CAS: 94525-05-0; 4,4'-(1,4-Phenylenebis(Oxy))Bis(3-(Trifluoromethyl)Aniline)

该化合物是化学化合物,其复杂结构特征包括一个苯乙烯组,该化学化合物与两个三氟甲基替代醋酸醋酸酯相连,该化合物通常具有与芳香氨和氟化化合物相关的特性,例如,加强热稳定性和材料科学的潜在应用,特别是在聚合物和涂层的开发方面.三氟甲基组的存在可带来独特的电子特性,使其在各种化学反应和应用中有用.此外,该化合物可能因其功能组而表现出特定的溶性特征和耐受性模式,这可能会影响其在不同的溶剂和条件下的行为.安全和处理考虑至关重要,因为与三氟甲基组化合物有关的化合物有时会对环境和健康造成危害.

英文名称4,4'-(1,4-Phenylenebis(Oxy))Bis(3-(Trifluoromethyl)Aniline)
中文名称4,4’-[1,4-苯基双(氧)]双[3-(三氟甲基)苯胺]
IUPAC名称4,4'-(1,4-phenylenebis(oxy))bis(3-(trifluoromethyl)aniline)
其它别名4,4'-[benzene-1,4-Diylbis(Oxy)]Bis[3-(Trifluoromethyl)Aniline] ; P-6Fapb
CAS编号94525-05-0
MFCD编号:MFCD07368071
EINECS号:807-961-2
分子式:C20H14F6N2O2
分子量:428.33
产品CID: 1996642
产品分类有机原料 → 氨基化合物 → 含氧基氨基化合物

相似结构搜索
InChIKey: LACZRKUWKHQVKS-UHFFFAOYSA-N
InChI=1S/C20H14F6N2O2/c21-19(22,23)15-9-11(27)1-7-17(15)29-13-3-5-14(6-4-13)30-18-8-2-12(28)10-16(18)20(24,25)26/h1-10H,27-28H2…
计算化学: 氢键受体数10.0氢键供体数2.0可旋转键数4.0

MSDS等安全信息

GHS象形图
GHS符号GHS07;
注释: Exclamation mark
危险类别急性毒性类别4(吸入)
急性毒性类别4(经皮)
急性毒性类别4(经口)
警示词Warning(警告)
危险描述H332 |吸入有害.
H312 |皮肤接触有害.
H302 |吞咽有害.
防范说明P261-P264-P270-P271-P280-P301+P312+P330-P302+P352+P312+P362+P364-P304+P340+P312-P501

欧盟法规

ECHA物质C&L通报

上下游产品

4-硝基-1-[4-[4-硝基-2-(三氟甲基)苯氧基]苯氧基]-2-(三氟甲基)苯 1,4'-Bis(4-Nitrotrifluoromethylphenoxy)Benzene 302781-16-4

合成工艺路线路线简述

302781-16-4 = 94525-05-0
反应条件:1.1 Reagents: Hydrazine Hydrate (1:1) Catalysts: Palladium Solvents: Ethanol; Rt -> Reflux; Reflux; 12 H,Reflux
标题:Synthesis And Characterization Of Novel Fluorosilicone Polyimides With High Optical Transparency
作者:Gu,Zheng; Zhang,Ping; Han,Qingxia; Huang,Qiang; Kang,Ming; Et Al
参考文献:High Performance Polymers 日期:2014 卷标:26(3) 页码:335-346]

302781-16-4 = 94525-05-0
反应条件:1.1 Reagents: Hydrazine Hydrate (1:1) Catalysts: Palladium Solvents: Ethanol; 30 Min,78 °C; 6 H,78 °C
标题:Synthesis And Characterization Of Fluorinated Polyimides Derived From 1,4-Bis[4-Amino-2-(Trifluoromethyl)Phenoxy]Benzene/tetrafluorobenzene
作者:Gao,Yafeng; Zhou,Yuming; He,Man; Wang,Haiyun; Cui,Yiping; Et Al
参考文献:Designed Monomers And Polymers 日期:2014 卷标:17(6) 页码:590-600]

302781-16-4 = 94525-05-0
反应条件:1.1 Reagents: Hydrazine Hydrate (1:1) Catalysts: Palladium Solvents: Ethanol; 78 °C; 6 H,Reflux
标题:Synthesis And Characterization Of Ternary-Copolymer Of Soluble Fluorinated Polyimides Based On 1,4-Bis (4-Amino-2-Trifluoromethylphenoxy) Benzene
作者:Fang,Cheng; Zhou,Yuming; He,Man; Bu,Xiaohai; Yin,Kang; Et Al
参考文献:Journal Of Applied Polymer Science 日期:2013 卷标:128(1) 页码:80-88]

