CAS: 65202-07-5; Dcpta

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    1,2-Dichloro-4-(2-chloroethoxy)-benzene diethylamine 2-(3,4-dichloro-phenoxy)-ethanol

    合成工艺路线路线简述

      1,2-Dichloro-4-(2-Chloroethoxy)-Benzene,二乙胺置于sodium Hydroxide体系中,用 N-甲基吡咯烷酮 作为反应溶剂,化学反应 0.5H,以91.84%的收率获得产物增产胺
      参考文献:一种增产胺的合成工艺
      标题:一种增产胺的合成工艺
      摘要:本发明公开了一种增产胺的合成工艺,属于精细化工技术领域.所述工艺包括以下步骤:A.将3,4‑二氯苯酚和碱金属氢氧化物溶于极性非质子性溶剂中后,加入1,2‑二卤乙烷,升温后,保温回流0.5~1H,精馏,回收未反应的1,2‑二卤乙烷和部分极性非质子性溶剂,釜底为中间产物和极性非质子性溶剂的混合液;b.向步骤a中得到的中间产物与极性非质子性溶剂的混合液中加入二乙胺,加热回流8~10H后,再加入碱金属氢氧化物,搅拌,然后过滤,将滤液精馏后得到增产胺,本发明通过改变传统的非均相反应为均相反应,降低成本的同时,抑制副反应的发生,提高了产品的收率.

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      专利信息


      专利号:US-11326192-B2
      优先权日:2017-07-18
      标 题:Variant of oleaginous yeast and its use for the production of lipids
      发明人:RODIGHIERO VALENTINA; FRANZOSI GIULIANA; COMPAGNO CONCETTA; CAPUSONI CLAUDIA
      权利人:VERSALIS SPA
      摘要:The present invention relates to a variant of oleaginous yeast of the species Trichosporon oleaginosus characterized by mutations affecting cell wall synthesis that change the morphology thereof with respect to the wild-type strain of the same species. In particular, thanks to said mutations, cell aggregates are formed which, with respect to the wild-type strain of the same species, lower the viscosity of the culture broth, are more easily separable therefrom and thus make their recovery easier. Said variant of oleaginous yeast of the species Trichosporon oleaginosus is also characterized by yields of oleaginous cellular biomass and intracellular accumulation of lipids that are similar or even higher than those of the wild-type strain. Further, the present invention relates to a process for the production of lipids through said variant of oleaginous yeast of the species Trichosporon oleaginosus . The lipids thus obtained can be advantageously used as synthesis intermediates, particularly in the so-called “green chemistryâ€? sector, or in the production of biofuels such as, for example, “biodieselâ€? or “green dieselâ€?, which can be used as such, or mixed with other fuel for transportation.

      专利号:US-11041178-B2
      优先权日:2017-10-30
      标题 :Process for the production of sugars from biomass derived for guayule plants
      发明人:BATTISTEL EZIO; VIOLA EGIDIO; DE CORATO UGO; BRACCIO GIACOBBE; VITO VALERIO
      权利人:VERSALIS SPA
      摘要:Process for the production of sugars from biomass derived from guayule plants comprising: subjecting said biomass to a biological pretreatment in the presence of at least one ligninolytic fungus obtaining a liquid phase comprising sugars and a first solid residue: subjecting said first solid residue to hydrolysis in the presence of at least one diluted inorganic acid obtaining a first hydrolysate comprising sugars and a second solid residue; subjecting said second solid residue to enzymatic hydrolysis obtaining a second hydrolysate comprising sugars and a third solid residue. The sugars thus obtained can be advantageously used as sources of carbon in fermentation processes for producing alcohols (e.g., ethanol, butanol), lipids, diols (e.g., 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 2,3-butanediol), or in chemical synthesis processes for producing other intermediates or chemical products (e.g., furfural). Said alcohols and lipids can be advantageously used in turn in the production of biofuels (e.g., biodiesel or “green dieselâ€?), which can be used as such, or mixed with other fuels for transportation, while said diols can be used in the production of products such as bio-butadiene which can in turn be used for manufacturing rubbers (e.g., polybutadiene or copolymers thereof). Said uses are particularly important in the case of a biorefinery.

      专利号:CN-114213468-A
      优先权日:2022-01-11
      标题 :A kind of metal iridium complex and its application in the synthesis of increased production amine

      专利号:US-6998471-B2
      优先权日:2001-07-25
      标题:Polynucleotides encoding an acetyl-CoA acetyltransferase from Hevea brasiliensis, related products, and methods
      发明人:HALLAHAN DAVID L; KEIPER-HRYNKO NATALIE M
      权利人:DU PONT
      摘要:The instant invention relates to bioproduction of isopentenyl diphosphate within the latex of the rubber tree, Hevea brasiliensis . Isopentenyl diphosphate (IPP) synthesis from acetate is mediated by a set of enzymes, acetyl-coA acetyltransferase, HMG-coA synthase, HMG-coA reductase, mevalonate kinase, phosphomevalonate kinase and mevalonate diphosphate decarboxylase, encoded by six genes isolated as expressed sequence tag (EST) cDNAs from Hevea brasiliensis latex. In addition, a variant sequence of one of these enzymes, acetyl-coA acetyltransferase, has been found.

      专利号:CN-119241376-A
      优先权日:2024-09-25
      标题 :Continuous synthesis method of yield-increasing amine
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      合成参考文献


      参考文献:10.1007/978-3-642-68204-9_17
      摘要:Nickell LG. Metabolic Effects, Ripening, and Yield Increases. 1982. In: Plant Growth Regulators.
      参考文献:10.1007/s11105-023-01373-x
      摘要:Santos MC, da Silva Soares JM, de Jesus Rocha A, dos Santos Oliveira WD, de Souza Ramos AP, Amorim EP, dos Santos-Serejo JA, Ferreira CF. Correlation Between Gene Expression and Antioxidant Enzyme Activity in Plants Tolerant to Water Stress: A Systematic Review. Plant Mol Biol Rep. 2023 Apr 21;41(3):512–25. doi: 10.1007/s11105-023-01373-x.
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