CAS: 95266-40-3; Trinexapac-Ethyl

该化合物是一个合成植物生长调节器,主要用于农业,特别是地盘管理和谷物作物;它作为肝素生物合成抑制剂,有效减少干量延缓,促进草地上较稠密的生长习惯;该化合物的特点是能够保持紧凑生长形式,提高地盘的美观,保持紧凑生长形式,特别有利于高尔夫球场和体育场;Trinnaxapac-乙基通常用作花岗喷雾,以其对非目标生物的毒性相对较低而著称,使地盘管理人员选择它为首选;其行动方式是抑制肝素途径中涉及的具体酶,导致减少隔热长度;此外,它具有有利的环境特征,土壤持久性较低,渗入地下水的风险最小;

结构式图片

欧盟法规

[ECHA物质欧盟农药活性物质

上下游产品

diethyl 2-acetylmethyl-1,4-butanedioate cyclopropanecarboxylic acid chloride

合成工艺路线路线简述

  • 4023-34-1 + 504-02-9 = 95266-40-3
    反应条件:1.1 Reagents: Sodium Hydride Solvents: Dichloromethane; 0 °C; 2 - 3 H,0 °C1.2 Catalysts: 1,8-Diazabicyclo[5.4.0]Undec-7-Ene; 4 - 5 H,2 Atm,100 °C1.3 Ph 3 - 41.4 Catalysts: Sulfuric Acid Solvents: Water; Rt
    标题:Preparation Of Trinexapac-Ethyl
    参考文献:China]

    486447-23-8 = 95266-40-3
    反应条件:1.1 Solvents: Water; Ph 7
    标题:Acylcyclohexanedione Derivatives As Potential In Vivo Sequential Inhibitors Of 4-Hydroxyphenylpyruvate Dioxygenase And Ga20 3β-Hydroxylase
    作者:Huang,Jian-Lin; Liu,Hun-Ge; Yang,Ding-Yah
    参考文献:Bioorganic & Medicinal Chemistry Letters 日期:2003 卷标:13(5) 页码:927-930]

    104273-62-3 = 95266-40-3
    反应条件:1.1 Reagents: Triethylamine Catalysts: 1-Butanaminium,N,N,N-Tributyl-,Azide (1:1) Solvents: Chloroform,Water; 25 °C1.2 Reagents: Hydrochloric Acid; Ph 3
    标题:Method For Preparing Cyclohexane Triketone Compounds
    参考文献:World Intellectual Property Organization]

    4023-34-1 + 1187-74-2 = 95266-40-3
    反应条件:1.1 Reagents: Sodium Methoxide Solvents: Toluene; 50 °C; 1 H,50 °C1.2 Reagents: N,N-Dimethylaniline Solvents: Methanol; 0 - 10 °C; 5 H,0 - 10 °C1.3 Reagents: Water; 30 Min
    标题:Process For Preparation Of Plant Growth Regulator Trinexapac Intermediate
    参考文献:China]

    4023-34-1 + 88805-65-6 = 95266-40-3
    反应条件:1.1 Reagents: Triethylamine Solvents: 1,2-Dichloroethane; Cooled; Overnight,Rt1.2 Reagents: 4-(Dimethylamino)Pyridine Solvents: 1,2-Dichloroethane; 5 H,Reflux
    标题:Synthesis Of Trinexapac-Ethyl
    作者:Gao,Min; Wang,Xiaozhong; Dai,Liyan; Chen,Yingqi
    参考文献:Nongyao 日期:2006 卷标:45(8) 页码:535-536]

    95266-40-3 = 95266-40-3
    反应条件:1.1 Reagents: Cupric Acetate Solvents: Ethanol; Rt -> -5 °C; 3 H,-5 °C
    标题:Production Method And Recovery Method For Ethyl 4-Cyclopropyl (Hydroxy) Methylene-3,5-Diketocyclohexanecarboxylate
    参考文献:China]

    1759-53-1 + 27513-35-5 = 95266-40-3
    反应条件:1.1 Reagents: Phosphorus Trichloride Solvents: N,N-Dimethylaniline; Cooled1.2 Catalysts: 4-(Dimethylamino)Pyridine; 4 H,60 °C1.3 Reagents: Water; Ph 5 - 6
    标题:Process For Preparation Of Trinexapac-Ethyl
    参考文献:China]

