5,11,17,23-Tetratert-Butyl-4,12,16,24-Tetrahydroxycalix[4]Arene Ethanol Complex 反应生成2,2'-亚甲基双-(4-甲基-6-叔丁基苯酚) 参考文献:About Selective Methods Of Synthesis Of 6-Tert-Butyl-2-Methylphenol And 6-Tert-Butyl-2,4-Dimethylphenol 标题:About Selective Methods Of Synthesis Of 6-Tert-Butyl-2-Methylphenol And 6-Tert-Butyl-2,4-Dimethylphenol 摘要:Vapor Phase Catalytic Methylation With Methanol Of 2-Tert-Butylphenol At The Temperature 280-300A Degrees C Proceeds Selectively With Formation Of 6-Tert-Butyl-2-Methylphenol. Elevating Reaction Temperature Above 300A Degrees C Leads To Formation Of 2,6-Dimethylphenol. Reaction Of 2-Tert-Butylphenol With Methanol In Alkaline Medium In The Presence Of Zinc Oxide Is Shown To Lead Initially To Formation Of A Mixture Of Calixarenes And Methylenebisphenols That At Elevated Temperature Exert Splitting Leading In Future To 6-Tert-Butyl-2,4-Dimethylphenol. Obtaining It In This Reaction From 2,2'-Methylenebis-(6-Tert-Butyl-4-Methylphenol) Proceeds Selectively. Pathways Of The Reductive Methylation Of Methylenebisphenols With Methanol In Alkaline Medium Is Considered. Doi:10.1134/s1070363209060218
专利号:WO-2009018504-A1 优先权日:2007-08-01 标题 :Process for the synthesis of diaminopyridine and related compounds 发明人:RITTER JOACHIM C 权利人:DU PONT; RITTER JOACHIM C 摘要:A process is provided for the synthesis of a diaminopyridine, such as 2,6-diaminopyridine and related compounds, which are used industrially as compounds and as components in the synthesis of a variety of useful materials. The synthesis proceeds by means of a chlorine-ammonia displacement in the presence of a copper source.
专利号:US-8084569-B2 优先权日:2006-12-21 标 题 :Process for the synthesis of diaminopyridines from glutarimidines 发明人:MINTER AARON; STOKES BERLIN 权利人:MINTER AARON; STOKES BERLIN; DU PONT 摘要:A liquid-phase process is provided for the synthesis from glutarimidines of diaminopyridines and related compounds, which are used industrially as compounds and as components in the synthesis of a variety of useful materials. The synthesis proceeds by means of a dehydrogenative aromatization process.
专利号:US-7999057-B2 优先权日:2008-07-08 标 题:Gas-phase process for the synthesis of diaminopyridines from glutaronitriles 发明人:HUTCHENSON KEITH W; MINTER AARON; SUNSHINE GREGG 权利人:DU PONT 摘要:A gas-phase, continuous process is provided for the manufacture of 2,6-diaminopyridine and related compounds from glutaronitriles, which are used industrially as compounds and as components in the synthesis of a variety of useful materials. The synthesis proceeds by means of a dehydrogenative aromatization process.
专利号:US-2011301314-A1 优先权日:2008-12-18 标题:Continuous liquid-phase process for the synthesis of diaminopyridines from glutaronitriles 发明人:HUTCHENSON KEITH W; MINTER AARON 权利人:HUTCHENSON KEITH W; MINTER AARON; DU PONT 摘要:A liquid-phase, continuous process is provided for the manufacture of 2,6-diaminopyridine and related compounds from glutaronitriles, which are used industrially as compounds and as components in the synthesis of a variety of useful materials. The synthesis proceeds by means of a dehydrogenative aromatization process.
