专利号:WO-2020253244-A1 优先权日:2019-06-20 标 题 :Process for catalytic synthesis of lactide 发明人:JIANG WEI; ZHANG YANKAI; SUN PING; LI AIMIN; ZHANG QUANXING 权利人:NANJING UNIVERSITY OF TECHNOLOGY; NANJING QUANKAI RES INSTITUTE OF BIOMATERIALS CO LTD 摘要:The present invention provides a process for the catalytic synthesis of lactide, comprising: mixing a lactic acid oligomer with a composite catalyst; and synthesizing lactide under a heating condition, and collecting the product using a vacuum distillation mode. The used composite catalyst is composed of a zinc or tin compound and an alkali metal compound. Compared with the prior art, the advantages of the present invention are that: the used composite catalyst features a high production rate with a small use amount, a low reaction temperature (150-220°C), and a short reaction time (2-5 h), has a single pass yield that may reach 95% or more, reduces energy consumption compared with the prior art, and facilitates industrial implementations.
专利号:US-11926608-B2 优先权日:2021-03-04 标题:Synthesis method and device for rapidly producing lactide at high yield 发明人:JIANG WEI; QI YUNBIAO; SUN PING; HUANG WEI; LI AIMIN; ZHANG QUANXING 权利人:NANJING UNIVERSITY OF TECHNOLOGY; NANJING QUANKAI RES INSTITUTE OF BIOMATERIALS CO LTD 摘要:The invention discloses a synthesis method and device for rapidly producing lactide at high yield. The method comprises: adding a single component of lactic acid or two components of lactic acid and catalyst, passing the mixture through a mixer to enter an oligomer preparation system, increasing a residence time through bottom circulation, synthesizing oligomeric lactic acid, and passing a gas-phase component through a rectification system. With the adoption of the device, the lactide is capable of being efficiently synthesized, crude lactide with a yield of 94% to 98% is capable of being obtained.
专利号:US-4683332-A 优先权日:1985-05-20 标 题 :Para-nitrodiphenylamine synthesis 发明人:STURM BUDD H 权利人:GOODYEAR TIRE & RUBBER 摘要:There is disclosed a process for the synthesis of para-nitrodiphenylamines via the Formanilide Process wherein the improvement is characterized in that a specific catalyst is utilized. More specifically, a zinc (II) compound (zinc in the plus two oxidation or valence state), is used as a catalyst in the preparation of para-nitrodiphenylamines via the formanilide process.
专利号:US-4435599-A 优先权日:1982-11-26 标 题 :Para-nitrodiphenylamine synthesis 发明人:STURM BUDD H 权利人:GOODYEAR TIRE & RUBBER 摘要:There is disclosed a process for the synthesis of para-nitrodiphenylamines wherein the improvement is characterized in that a specific co-catalyst system is utilized. More specifically, a zinc (II) compound (zinc in the plus two oxidation or valence state), is used in conjunction with copper or a copper compound as a co-catalyst system in the preparation of para-nitrodiphenylamines.
专利号:US-6133473-A 优先权日:1998-06-25 标 题 :Synthesis of carbamate compounds 发明人:BERRIER JOHN VINCENT 权利人:ROHM & HAAS 摘要:Disclosed is a method for the preparation of carbamate compounds substantially free of by-products; the carbamate compounds being prepared by reacting an isocyanate with a hydroxylated compound in the presence of certain catalysts that increase the rate of carbamylation while decreasing the rate of by-product formation.
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