CAS: 18146-00-4; Allyloxytrimethylsilane

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烯丙醇 反应生成烯丙氧基三甲硅烷
参考文献:Synthesis Of Diosphenol Ethers By Means Of Alkoxytrimethylsilanes
标题:Synthesis Of Diosphenol Ethers By Means Of Alkoxytrimethylsilanes
摘要:
Doi:10.1016/s0040-4039(00)85105-9

专利信息

专利号:US-5442065-A
优先权日:1993-09-09
标 题:Synthesis of tetrahydroquinoline enediyne core analogs of dynemicin
发明人：MAGNUS PHILIP D; ILIADIS THEODORE; EISENBEIS SHANE A; FAIRHURST ROBIN A
权利人:UNIV TEXAS
摘要:A process is described for the preparation of the core azobicyclo[7.3.1]tridecaenediyne moiety of the antitumor antibiotic dynemicin. The synthesis allows efficient production of the enediyne as a stable, compound in good yield from the adamantyl N-protected azabicyclo[7.3.1]tridecadiyne. The adamantyl protecting group is employed in the starting material, N-adamantyl dihydroquinoline or N-adamantyl 6-methoxy quinoline. Also disclosed are process for the synthesis of 3-hydroxy-6-methoxyquinoline and several N-substituted derivatives of azobicyclo[7.3.1]tridecaenediyne. Solid tumor and leukemia assays were performed on the analogs of dynemicin. The results suggest a method that these compounds will useful in treating certain types of leukemias and solid tumors. The disclosed synthesis provides a route to new dynemicin intermediates and analogs which will allow development of second and third generation dynemicins.

专利号:EP-1892237-A1
优先权日:2004-01-28
标 题 :Vinylchloroformate-free synthesis of vinyl and allyl(thio)carbamates
发明人：SEELYE DAVID E; KUNZLER JAY F; SALAMONE JOSEPH C
权利人:BAUSCH & LOMB
摘要:The invention generally relates to methods of forming allyl(thio)carbamates and more particularly to a method of synthesizing allyl(thio)carbamates that does not necessitate the use of phosgene and organomercury intermediates.

专利号:US-7402689-B2
优先权日:2004-01-28
标 题 :Vinylchloroformate-free synthesis of vinyl and allyl(thio) carbamates
发明人：SEELYE DAVID E; KUNZLER JAY F; SALAMONE JOSEPH C
权利人:BAUSCH & LOMB
摘要:The invention generally relates to methods of forming vinyl(thio)carbamates and more particularly to a vinylchloroformate-free method of synthesizing (N-vinyloxycarbonyl)-3-aminopropyltris(trimethylsiloxysilane).

专利号:SU-1735300-A1
优先权日:1990-01-22
标题 :Method for synthesis of s-trimethylsilyl esters of dithio- or tetrathiophosphoric acids

专利号:WO-2005073181-A1
优先权日:2004-01-28
标 题:Vinylchloroformate-free synthesis of vinyl and allyl(thio)carbamates

专利号:US-4139403-A
优先权日:1977-08-19
标题:Dinitroalkyl and fluorodinitroalkyl silicon compounds
发明人：BAUM KURT; LERDAL DUANE A; HORN JERALD S
权利人:US NAVY
摘要:Energetic silicon compounds of the general formulae ##STR1## The gem dinitro compounds are prepared from alkyl bromide silanes by sod nitrite displacement and oxidative nitration. The compounds are then fluorinated. To prepare the polysiloxanes, phenyl blocking groups are used during synthesis of the fluoro dinitro moiety and are then replaced with bromine and the monomer is hydrolyzed.