CAS: 27676-62-6; 1,3,5-Tris(3,5-Di-Tert-Butyl-4-Hydroxybenzyl)-1,3,5-Triazinane-2,4,6-Trione

该化合物是一种高性能的苯酚抗氧化剂,广泛用于聚合物稳定,其分子结构有三个阻塞的酚组与异氰尿核相关,提供了极好的热稳定性和氧化稳定性,有效抑制了多醇芬,弹性体和暴露于高温或紫外辐射的其他聚合物的降解,主要优势包括低挥发性,长期耐久性,以及与其他稳定剂结合时的协同效应.其高分子重量可确保最小的迁移和提取,使之适合汽车部件和隔热线等要求应用.该产品与广泛的加工方法兼容,包括外壳和注射模具.

结构式图片

上下游产品

formaldehyd cyanuric acid 2,6-di-tert-butylphenol

合成工艺路线路线简述

  • 合成目标产物 Antioxidant3114 主要起始原料 Formaldehyde And Cyanuric Acid And 2,6-Di-Tert-Butylphenol
  • (文献来源)合成步骤主要原料 Formaldehyde 和 Cyanuric Acid 和 2,6-Di-Tert-Butylphenol
氰尿酸,2,6-二叔丁基-4-溴甲基苯酚置于六甲基磷酰三胺,Sodium Hydride体系中,用87.4 %的收率获得抗氧剂 3114
参考文献:Cn117186019
标题:Cn117186019

专利信息


专利号:EP-0062322-A1
优先权日:1981-04-03
标 题 :Improved process for synthesis of hindered amine stabilizers for polymeric materials
发明人:LAI JOHN TA-YUAN
权利人:GOODRICH CO B F
摘要:Process for the synthesis of hindered polysubstituted α-amino acetamides by reaction of a secondary amine with an α-halo acetamide in a basic organic reaction medium and in the presence of a phase transfer catalyst. The product thus obtained can comprise a multifunctional compound having one or more hindered amino moieties. These compounds are highly effective as UV stabilizers in a variety of plastics, especially the alpha monoolefins.

专利号:US-2009318592-A1
优先权日:2005-10-11
标 题 :Process for the Synthesis of Amine Ethers
发明人:FREY MARKUS; BROENNIMANN VALERIE
权利人:CIBA GEIGY CORP
摘要:The present invention relates to novel processes for the preparation of a sterically hindered amine ether by reacting a corresponding sterically hindered amine oxide with a ketone or an aldehyde with at least one reactive H in the presence of a peroxydisulphate. Products obtained by this process may be hydrogenated. The compounds made by these processes are particularly effective in the stabilization of polymer compositions against harmful effects of light, oxygen and/or heat and as flame-retardants for polymers.

专利号:US-2007191516-A1
优先权日:2004-03-15
标题 :Process for the synthesis of amine ethers
发明人:FREY MARKUS; RAST VALERIE; BRAIG ADALBERT; KRAMER ANDREAS
权利人:FREY MARKUS; RAST VALERIE; BRAIG ADALBERT; KRAMER ANDREAS
摘要:A process for the preparation of a sterically hindered amine ether which comprises reacting a corresponding sterically hindered aminoxide with a C 5 -C 18 alk-1-ene in the presence of an organic hydroperoxide and optionally hydrogenating the resulting product as well as the product mixtures obtained therewith and their use as stabilizers and flame retardants.

专利号:US-7803959-B2
优先权日:2006-04-05
标 题 :Synthesis of aromatic silicon-containing compounds
发明人:COGGAN JENNIFER A; BENDER TIMOTHY P; TOTH ALAN EDWARD JOHN
权利人:XEROX CORP
摘要:Methods are provided for preparing aromatic silicon-containing compounds. The methods include providing an aromatic starting material; reacting the aromatic starting material with a base to form an aromatic salt; and reacting the aromatic salt with a halo-alkylene-silane to form an aromatic silicon-containing compound. Compositions prepared by these methods, protective layers that include hydrolysis and condensation products of such compositions, electrophotographic photoreceptors that include such protective layers, and image forming apparatuses that include such electrophotographic photoreceptors are also provided. In addition, method for preparing electrophotographic photoreceptors that include protective layers including hydrolysis and condensation products of aromatic silicon-containing compounds prepared by the methods for preparing aromatic silicon-containing compounds are provided.

专利号:US-7402675-B2
优先权日:2000-05-26
标题 :Process for the synthesis of amine ethers from secondary amino oxides
发明人:HAFNER ANDREAS; KIRNER HANS JUERG; SCHWARZENBACH FRANZ; VAN DER SCHAAF PAUL ADRIAAN; NESVADBA PETER
权利人:CIBA SC HOLDING AG
摘要:An amine ether of formula A n nwherein a is 1 or 2; and when a is 1, E is E′; when a is 2, E is L;n E′ is C 1 -C 36 alkyl; C 3 -C 18 alkenyl; C 2 -C 18 alkinyl; C 5 -C 18 cycloalkyl; C 5 -C 18 cycloalkenyl; a radical of a saturated or unsaturated aliphatic bicyclic or tricyclic hydrocarbon of 7 to 12 carbon atoms; C 2 -C 7 alkyl or C 3 -C 7 alkenyl substituted by halogen; C 7 -C 15 aralkyl or C 7 -C 15 aralkyl substituted by C 1 -C 4 alkyl or phenyl; or E′ is a radical of formula (VII) as explained in claim 1; T′ is tertiary C 4 -C 18 alkyl or phenyl, each of which are unsubstituted or substituted by halogen, OH, COOR 21 or C(O)—R 22 ; or T′ is C 5 -C 12 cycloalkyl; C 5 -C 12 cycloalkyl which is interrupted by at least one O or —NR 18 —; a polycyclic alkyl radical having 7-18 carbon atoms, or the same radical which is interrupted by at least one O or —NR 18 —; or T′ is —C(G 1 )(G 2 )-T″; or C 1 -C 18 alkyl or C 5 -C 12 cycloalkyl substituted by n n n n n n n n n n n n T″ is hydrogen, halogen, NO 2 , cyano, or is a monovalent organic radical comprising 1-50 carbon atoms; n or T″ and T′ together form a divalent organic linking group completing, together with the hindered amine nitrogen atom and the quaternary carbon atom substituted by G 1 and G 2 , an optionally substituted five- or six-membered ring structure; and all other residues are as defined in claim 1, n are obtained in good yield from the corresponding N-oxyl hindered amine precursor by reaction with a hydrocarbon E 1 -H or H-L-H in the presence of an organic hydroperoxide and a catalytic amount of copper or a copper compound. n n n n n The products of present process find utility as polymerization regulators and/or light stabilizers for organic material.

专利号:US-4473694-A
优先权日:1981-04-03
标 题:Process for the preparation of polysubstituted α-aminoacetamides
发明人:LAI JOHN T
权利人:GOODRICH CO B F
摘要:Process for the synthesis of hindered polysubstituted alpha -amino acetamides which comprises first reacting an alpha -haloacetamide with a base to form an intermediate alpha -lactam which in turn is reacted with a primary or secondary amine. The product thus obtained can comprise a multifunctional compound having one or more hindered amino moieties. These compounds are highly effective as UV stabilizers in a variety of plastics, especially the alpha monoolefins.
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✅ COA系统入驻 | 共享模式

合成参考文献


摘要:S47 | ECHAPLASTICS | A list from the Plastic Additives Initiative Mapping Exercise by ECHA | DOI:10.5281/zenodo.2658139
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