专利号:US-3742080-A 优先权日:1969-04-11 标 题 :Rhodium based catalysts for the synthesis of 1,4-dienes 发明人:SU A 权利人:DU PONT 摘要:Improved catalysts are provided for the synthesis of 1,4-dienes from Alpha -monoolefins and conjugated dienes. The catalysts are rhodium (III) salts in combination with amides, phosphoramides, phosphine oxides, or water. The improved catalysts allow control of the trans-cis ratio of the 1,4-diene formed and are operable at useful rates in a wide range of solvent systems, both protonic and aprotic.
专利号:US-2018361327-A1 优先权日:2016-02-26 标题 :Gas separation membrane, gas separation module, gas separator, gas separation method, composition for forming gas separation layer, method of producing gas separation membrane, polyimide compound, and diamine monomer 发明人:KODAMA KEISUKE; SAWADA MAKOTO; WADA KENJI 权利人:FUJIFILM CORP 摘要:A gas separation membrane including a gas separation layer contains a crosslinked polyimide compound. In the gas separation membrane, and a gas separation module, a gas separator, and a gas separation method obtained by using the gas separation membrane, the crosslinked polyimide compound has a specific structural portion. A composition for forming a gas separation layer suitable for forming a gas separation layer of the gas separation membrane; a method of producing a gas separation membrane obtained by using this composition; a polyimide compound suitable as a raw material of a gas separation layer of the gas separation membrane; and a diamine monomer suitable for synthesis of this polyimide compound are provided.
专利号:US-4243787-A 优先权日:1977-11-23 标 题 :Bulk anionic polymerization process using an alkali metal amide and the salt of the same alkali metal with a hydroxylic compound 发明人:BOILEAU SYLVIE L; CAUBERE PAUL J; NDEBEKA GILBERTE; LECOLIER SERGE L; RAYNAL SERGE F 权利人:POUDRES & EXPLOSIFS STE NALE 摘要:The invention relates to a process for the anionic polymerization and copolymerization of vinyl, dienic and heterocyclic monomers. According to the invention, the process consists in carrying out the reaction in the presence of an initiator consisting of a molecular combination of an alkali metal amide and the salt of the same alkali metal with at least one hydroxylic compound and in the absence of solvent. The initiator can be prepared by intimately mixing its constituents or in the presence of a solvent of low polarity which is subsequently evaporated off, or in situ in the monomer. Application to the synthesis of special or widely used polymers and copolymers.
专利号:US-10227300-B2 优先权日:2015-01-22 标题 :Synthesis of triacetonediamine compounds by reductive amination proceeding from triacetonediamine and derivatives thereof 发明人:WILLY BENJAMIN; NIEMEYER JOCHEN; KREILKAMP GUENTER; VOM BRUCH BEATRIX; NEUMANN MANFRED; KEUP MICHAEL 权利人:WILLY BENJAMIN; NIEMEYER JOCHEN; KREILKAMP GUENTER; VOM BRUCH BEATRIX; NEUMANN MANFRED; KEUP MICHAEL; EVONIK DEGUSSA GMBH 摘要:An N-substituted triacetonediamine compound is prepared by reacting 4-amino-2,2,6,6-tetramethylpiperidine or a derivative thereof with a carbonyl compound in a reductive amination, wherein reductive conditions are established by conducting the reaction in the presence of hydrogen and in the presence of a supported catalyst, wherein the supported catalyst includes at least one metal M, wherein the metal M is selected from the group consisting of V, Cr, Mo, Mn, Ni, Pd, Pt, Fe, Ru, Os, Co, Rh, Ir, and Cu.
专利号:US-3732252-A 优先权日:1971-12-29 标题:Method for the synthesis of trioxan 发明人:KOMAZAWA H; MATSUNO O 权利人:POLYPLASTICS CO 摘要:A PROCESS FOR SYNTHESIZING TRIOXAN BY HEATING AN AQUEOUS SOLUTION OF 25-80% BY WEIGHT OF FORMALDEHYDE IN THE PRESENCE OF 1-20* BY WEIGHT OF AN ACIDIC SUBSTANCE AS CATALYST, CHARACTERIZED BY ADDING ONE OR MORE OF SOLUBLE ORGANIC COMPOUNDS SUCH AS ALCOHOLS, ETHERS OR ESTERS HAVING A DIELECTRIC CONSTANT OF LESS THAN 40 IN SUCH AN AMOUNT AS DEFINED BELOW: (1) $0.0233 (WT. PERCENT) X (WT. PERCENT OF WATER IN THE REACTION MIXTURE) FOR THE COMPOUND HAVING A DIELECTRIC CONSTANT OF LESS THAN 10. (2) $0.00233X(DIELECTRIC CONSTANT)(WT. PERCENT OF WATER IN THE REACTION MIXTURE) FOR THE COMPOUND HAVING A DIELECTRIC CONSTANT OF 10.1-20. (3) $(0.0325 (DIELECTRIC CONSTANT-20)+0.0465)X(WT. PERCENT OF WATER IN THE REACTION MIXTURE) FOR THE COMPOUND WITH A DIELECTRIC CONSTANT OF 20.1-40.
摘要:Lide, D.R. CRC Handbook of Chemistry and Physics 86TH Edition 2005-2006. CRC Press, Taylor & Francis, Boca Raton, FL 2005, p. 3-298 摘要:Organization for Economic Cooperation and Development; Screening Information Data Set for 2-(2-(2-Ethoxyethoxy)ethoxy)-ethanol, CAS #112-50-5 p.9 (May 1996). Available from the Database Query page at 摘要:Meylan WM et al; Environ Sci Technol 28: 459-65 (1992) 摘要:EPA/Office of Pollution Prevention and Toxics; High Production Volume (HPV) Challenge Program. Available from, as of March 6, 2007: 摘要:Organization for Economic Cooperation and Development; Screening Information Data Set for 2-(2-(2-Ethoxyethoxy)ethoxy)-ethanol, CAS #112-50-5 p.12 (May 1996). Available from, as of February 27, 2007: https://www.inchem.org/pages/sids.html