专利号:EP-0062322-A1 优先权日:1981-04-03 标 题 :Improved process for synthesis of hindered amine stabilizers for polymeric materials 发明人:LAI JOHN TA-YUAN 权利人:GOODRICH CO B F 摘要:Process for the synthesis of hindered polysubstituted α-amino acetamides by reaction of a secondary amine with an α-halo acetamide in a basic organic reaction medium and in the presence of a phase transfer catalyst. The product thus obtained can comprise a multifunctional compound having one or more hindered amino moieties. These compounds are highly effective as UV stabilizers in a variety of plastics, especially the alpha monoolefins.
专利号:US-6909010-B2 优先权日:2001-04-11 标题:Facile synthesis of symmetric esters of alkylenebisphosphonic acids 发明人:HERLINGER ALBERT W; STEPINSKI DOMINIQUE C 权利人:UNIV LOYOLA CHICAGO 摘要:A facile synthesis of symmetric esters of C 1 -C 10 alkylenebisphopsphonic acids is disclosed in which a C 1 -C 10 alkylenebis(phosphonic dichloride) is reacted with an alcohol in the presence of a catalytic amount of 1H-tetrazole and a base in an aprotic solvent to form a first reaction mixture. The first reaction mixture is maintained for a time period sufficient to form a C 1 -C 10 alkylenebis(chloro ester phosphonate) that is reacted under basic conditions with an excess of a hydroxylated compound to form a second reaction mixture that is itself maintained for a time period sufficient to form a C 1 -C 10 alkylenebis(ester phosphonate) partial ester, homoleptic tetraester or mixed tetraester. The material so formed can be recovered or used as is.
1: Johari-Ahar M, Karami P, Ghanei M, Afkhami A, Bagheri H. Development of a molecularly imprinted polymer tailored on disposable screen-printed electrodes for dual detection of EGFR and VEGF using nano-liposomal amplification strategy. Biosens Bioelectron. 2018 Feb 3;107:26-33. doi: 10.1016/j.bios.2018.02.005. [Epub ahead of print] doi: 10.18632/oncotarget.22858. eCollection 2017 Dec 29. 3: Joshi A, Nandi S, Chester D, Brown AC, Muller M. Study of Poly(N-isopropylacrylamide-co-acrylic acid) (pNIPAM) Microgel Particle Induced Deformations of Tissue-Mimicking Phantom by Ultrasound Stimulation. Langmuir. 2018 Jan 30;34(4):1457-1465. doi: 10.1021/acs.langmuir.7b02801. Epub 2018 Jan 9. doi: 10.1021/acs.est.7b05057. Epub 2017 Dec 28. doi: 10.1016/j.toxlet.2017.11.028. Epub 2017 Nov 24. 6: Liu M, Gao K, Fan Y, Guo X, Wu J, Meng X, Hou H. Co-Cluster-Based Metal-Organic Frameworks as Selective Catalysts for Benzene Tandem Acylation-Nazarov Cyclization to Benzocyclopentanone. Chemistry. 2018 Jan 26;24(6):1416-1424. doi: 10.1002/chem.201704749. Epub 2017 Dec 18. doi: 10.1016/j.scitotenv.2017.09.084. Epub 2017 Oct 4. doi: 10.1002/jbm.a.36240. Epub 2017 Oct 11. doi: 10.1039/c7fo00376e. doi: 10.1016/j.talanta.2017.06.035. Epub 2017 Jun 16. doi: 10.1371/journal.pone.0175364. eCollection 2017.
合成参考文献
摘要:Journal of Toxicological Sciences., 19(77), 1994 [] 摘要:Ashford RD; Ashford's Dictionary of Industrial Chemicals: Properties, Production, Uses. London, England: Wavelength Publ, Ltd (1994) 摘要:AMER CYANAMID CO; Reports on Toxicological Information of Cyagard RF-1 & Pyroset TKO; 08/28/80; EPA Doc No. 88-8000369; Fiche No. OTS0204880 摘要:Franke C et al; Chemosphere 29: 1501-14 (1994) 摘要:S13 | EUCOSMETICS | Combined Inventory of Ingredients Employed in Cosmetic Products (2000) and Revised Inventory (2006) | DOI:10.5281/zenodo.2624118