    199446-36-1 = 95266-40-3
    反应条件:1.1 Reagents: Dimethylformamide,Triethylamine Catalysts: Sodium Azide Solvents: Toluene; 4 H,90 °C; 90 °C -> Rt1.2 Reagents: Hydrochloric Acid Solvents: Water; Ph 3 - 4
    标题:Study On Synthesis Of Trinexapac-Ethyl
    作者:Zhu,Chang-Song; Huang,Bin; Liu,Jun-Jie; Yang,Jun; Ji,Jian-Fei; Et Al
    参考文献:Jingxi Yu Zhuanyong Huaxuepin 日期:2011 卷标:19(8) 页码:11-13]

    27513-35-5 + 33993-24-7 = 95266-40-3
    反应条件:1.1 Reagents: Sodium Methoxide Solvents: Methanol; Reflux; 2 H,Reflux1.2 2.5 H,Reflux1.3 Reagents: Hydrochloric Acid Solvents: Water; Ph 1 - 2,Cooled
    标题:Process For Preparation Of Trinexapac-Ethyl
    参考文献:China]

    4023-34-1 + 88805-65-6 = 95266-40-3
    反应条件:1.1 Reagents: Triethylamine Solvents: 1,2-Dichloroethane; Cooled; 30 °C; 15 H,30 °C1.2 Catalysts: Sodium Ethoxide Solvents: 1,2-Dichloroethane; 5 H,Reflux1.3 Reagents: Hydrochloric Acid Solvents: Water; Acidified
    标题:Synthesis Of Trinexapac-Ethyl
    作者:Tian,Shuai; Gao,Zhongliang; Xie,Zhendong
    参考文献:Huaxue Shijie 日期:2018 卷标:59(11) 页码:749-753]

    4023-34-1 + 27513-35-5 = 95266-40-3
    反应条件:1.1 Reagents: Triethylamine Solvents: Toluene; 0 - 15 °C; 1 - 5 H,0 - 15 °C1.2 Reagents: Ethanedinitrile Solvents: Acetone; 15 °C -> 90 °C; 90 - 95 °C; 95 °C -> 30 °C1.3 Reagents: Hydrochloric Acid Solvents: Water; Ph 1 - 2,15 - 30 °C
    标题:Method For Preparing High-Content Trinexapac-Ethyl
    参考文献:China]

    199446-36-1 = 95266-40-3
    反应条件:1.1 Reagents: Triethylamine,Potassium Cyanide Solvents: Dimethylformamide,Toluene; Rt -> 90 °C; 4 H,80 - 90 °C; 90 °C -> Rt1.2 Reagents: Hydrochloric Acid Solvents: Water; Ph 3 - 4,Rt
    标题:Process For Preparation Of Plant Growth Regulator Trinexapac-Ethyl
    参考文献:China]

    = 95266-40-3 [标题:Reaction Conditions
    标题:Preparation Of Cyclohexanedionecarboxylic Acid Derivatives As Herbicides And Plant Growth Regulators
    参考文献:United States]

    = 95266-40-3 [标题:Reaction Conditions
    标题:Preparation Of Inactivated Viral Vaccines Using Furocoumarins And Long Wavelength Uv Irradiation,Under A Non-Oxidizing Atmosphere
    参考文献:United States]

    = 95266-40-3 [标题:Reaction Conditions
    标题:Cyclohexanedionecarboxylic Acid Derivatives Having A Herbicidal And Plant Growth Regulating Activity
    参考文献:European Patent Organization

海关参考信息

专利信息


专利号:WO-2025056767-A1
优先权日:2023-09-15
标题 :Process for the preparation of enantiomerically enriched aliphatic amines
发明人:BOU HAMDAN FARHAN; GODINEAU EDOUARD; SMEJKAL TOMAS; DUMEUNIER RAPHAEL; BOUSSEMGHOUNE MOHAMED ABDELOUAHAB; BLUM MATHIAS
权利人:SYNGENTA CROP PROTECTION AG
摘要:The present invention relates to a process for the preparation of enantiomerically enriched cyclobutylamines of formula (I) from α-tertiary cyclobutanones and reacting said enantiomerically enriched cyclobutylamines to enantiomerically enriched cyclobutylamides. Such compounds are useful intermediates in the synthesis of microbiocidal thiazole compounds.