302325-32-2 = 94525-05-0
反应条件:1.1 Catalysts: Carbon,Iron Chloride (Fecl3) Solvents: 2-Methoxyethanol; Rt -> 110 °C1.2 Reagents: Hydrazine Hydrate (1:1) Solvents: Water; 110 °C; 10 H,Reflux; Cooled1.3 Reagents: Hydrochloric Acid Solvents: Water1.4 Reagents: Ammonia Solvents: Water; Ph 11 - 12
标题:Preparation And Characterization Of Fluorinated Polyurethane Elastomers
作者:Xu,Wenzong; Du,Xianbing; Lu,Bo; Yin,Jianguo
参考文献:Zhongguo Pige 日期:2010 卷标:39(11) 页码:35-40]

302781-16-4 = 94525-05-0
反应条件:1.1 Reagents: Iron,Hydrochloric Acid Solvents: Ethanol; 25 Min,75 °C; 75 °C -> 55 °C; 7 H,55 °C -> 80 °C
标题:Preparation Method Of Pigment Carbon Black From Waste Polydicyclopentadiene
参考文献:China]

302781-16-4 = 94525-05-0
反应条件:1.1 Reagents: Iron,Hydrochloric Acid Solvents: Ethanol; 2 H,Heated1.2 Reagents: Ammonium Hydroxide; 30 Min
标题:Modified Epoxy Resin Composition And Preparation Method Thereof
参考文献:China]

302781-16-4 = 94525-05-0
反应条件:1.1 Reagents: Hydrochloric Acid Catalysts: Iron Solvents: Ethanol,Water; 4 H,Reflux
标题:Fluorine-Containing Polyimide Polymer,Its Preparation Method And Polyimide Composite Film
参考文献:China]

777-37-7 = 94525-05-0
反应条件:1.1 Reagents: Potassium Carbonate Solvents: Dimethyl Sulfoxide1.2 Reagents: Hydrazine Catalysts: Palladium
标题:Optically Transparent And Colorless Poly(Ether-Imide)S Derived From A Phenylhydroquinone Bis(Ether Anhydride) And Various Trifluoromethyl-Substituted Bis(Ether Amine)S
作者:Yang,Chin-Ping; Chen,Yung-Chung; Hsiao,Sheng-Huei; Guo,Wenjeng; Wang,Hui-Min
参考文献:Journal Of Polymer Research 日期:2010 卷标:17(6) 页码:779-788]

302781-16-4 = 94525-05-0
反应条件:1.1 Reagents: Hydrogen Catalysts: Palladium Solvents: Tetrahydrofuran; Rt
标题:Diamine Precursors,Polyimides With Improved Optical Transmission Properties And Their Manufacture
参考文献:United States]

302781-16-4 = 94525-05-0
反应条件:1.1 Reagents: Hydrochloric Acid Catalysts: Iron Solvents: Acetone,Water; 8 H,55 °C
标题:Fracturing Pump Plunger Processing Technology With Wear-Resistant And Corrosion-Resistant Protective Layer
参考文献:China]

302781-16-4 = 94525-05-0
反应条件:1.1 Reagents: Hydrochloric Acid,Stannous Chloride Solvents: Ethanol; 20 H,Reflux
标题:Corrosion-Resistant Epoxy Resin Coating And Preparation Method Thereof
参考文献:China]

302781-16-4 = 94525-05-0
反应条件:1.1 Reagents: Iron,Hydrochloric Acid Solvents: Ethanol,Water; Rt
标题:Mechanical And Thermal Properties Of Epoxy Resins Modified By A Novel Thermoplastic-Polyimide
作者:Ji,Yu; Zhang,Yan; Wang,Ping; Li,Yuanyuan; Sui,Jianhua
参考文献:Fibers And Polymers 日期:2021 卷标:22(1) 页码:205-212]

302781-16-4 = 94525-05-0
反应条件:1.1 Reagents: Hydrazine Hydrate (1:1) Catalysts: Palladium
标题:Novel 'Naked-Eye' Bis-Schiff Base Fluorescent Chemosensors For Sensitive Detection Of Zn2+ And Bio-Imaging In Living Cells
作者:Wang,Xinchao; Ding,Ge; Duan,Yuanke; Wang,Min; Zhu,Guangshi; Et Al
参考文献:Tetrahedron 日期:2020 卷标:76(16)]

302781-16-4 = 94525-05-0
反应条件:1.1 Reagents: Iron,Hydrochloric Acid Solvents: Ethanol; 2 H,Reflux1.2 Reagents: Ammonium Hydroxide Solvents: Water; 30 Min,Rt
标题:Modified Epoxy Resin And Preparation Method Thereof
参考文献:China]

