CAS: 865-44-1; Iodine Trichloride

该化合物是一种化学化合物,其特点是在室温下以深褐色至黑色固态外观为特征,是一种由碘和氯组成的共价化合物,具有三角双极分子几何特征,已知三氯化碘具有很强的氧化特性,可以与消毒剂发生强烈反应,在有机溶剂中溶解,可在水中进行水解,产生盐酸和碘.该化合物在有机合成中具有应用性,特别是在制造碘化合物时.ICl3还被用于分析化学中检测某些物质.由于它具有反应性,因此应谨慎处理它,因为它能够刺激皮肤,眼睛和呼吸系统.适当的安全措施,包括使用个人防护设备,在与该物质合作时至关重要.

结构式图片

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CAS号7553-56-2 碘 | CAS号7782-50-5 氯气 | CAS号7790-99-0 一氯化碘 | CAS号10025-85-1 氯化氮 | CAS号7647-01-0 盐酸 | CAS号7782-68-5 碘酸 | CAS号13446-76-9 碘酸铷 | CAS号7791-25-5 磺酰氯 | CAS号12029-98-0 五氧化二碘 | CAS号13536-50-0 tin(IV) bromide... | CAS号7646-78-8 四氯化锡 | CAS号75-44-5 光气 | CAS号7782-50-5 氯气 | CAS号7790-99-0 一氯化碘 | CAS号7782-68-5 碘酸 | CAS号7647-01-0 盐酸 | CAS号10034-85-2 氢碘酸 | CAS号7553-56-2 碘 | CAS号7757-82-6 元明粉

合成工艺路线路线简述

    磺酰氯置于碘体系中,用 Not Given 作为反应溶剂,化学反应生成 三氯化碘
    参考文献:乙腈中硫酰氯与元素的反应性
    标题:乙腈中硫酰氯与元素的反应性
    摘要:与单独的so 2 Cl 2相比,Mecn中的硫酰氯与除最难熔的元素外的所有元素发生反应,从而主要反应生成溶剂化的氯化物,而单独的so 2 Cl 2至少需要该温度的两倍.有证据表明存在基于类比,热化学,传输测量和加成效应的离子机理.描述了导致聚合的这些溶液的不稳定性及其抑制作用.反应中形成的二氧化硫除了影响混合价tl 4 Cl 6的形成外,很少起还原作用..在不同溶剂中的半定量动力学测量结果强调了mecn的独特性.对于大多数元素而言,侵蚀是通过控制在整个表面膜上的扩散来实现的,从而对时间呈抛物线依赖性,如果通过改变溶剂混合物来防止膜的生长,可以线性化时间.这些表面膜的不同性质消除了速率和周期性之间的任何简单关系.指出了一些应用.
    DOI:10.1039/dt9910003325

    专利信息


    专利号:US-8933181-B2
    优先权日:2006-10-06
    标题:Branched polymers and methods for their synthesis and use
    发明人:MOURI HIROSHI; LUO STEVEN; KURASCH JESSICA; ROBERTSON CHRISTOPHER G; WARREN SANDRA
    权利人:MOURI HIROSHI; LUO STEVEN; KURASCH JESSICA; ROBERTSON CHRISTOPHER G; WARREN SANDRA; BRIDGESTONE CORP
    摘要:Branched polymers including multi-branched polymers, functionalized branched polymers, star-branched polymers, and dendigraft polymers. Methods for the synthesis of branched polymers and method for the use of branched polymers in tire components are also included.

    专利号:US-9157156-B2
    优先权日:2009-07-07
    标题 :Process for the preparation of a iodinating agent
    发明人:ANELLI PIER LUCIO; VISCARDI CARLO FELICE; DELOGU PIETRO; GOFFREDI FABRIZIO; NARDELLI ALFONSO; GIOVENZANA GIOVANNI BATTISTA
    权利人:ANELLI PIER LUCIO; VISCARDI CARLO FELICE; DELOGU PIETRO; GOFFREDI FABRIZIO; NARDELLI ALFONSO; GIOVENZANA GIOVANNI BATTISTA; BRACCO IMAGING SPA
    摘要:The present invention describes a process for the synthesis of a iodinating agent, being said iodinating agent iodine chloride (ICI.) In particular, the present invention relates to a process for the electrochemical preparation of ICI, as a useful iodinating agent in the preparation of iodinated organic compounds for use as contrast agents or their precursors in the synthesis of the same.

    专利号:US-2005020616-A1
    优先权日:2003-07-21
    标 题 :Aryl fused azapolycyclic compounds
    发明人:COE JOTHAM W; O'DONNELL CHRISTOPHER J
    权利人:PFIZER
    摘要:This invention is directed to compounds of the formula (I): n n nand their pharmaceutically acceptable salts, wherein R 1 , R 2 , R 3 and Z are as defined herein; intermediates for the synthesis of such compounds, pharmaceutical compositions containing such compounds; and methods of using such compounds in the treatment of neurological and psychological disorders.

    专利号:US-7205300-B2
    优先权日:1997-12-31
    标 题:Aryl fused azapolycyclic compounds
    发明人:COE JOTHAM WADSWORTH; BROOKS PAIGE ROANNE PALMER
    权利人:PFIZER
    摘要:This invention is directed to compounds of the formula (I): n nand their pharmaceutically acceptable salts, wherein R 1 , R 2 , and R 3 are as defined herein; intermediates for the synthesis of such compounds, pharmaceutical compositions containing such compounds; and methods of using such compounds in the treatment of neurological and psychological disorders.

    专利号:US-11767388-B1
    优先权日:2019-09-18
    标 题 :Silicon-functionalized rubber
    发明人:ENSIGN SETH CODY; VIELHABER MARGARET FLOOK; JOHNGRASS JENA LYNN; MA LIQING
    权利人:GOODYEAR TIRE & RUBBER
    摘要:The compatibility between silica fillers and synthetic rubbers which are synthesized utilizing lanthanide-based catalyst systems, such as neodymium catalyst systems can be improved by terminating the polymerization with a vinyl silane terminating agent. In doing so the vinyl silane is allowed to react with the polymer chain ends of the neodymium rubber to functionalize the chain ends of the polymer chains with silicon containing groups. This results in the rubber having better characteristics for utilization in tire rubber formulations, such a tire tread formulations, that exhibit improved wear characteristics and lower rolling resistance. The process for the synthesis of such functionalized polydiene rubber comprises (1) polymerizing a diene monomer in the presence of a lanthanide-based catalyst system, and (2) terminating the polymerization with a vinyl silane terminator. The functionalized polydiene rubber composition made by this method is comprised of a polydiene rubber which is functionalized at its chain ends with a silicon containing group.

    专利号:US-7122534-B2
    优先权日:1998-04-29
    标 题:Aryl fused azapolycyclic compounds
    发明人:COE JOTHAM WADSWORTH
    权利人:PFIZER
    摘要:The present invention relates to compounds of formula (I) n n nand their pharmaceutically acceptable salts, wherein R 1 , R 2 , R 3 and Z are as defined herein, intermediates in the synthesis of such compounds, pharmaceutical compositions containing such compounds and methods of using such compounds in the treatment of neurological and psychological disorders.
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    合成参考文献


    摘要:Hartung, J., Science of Synthesis, (2007) 35, 29.
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