CAS: 1746-03-8; Vinylphosphonicacid

该化合物是一种有机磷化合物,其特征是其乙烯基和磷酸功能; 一种无色的黄色液,在水和有机溶剂中溶解,使其具有多种用途; 化合物具有碳原子之间的双重结合,允许聚合,使其在合成聚乙烯基硫酸和其他共生聚合物时可以用作单体; 硫磷基酸由于存在磷酸组,可以捐献质子溶解,因而具有酸性; 这种特性使得它可用于诸如粘合剂,涂层等应用,并成为聚合化学的修饰剂; 此外,它可以作为一种发泡剂,并在生物医学应用中,包括在药物运载系统中研究其潜力; 在处理该化合物时,应当采取安全防范措施,因为它可能会刺激皮肤和眼睛. 总的来说, 硫磷酸是一种有价值的化学品,具有多种工业和研究用途.

结构式图片

相似化合物

4645-32-3 34163-96-7 26598-36-7

欧盟法规

REACH注册ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

vinyldichlorophosphine oxide vinylphosphonic acid bis(trimethylsilyl) ester 2-chloroethylphosphonic acid bis(4-methoxyphenyl) vinylphosphonatedimethylvinylphosphonate ethenylphosphine Diethyl vinylphosphonate vinyldichlorophosphine oxide

合成工艺路线路线简述

    乙烯利置于air体系中,化学反应生成乙烯基膦酸
    参考文献:Microwave Synthesis Of Vinylphosphonic Acid And Its Derivatives
    标题:Microwave Synthesis Of Vinylphosphonic Acid And Its Derivatives
    摘要:Microwave Pyrolysis Of Beta-Substituted Ethylphosphonic Acid Derivatives Was Studied. The Resulting Mixture Of Vinylphosphonic Acid Derivatives Is Similar To That Obtained By Convective Heating.
    Doi:10.1134/s1070427212040179

    海关参考信息

    专利信息


    专利号:WO-2024012791-A1
    优先权日:2022-07-11
    标题 :Electrochemical synthesis of pyrazolines and pyrazoles
    发明人:BÄR ROBIN MAXIMILIAN; FORD MARK JAMES; KALDAS SHERIF JAMES; WALDVOGEL SIEGFRIED; HOFMANN SILJA; LINDEN MARTIN
    权利人:BAYER AG
    摘要:The present invention relates to an electrochemical process for the synthesis of pyrazolines and pyrazoles of formula (I). The process can be especially used for the synthesis of the herbicide safener mefenpyr-diethyl.

    专利号:US-6610802-B2
    优先权日:2001-05-29
    标题 :Process for synthesis of polymer compositions, polymer compositionS obtainable by the process, and use of the same
    发明人:ROOS SEBASTIAN; EISENBERG BORIS; HARPE CAROLIN
    权利人:ROHMAX ADDITIVES GMBH
    摘要:The present invention relates to a process for synthesis of polymer compositions with reduced catalyst content, wherein ethylenically unsaturated monomers containing less than 0.5 wt % of ethylenically unsaturated monomers with at least one carboxylic group, sulfonic acid group and/or at least one phosphonic acid group relative to the total weight of the ethylenically unsaturated monomers are polymerized by means of initiators containing a transferable group of atoms and of one or more catalysts comprising at least one transition metal in the presence of ligands which can form a coordination compound with the metal catalyst or catalysts and, after the polymerization, the catalyst contained in the polymer is at least partly separated. For this purpose, the polymer composition is filtered, after the polymerization, in the presence of at least one filter aid which contains at least 0.5 wt %, relative to the total weight of the filter aid, of repeating units that contain at least one carboxylic acid group, sulfonic acid group and/or at least one phosphonic acid group.

