are independently unsubstituted or substituted with one, two or three substituents. Each substituent on Phenyl Ring A, Phenyl Ring B and Phenyl Ring C is independently chosen.R is -H, a aliphatic group, a substituted aliphatic group, an aryl group, a substituted aryl group, -C(O)-R', -C(O)-H, -C(O)-NHR', -S(O)2R', -C(O)-C(O)-R', -C(O)-C(O)-H, -C(S)-R', -C(S)-H, -C(O)-OR', -C(S)-OR', -C(O)-SR', -C(S)-SR', -C(O)-NR'2 or -C(O)-C(S)-R'. R' is an aliphatic group, a substituted aliphatic group, an aryl group or a substituted aryl group.R1 is a leaving group.The present invention also includes novel compounds which are intermediates in the preparation of 11-aryl-5,6-dihydro-11H-dibenz[b,e]azepines.

专利号:US-6524446-B2
优先权日:2001-03-27
标 题 :Process for synthesis of a porphyrin compound using a molecular sieve catalyst under microwave irradiation
发明人：KULKARNI SHIVANAND JANARDAN; RAGHAVAN KONDAPURAM VIJAYA; MOTKURI RADHA KISHAN; NAGABANDI SRINIVAS
权利人:COUNCIL SCIENT IND RES
摘要:The present invention provides an improved process for synthesis of porphyrin compounds of the general formula 1 n from pyrrole and aromatic aldehyde over zeolite molecular sieve catalysts using microwave heating, (solvent free) to provide an eco-friendly, economical, faster and selective heterogeneous method.

专利号:US-10266565-B2
优先权日:2011-04-12
标 题 :Peptide mimetic ligands of polo-like kinase 1 polo box domain and methods of use
发明人：BURKE JR TERRENCE R; LIU FA; LEE KYUNG S; PARK JUNG-EUN
权利人:BURKE JR TERRENCE R; LIU FA; LEE KYUNG S; PARK JUNG EUN; THE US SECRETARY DEPARTMENT OF HEALTH & HUMAN SERVICES
摘要:Novel compounds are provided that bind to polo-like kinases through the polo-box domain. In certain embodiments, the novel compounds are PEGylated peptides. The PEGylated peptides in accordance with the invention demonstrate high PBD-binding affinity. In certain embodiments, the PEGylated peptides have also achieved activities in whole cell systems. The invention also provides compounds that bind polo-like kinases through the polo-box domain and possess reduced anionic charge. Further provided are methods of design and/or synthesis of the PEGylated peptides and methods of use thereof. The invention provides methods of use of the compounds and methods of synthesis of the compounds.