苯甲腈 N-氧化物置于正丁基锂,聚合甲醛,三氟乙酸体系中,用 氯仿 用作溶剂,化学反应 72.0H,反应生成联苯甲酰 参考文献:Reactions Of Nitrile Oxides With 2-Lithio-1,3-Dithianes Synthesis Of α-Diketones 标题:Reactions Of Nitrile Oxides With 2-Lithio-1,3-Dithianes Synthesis Of α-Diketones 摘要: Doi:10.1016/s0040-4039(00)77826-9
专利号:US-9969823-B1 优先权日:2011-09-01 标题 :Synthesis and polymerization of vinyl triazolium ionic liquids 发明人:LUEBKE DAVID; NULWALA HUNAID; MATYJASZEWSKI KRZYSZTOF; ADZIMA BRIAN 权利人:US ENERGY; THE US DEPARTMENT OF ENERGY 摘要:Herein, we describe polymerized ionic liquids, demonstrate the synthesis of polymerized ionic liquids, and demonstrate the polymerization of triazolium monomers. One embodiment shows the polymeriazation of the triazolium monomers with bis(trifluoromethanesulfonyl)imide anions. In another embodiment we show the feasibility of copolymerizing with commodity monomers such as styrene using free radical polymerization techniques.
专利号:US-10487099-B2 优先权日:2017-06-30 标 题:Synthesis of hypervalent iodine reagents with dioxygen 发明人:POWERS DAVID CHARLES; MAITY ASIM; HYUN SUNG-MIN 权利人:TEXAS A & M UNIV SYS 摘要:Methods of synthesis of hypervalent iodine reagents and methods for oxidation of organic compounds are disclosed.
专利号:WO-2024260915-A1 优先权日:2023-06-19 标题:Dynamic covalent chemistry of spiropyrans for synthesis of photoswitchable photoinitiators and uses thereof 发明人:GARMSHAUSEN YVES 权利人:XOLO GMBH 摘要:The present invention relates to spiropyrans and process for the manufacture of them. In particular, a method is provided to exchange the indole and salicylaldehyde part of a spiropyran in a reversible reaction. The method is used for the synthesis of dual color photoinitiators with specific substituents and substitution patterns, which result in improved dual color volumetric printing (xolography). Furthermore, a process for locally polymerizing a starting material by dual color photopolymerization is disclosed.
专利号:US-6294664-B1 优先权日:1993-07-29 标 题:Synthesis of oligonucleotides 发明人:RAVIKUMAR VASULINGA; COLE DOUGLAS L 权利人:ISIS PHARMACEUTICALS INC 摘要:Synthetic processes are provided for the solution phase synthesis of oligonucleotides, especially phosphorothioate oligonucleotides, and intermediate compounds useful in the processes. Intermediates having structure (I) are prepared in accordance with preferred embodiments.
专利号:US-6870039-B2 优先权日:1993-07-29 标题 :Synthesis of oligonucleotides 发明人:RAVIKUMAR VASULINGA; COLE DOUGLAS L 权利人:ISIS PHARMACEUTICALS INC 摘要:Synthetic processes are provided for the solution phase synthesis of oligonucleotides, especially phosphorothioate oligonucleotides, and intermediate compounds useful in the processes. Intermediates having structure n n nare prepared in accord with preferred embodiments.
专利号:US-5571902-A 优先权日:1993-07-29 标题:Synthesis of oligonucleotides 发明人:RAVIKUMAR VASULINGA; COLE DOUGLAS L 权利人:ISIS PHARMACEUTICALS INC 摘要:Synthetic processes are provided for the solution phase synthesis of oligonucleotides, especially phosphorothioate oligonucleotides, and intermediate compounds useful in the processes. Intermediates having structure ##STR1## are prepared in accord with preferred embodiments.