CAS: 766-05-2; Cyclohexanecarbonitrile

相似化合物

1122-56-1 98-89-5 4435-14-7

上下游产品

cyclohex-1-enecarbonitrile toluene-4-sulfonamide Cyclohexanecarboxylic acid cyclohexylcarboxamidemethyl cyclohexanecarboximidate hydr°Chloride N-phenylcyclohexanecarboximidamide H-[1,2,4]triazol-3-yl)-naphthalen-2-ol3-(5-cyclohexyl-1H-[1,2,4]triazol-3-yl)-naphthalen-2-ol H-[1,2,4]triazole3-cyclohexyl-5-phenyl-1H-[1,2,4]triazole

环己甲酸置于氯化亚砜,Palladium Diacetate,Selectfluor,乙腈体系中,用 四氢呋喃 作为反应溶剂,化学反应 19.08H,反应生成 环己甲腈
参考文献:钯催化伯酰胺脱水形成腈的开发和利用.
标题:钯催化伯酰胺脱水形成腈的开发和利用.
摘要:在selectfluor的存在下,钯(II)催化剂可将伯酰胺高效且化学选择性地转化为腈.酰胺可以连接到芳环,杂芳环或脂族侧链上,并且该反应可耐受空间体积和电子修饰.含有三个谷氨酰胺基团的肽醇的脱水为每个谷氨酰胺残基提供了构效关系.因此,这种脱水可以通过合成突变与谷氨酰胺的丙氨酸扫描相似.
DOI:10.1021/acs.Orglett.8B02422

专利信息

专利号:US-7429672-B2
优先权日:2006-06-09
标题 :Process for the direct synthesis of trialkoxysilane
发明人：LEWIS KENRICK M; CAMERON RUDOLPH A; RITSCHER LEGAL REPRESENTATIVE KAREN
权利人:MOMENTIVE PERFORMANCE MAT INC
摘要:This invention discloses a process to improve reaction stability in the Direct Synthesis of trialkoxysilanes. The process is particularly effective in the Direct Synthesis of triethoxysilane and its higher alkyl cognates providing improved triethoxysilane yields.

专利号:WO-2023102600-A1
优先权日:2021-12-06
标题:Synthesis of amphiphilic block copolymers and polymeric nanofibers produced therefrom
发明人：ZETTERLUND PER B; ISHIZUKA FUMI; KIM HYUN JIN; CHATANI SHUNSUKE; NIINO HIROSHI
权利人:NEWSOUTH INNOVATIONS PTY LTD
摘要:The present disclosure relates to the field of synthesis of block copolymers, and polymeric nanofibers having a core-shell morphology produced therefrom. The present disclosure relates to the field of synthesis of block copolymers where one block is more hydrophobic than the other block and is a different composition. The disclosure also relates to uses of these polymeric nanofibers in various applications, such as reinforcing a polymeric matrix and for coatings applications.

专利号:US-2012184653-A1
优先权日:2011-01-18
标 题:Synthesis of linear phosphorus-containing functional fluorocopolymer
发明人：WANG LIANG; WANG VIKTORIA
权利人:WANG LIANG; WANG VIKTORIA
摘要:This invention relates to a synthesis of a linear fluorocopolymer having a plurality of pendant phosphorus-containing functional groups. The synthesized phosphorus-containing fluorocopolymer has chain linearity and narrow molecular weight distributions. It has applications as a lubricant additive that provides friction-reduction, anti-wear, and corrosion protection properties.

专利号:US-6765114-B1
优先权日:1998-12-29
标题 :Process for the synthesis of 1-(aminomethyl)cyclohexyl-acetic acid
发明人：GIZUR TIBOR; LENGYEL ZOLTANNE; SZALAI KRISZTINA
权利人:RICHTER GEDEON VEGYESZET
摘要:The invention relates to a new process for the synthesis of 1-(aminomethyl)cyclohexyl-acetic acid of formula (I) via the new intermedier 1-(nitromethyl)cyclohexyl-acetic acid derivative of formula (II), wherein R represents hydrogen, benzyl group, diphenylmethyl group or C 1 -C 4 alkyl or alkoxy aromatic ring substituted derivatives thereof.

专利号:US-11745159-B2
优先权日:2017-10-20
标题:Heated nanowells for polynucleotide synthesis
发明人：MARSH EUGENE P; INDERMUHLE PIERRE F; PECK BILL JAMES
权利人:TWIST BIOSCIENCE CORP
摘要:Defined sequence RNA synthesis by 3′→5′ direction is now well established and currently in use for synthesis and development of vast variety of therapeutic grade RNA and Si RNA etc. A number of such synthetic RNA requires a modification or labeling of 3′-end of an oligonucleotide. The synthesis of 3′-end modified RNA requiring lipophilic, long chain ligands or chromophores, using 3′→5′ synthesis methodology is challenging, requires corresponding solid support and generally results in low coupling efficiency and lower purity of the final oligonucleotide in general because of large amount of truncated sequences containing desired hydrophobic modification. We have approached this problem by developing reverse RNA monomer phosphoramidites for RNA synthesis in 5′→3′-direction. They lead to very clean oligonucleotide synthesis allowing for introduction of various modifications at the 3′-end.

专利号:US-10465033-B2
优先权日:2016-11-10
标题:One step synthesis of ultrahigh molecular weight block copolymers
发明人：URBAN MAREK W
权利人:UNIV CLEMSON; UNIV CLEMSON RES FOUNDATION
摘要:Single-step synthesis processes for production of ultrahigh molecular weight block copolymers are described. The ultrahigh molecular weight copolymers can have a molecular weight of about 10 6 or greater and can be formed within a few hours in a surfactant-free environment. The formation process is controlled by initiator-starvation conditions in a sequential polymerization of monomers exhibiting different solubility in the solvent.