    专利号:US-6429329-B1
    优先权日:1995-02-10
    标题:Synthesis of a hydrocarbylvinylphosphonic acid hydrocarbyl ester
    发明人:AARONSON ALAN M; TOMKO JOHN; TELSCHOW JEFFREY E; BOELEE JOHANNES HERMANUS; JAFFE FRED
    权利人:AKZO NOBEL NV
    摘要:A process for the synthesis of a hydrocarbylvinyl-1-phosphonic acid hydrocarbyl ester, such as a 1-phenylvinylphosphonic acid dialkyl ester, which utilizes: (a) the base catalyzed addition (preferably using a nonnucleophilic strong organic base) of a hydrocarbyl phosphite, such as a dialkyl phosphite containing no more than about eight carbon atoms in either of its alkyl groups, to an aldehyde or methyl ketone, such as a phenyl ketone, as exemplified by acetophenone, to form a hydrocarbyl 1-hydroxy-1-hydrocarbylphosphonate, such as a dialkyl 1-hydroxy-1-phenylalkylphosphonate compound; (b) the acid-catalyzed esterification (preferably acetylation) of the compound from (a) with an acid anhydride to form an acylated intermediate; and (c) the removal of carboxylic acid (preferably at a temperature of from about 50° C. to about 215° C. under reduced or atmospheric pressure) from the intermediate from (b) to form the desired hydrocarbylvinylphosphonic acid hydrocarbyl ester, such as a 1-phenylvinylphosphonic acid dialkyl ester.

    专利号:US-11485804-B2
    优先权日:2017-10-17
    标题:Method for the synthesis of fluoropolymers
    发明人:D'APRILE FIORENZA; KAPELYUSHKO VALERIY; KENT BRADLEY LANE; BRINATI GIULIO; PONTA LAURA
    权利人:SOLVAY SPECIALTY POLYMERS IT
    摘要:The present invention relates to a fluorosurfactant-free emulsion polymerization method for the synthesis of a fluoropolymer, more in particular of a VDF-based polymer.

    专利号:US-8785629-B2
    优先权日:2009-06-18
    标题 :Phosphonates synthons for the synthesis of phosphonates derivatives showing better bioavailability
    发明人:AGROFOGLIO LUIGI A; ROY VINCENT; PRADERE UGO
    权利人:AGROFOGLIO LUIGI A; ROY VINCENT; PRADERE UGO; CENTRE NAT RECH SCIENT; UNIV ORLEANS
    摘要:Synthons for the synthesis of phosphonates prodrugs POM and POC, especially for direct Cross Metathesis.

    专利号:US-9403854-B2
    优先权日:2001-03-30
    标 题 :Cross-metathesis reaction of functionalized and substituted olefins using group 8 transition metal carbene complexes as metathesis catalysts
    发明人:GRUBBS ROBERT H; CHATTERJEE ARNAB K; CHOI TAE-LIM; GOLDBERG STEVEN D; LOVE JENNIFER A; MORGAN JOHN P; SANDERS DANIEL P; SCHOLL MATTHIAS; TOSTE F DEAN; TRNKA TINA M
    权利人:CALIFORNIA INST OF TECHN
    摘要:The invention pertains to the use of Group 8 transition metal carbene complexes as catalysts for olefin cross-metathesis reactions. In particular, ruthenium and osmium alkylidene complexes substituted with an N-heterocyclic carbene ligand are used to catalyze cross-metathesis reactions to provide a variety of substituted and functionalized olefins, including phosphonate-substituted olefins, directly halogenated olefins, 1,1,2-trisubstituted olefins, and quaternary allylic olefins. The invention further provides a method for creating functional diversity using the aforementioned complexes to catalyze cross-metathesis reactions of a first olefinic reactant, which may or may not be substituted with a functional group, with each of a plurality of different olefinic reactants, which may or may not be substituted with functional groups, to give a plurality of structurally distinct olefinic products. The methodology of the invention is also useful in facilitating the stereoselective synthesis of 1,2-disubstituted olefins in the cis configuration.
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    主要参考文献

    参考标题:Synthesis Of Carboxylic Acids By Palladium‐catalyzed Hydroxycarbonylation
    作者:Rui Sang,Peter Kucmierczyk,Ricarda Dühren,Rauf Razzaq,Kaiwu Dong,Jie Liu,Robert Franke,Ralf Jackstell,Matthias Beller |发布日期:2019.10
    摘要:Systems, As Well As Terminal Alkenes, Into The Corresponding Carboxylic Acids In Excellent Yields. The Outstanding Stability Of The Catalyst System (26 Recycling Runs In 32 Days Without Measurable Loss Of Activity), Is Showcased In The Preparation Of An Industrially Relevant Fatty Acid. Key-To-Success Is The Use Of A Built-In-Base Ligand Under Acidic Aqueous Conditions. This Catalytic System Is Expected To

    合成参考文献


    摘要:Journal of Agricultural and Food Chemistry., 39(380), 1991
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