专利号:US-11919928-B2
优先权日:2016-03-16
标题 :Method for producing dihydrotentoxin
发明人:KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI
权利人:KUMIAI CHEMICAL INDUSTRY CO
摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.

专利号:US-2008254993-A1
优先权日:2007-01-31
标题:Use of abscisic acid analogs to enhance growth control
发明人:LIU XIAOZHONG; PETRACEK PETER D; HEIMAN DANIEL F; BEACH MARK; WARRIOR PREM
权利人:LIU XIAOZHONG; PETRACEK PETER D; HEIMAN DANIEL F; BEACH MARK; WARRIOR PREM
摘要:This invention describes the use of analogs or derivatives of abscisic acid or their salts in combination with gibberellin biosynthesis inhibitors to improve the performance of gibberellin synthesis inhibitors, and to increase water conservation in plants such as turfgrass.

专利号:WO-2019218027-A1
优先权日:2018-05-18
标题:Core-shell particles
发明人:MEANEY SHANE; TABOR RICHARD; FOLLINK BART
权利人:UNIV MONASH
摘要:The application relates to a core-shell particle having a) a cross-linked polyelectrolyte core, and b) a silica-based shell having covalently bound thereto one or more groups of formula –R–F, wherein R is an organic group and F is a functional moiety. The application also relates to a method of synthesis of a core-shell particle, the method comprising the steps of: a) providing a cross-linked polyelectrolyte core template, b) coating the core template with a silica-based shell, and c) introducing one or more groups of formula –R–F covalently bound to the silica-based shell, wherein R is an organic group and F is a functional moiety.

专利号:US-2011230343-A1
优先权日:2008-10-24
标题 :Method for the Manufacture of Microparticles Comprising an Effect Substance
发明人:SCHROERS MICHAEL; DYLLICK-BRENZINGER RAINER; MERK MICHAEL; BARG HEIKO
权利人:BASF SE
摘要:A subject matter of the present invention is a process for the preparation of effect compound-comprising microparticles M comprising A) the formation of a crude suspension of microparticles A by means of enzymatic polyester synthesis in an inverse miniemulsion comprising enzyme, effect compound and polyester monomers; and B) the polymerization of wall monomers from the group consisting of ethylenically unsaturated monomers, polyisocyanates and polyepoxides in the crude suspension of microparticles A. Furthermore, the present invention relates to microparticles M which can be obtained by means of the process according to the invention and also to an agrochemical formulation comprising microparticles M. In addition, the present invention relates to the use of microparticles M prepared according to the invention as component in colorants, cosmetics, drugs, biocides, plant protection agents, fertilizers, additives for food or animal fodder, or auxiliaries for polymers, paper, textiles, leather, detergents or cleaners. Finally, the invention also relates to a method for combating undesirable plant growth, to a method for combating undesirable insect or acarid infestation on plants and/or for combating phytopathogenic fungi, and to seeds treated with the agrochemical formulation.

专利号:US-11213031-B2
优先权日:2017-11-13
标 题:Tetrazolylpropyl derivatives and their use as fungicides
发明人:SUDAU ALEXANDER; HOFFMANN SEBASTIAN; DAHMEN PETER; WEBSTER ROBERT ALAN; MEISSNER RUTH; GOERTZ ANDREAS; MILLER RICARDA; COQUERON PIERRE-YVES; BERNIER DAVID; NICOLAS LIONEL; BRUNET STEPHANE; KENNEL PHILIPPE; TOQUIN VALERIE; GOURGUES MATHIEU; LOQUE DOMINIQUE; THOMAS VINCENT
权利人:BAYER AG; BAYER CROPSCIENCE AG
摘要:The present invention relates to tetrazolylpropyl derivatives of formula (I) n nwherein one of V 1 and V 2 represents CR 3 and the other one of V 1 and V 2 represents N, Q represents a 6-membered aromatic cycle as defined in the specification, and R 1 , R 2 , R 3 , R 4 , and R 5 are defined as disclosed in the specification, to compositions comprising such compounds, to the use of said compounds as fungicides, as well as to particular intermediates useful in the synthesis of said tetrazolylpropyl derivatives.
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地址:江苏省常州市金坛区洮西工业园
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合成参考文献


摘要:Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan., 22(351), 1997
摘要:Pesticide Manual., 9(351), 1991
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