777-37-7 = 94525-05-0
反应条件:1.1 Reagents: Potassium Carbonate Solvents: Dimethyl Sulfoxide1.2 Reagents: Hydrazine Hydrate (1:1) Catalysts: Palladium
标题:Organosoluble And Colorless Fluorinated Poly(Ether Imide)S Derived From A Highly Contorted Biphenyl-2,2'-Diol Bis(Ether Anhydride) And Aromatic Bis(Ether Amine)S With Trifluoromethyl Substituents
作者:Chen,Yung-Chung; Hsiao,Sheng-Huei; Su,Yu-Yang
参考文献:Journal Of Polymer Research 日期:2017 卷标:24(6) 页码:1-11]

302781-16-4 = 94525-05-0
反应条件:1.1 Reagents: Hydrazine Catalysts: Palladium Solvents: Ethanol
标题:Synthesis And Characterization Of Novel Sulfonated Aromatic Polyamides For Proton Exchange Membranes
作者:Hu,Yaping; Li,Guang
参考文献:Advanced Materials Research (Durnten-Zurich 日期:2013 卷标:821 页码:821-822]

302781-16-4 = 94525-05-0
反应条件:1.1 Reagents: Hydrazine Hydrate (1:1) Catalysts: Palladium; Heated
标题:Synthesis And Characterization Of Novel Fluorine-Containing Polyetherimide
作者:Yu,Xin-Hai; Liu,Wang-Zhang
参考文献:Huaxue Yu Nianhe 日期:2010 卷标:32(5) 页码:10-13

4-硝基-1-[4-[4-硝基-2-(三氟甲基)苯氧基]苯氧基]-2-(三氟甲基)苯置于palladium On Activated Charcoal,一水合肼体系中,化学反应生成 4,4'-[1,4-苯基双(氧)]双[3-(三氟甲基)苯胺]
参考文献:Novel 'naked-Eye' Bis-Schiff Base Fluorescent Chemosensors For Sensitive Detection Of Zn2+ And Bio-Imaging In Living Cells
标题:Novel 'naked-Eye' Bis-Schiff Base Fluorescent Chemosensors For Sensitive Detection Of Zn2+ And Bio-Imaging In Living Cells
摘要:Novel Chemosensors Based On Excited State Intramolecular Proton Transfer Chemosensors (F1,F3,F5) And Reference Dyes (F2,F4,F6) Are Presented In This Work. Target Dyes Fl,F3 And F5 Display High Selectivity And Sensitivity Toward Zn2+ In Solvents (Such As Etoh,Etoh/pbs Buffer) In The Presence Of Competitive Ions (K+,Na+,Ni2+,Pb2+,Mn2+,Mg2+,Hg2+,Cu2+,Cd2+,Cr3+,Fe3+). Sensing Property For Zn2+ Was Studied By Uv-Visible,Fluorescence Spectrophotometric Analyses And Job'S Plot Analyses. F1,F3 And F5 For Zn2+ Detection Revealed Extremely Low Detection Limit (67.2 Nm),High Anti-Interference Ability,And The Immediate Response. Furthermore,Inverted Fluorescence Microscopy Imaging Experiment Were Also Investigated,The Results Demonstrated That The Probes Have Well Cell Membrane Permeability And Hypotoxicity. Simultaneously,Due To The Ability To Adapt A Wider Range Of Ph,The Probes Could Also Image Zn2+ In Live Cells With Remarkable Fluorescence Variation And Provide A New Method To Visualize Monitoring In Live Cells. (C) 2020 Elsevier Ltd. All Rights Reserved.
DOI:10.1016/j.Tet.2020.131108

海关参考信息

2902300000-甲苯
2907121100-间甲酚
2903399090-其他无环烃卤化衍生物
2908199090-其他酚的卤化衍生物
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详情请参考：📖 海关编码查询和海关进出口税则

专利信息

专利号:US-2025054696-A1
优先权日:2023-08-10
标题:Thin film capacitor
发明人：CHO WEI-YU
权利人:META SYNTHESIS MAT CO LTD
摘要:A thin film capacitor is provided. The thin film capacitor includes a dielectric layer and a conductive layer. The dielectric layer includes polyimide and conductive particles. The polyimide includes ether linkages. Based on 100 weight parts of the polyimide, a total amount of monomer units including the ether linkages is 50 weight parts to 100 weight parts. Based on 100 weight parts of the dielectric layer, a total amount of the conductive particles is 10 weight parts to 70 weight parts. The conductive layer is disposed on a surface of the dielectric layer.

专利号:US-2016032052-A1
优先权日:2014-08-01
标题:Process for manufacturing polyamide
发明人：KATAYAMA TOSHIHIKO; OKADA JUN; KAWASAKI RITSUYA; UMEDA HIDEO
权利人:SUMITOMO BAKELITE CO
摘要:In one or a plurality of embodiments, a process for manufacturing polyamide, with a reduced use of an amide-based solvent in synthesis, is provided. In one or a plurality of embodiments, provided is a process for manufacturing polyamide, including steps (a) to (c): (a) dissolving diacid dichloride in a non-amide-based organic solvent; (b) adding diamine to a solution obtained in the step (a) and reacting the diacid dichloride with the diamine so as to generate polyamide; and (c) adding a trapping reagent capable of trapping hydrochloric acid, at any time at least before the step (b), at the same time of starting the step (b), or during the step (b).

专利号:US-2016075826-A1
优先权日:2014-09-11
标题:Process for manufacturing polyamide
发明人：SUN LIMIN; ZHANG DONG; JING JIAOKAI; HARRIS FRANK W; OKADA JUN; KATAYAMA TOSHIHIKO; UMEDA HIDEO; KAWASAKI RITSUYA
权利人:AKRON POLYMER SYSTEMS INC; SUMITOMO BAKELITE CO
摘要:In one or a plurality of embodiments, a process for manufacturing polyamide without using PrO (propylene oxide) in synthesis is provided. In one or a plurality of embodiments, provided is a process for manufacturing polyamide, including steps (a) to (c): (a) reacting diacid dichloride monomer with at least two kinds of diamine monomers in a solvent so as to generate polyamide; and (b) removing hydrochloric acid physically out of a reaction system, the hydrochloric acid being generated during the reaction in the step (a); or (c) adding a trapping reagent capable of trapping hydrochloric acid, at any time at least before the step (a), at the same time of starting the step (a), or during the step (a), wherein at least one of the diamine monomers is a diamine monomer containing a carboxyl group, and the trapping reagent does not include propylene oxide.

专利号:US-2012305484-A1
优先权日:2011-06-03
标题 :Thermally Rearranged (TR) Polymers as Membranes for Ethanol Dehydration
发明人：FREEMAN BENNY D; PAUL DONALD R; CZENKUSCH KATRINA; RIBEIRO JR CLAUDIO P; BA CHAOYI
权利人:FREEMAN BENNY D; PAUL DONALD R; CZENKUSCH KATRINA; RIBEIRO JR CLAUDIO P; BA CHAOYI; UNIV TEXAS
摘要:Synthesis and use of a new class of polymeric materials with favorable separation characteristics for the dehydration of ethanol and other organic solvents is described herein. The thermally rearranged (TR) polybenzoxazole (PBO), polybenzimidazole (PBI) and polybenzothiazole (PBT) membranes of the present invention can be used for the dehydration of ethanol during processing to fuel grade biodiesel by either pervaporation or vapor permeation. The unique microstructure of the membranes provides excellent separation characteristics, and this, coupled with their inherent thermal and chemical stability, enables their usage in other separations, such as the dehydration of other organic solvents.

专利号:CN-104478838-B
优先权日:2014-11-28
标题:A kind of phenylethynyl-containing dianhydride monomer and its synthesis method and application

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合成参考文献

参考文献:10.1007/s10118-023-2985-4
摘要:Gao M, Zhai L, Mo S, Jia Y, Liu Y, He M, Fan L. Thermally Conductive Polyimide/Boron Nitride Composite Films with Improved Interfacial Compatibility Based on Modified Fillers by Polyimide Brushes. Chin J Polym Sci. 2023 May 18;41(12):1921–36. doi: 10.1007/s10118-023-2985-4.
参考文献:10.1007/s11431-023-2476-6
摘要:Tan J, Shen J, Huang J, Zhao C, Li H, Liu X, Xie F, Liu Y. Synthesis and characterization of soluble intrinsic black polyimide with excellent comprehensive properties. Sci. China Technol. Sci. 2023 Nov 08;66(12):3604–14. doi: 10.1007/s11431-023-2476-6.
参考文献:10.1007/s10854-023-11731-w
摘要:Li H, Wang X, Wu T, Gong Y, Zhao H, Liu Z, Dastan D, Ma K, Hu Z. Mechanical enhancement and dielectric properties of SiO2 contained polyimides under high frequency. J Mater Sci: Mater Electron. 2023 Dec;34(36). doi: 10.1007/s10854-023-11731-w.
参考文献:10.1007/s10853-025-11148-2
摘要:Šimonová ZF, Machotová J, Podzimek Š, Mistrík J, Houdek J, Dědourková T, Zelenka J, Šimon P. Effect of trifluoromethyl groups on properties of aromatic and semi-aromatic polyimides for space applications. J Mater Sci. 2025 Aug;60(32):14221–35. doi: 10.1007/s10853-025-11148-2.