CAS: 1067-87-4; Diethyl Allylphosphonate

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CAS号106-95-6 烯丙基溴 | CAS号122-52-1 亚磷酸三乙酯 | CAS号762-04-9 亚磷酸二乙酯 | CAS号591-87-7 乙酸烯丙酯 | CAS号1469-70-1 碳酸丙烯乙酯 | CAS号1809-20-7 亚磷酸二异丙酯 | CAS号107-05-1 氯丙烯 | CAS号1609-72-9 1-diethoxyphosp... | CAS号814-49-3 氯磷酸二乙酯 | CAS号23859-75-8 3-diethoxyphosp... | CAS号1067-71-6 乙酰基甲基膦酸二乙酯 | CAS号3986-95-6 diethyl 3-oxopr... | CAS号66498-59-7 3-溴-1-丙烯膦酸二乙酯 | CAS号1606-75-3 (甲酰基甲基)磷酸二乙酯 | CAS号16939-57-4 1-苯-1,3-丁二烯 | CAS号31915-94-3 (Z)-buta-1,3-di... | CAS号135760-95-1 3-diethoxyphosp... | CAS号52378-69-5 反-肉桂基膦酸二乙酯 | CAS号137811-76-8 (1-diethoxyphos...

Diaethyl-Allyl-Phosphit 以 Xylene 用作溶剂,化学反应 5.0H,反应生成烯丙基磷酸二乙酯
参考文献:1-(三甲基甲硅烷基)-2-丙烯酸二乙酯的合成
标题:1-(三甲基甲硅烷基)-2-丙烯酸二乙酯的合成
摘要:摘要 在三乙胺存在下,由烯丙醇和氯亚磷酸二乙酯合成 L-(三甲基甲硅烷基)-2-丙烯基膦酸二乙酯 5,制备的亚磷酸二乙酯 2 发生 [2,3]-σ 重排,形成 2-丙烯基膦酸二乙酯 3 和以下描述了其碳负离子 4 与三甲基氯硅烷的反应.
Doi:10.1080/10426509808036975

专利信息

专利号:US-9403854-B2
优先权日:2001-03-30
标 题 :Cross-metathesis reaction of functionalized and substituted olefins using group 8 transition metal carbene complexes as metathesis catalysts
发明人：GRUBBS ROBERT H; CHATTERJEE ARNAB K; CHOI TAE-LIM; GOLDBERG STEVEN D; LOVE JENNIFER A; MORGAN JOHN P; SANDERS DANIEL P; SCHOLL MATTHIAS; TOSTE F DEAN; TRNKA TINA M
权利人:CALIFORNIA INST OF TECHN
摘要:The invention pertains to the use of Group 8 transition metal carbene complexes as catalysts for olefin cross-metathesis reactions. In particular, ruthenium and osmium alkylidene complexes substituted with an N-heterocyclic carbene ligand are used to catalyze cross-metathesis reactions to provide a variety of substituted and functionalized olefins, including phosphonate-substituted olefins, directly halogenated olefins, 1,1,2-trisubstituted olefins, and quaternary allylic olefins. The invention further provides a method for creating functional diversity using the aforementioned complexes to catalyze cross-metathesis reactions of a first olefinic reactant, which may or may not be substituted with a functional group, with each of a plurality of different olefinic reactants, which may or may not be substituted with functional groups, to give a plurality of structurally distinct olefinic products. The methodology of the invention is also useful in facilitating the stereoselective synthesis of 1,2-disubstituted olefins in the cis configuration.

专利号:US-7820831-B2
优先权日:2002-09-11
标 题:Compounds comprising a thiocarbonyl-sulfanyl group which can be used for the radical synthesis of α-perfluoroalkylamine compounds
发明人：ZARD SAMIR; GAGOSZ FABIEN; TOURNIER LUCIE
权利人:CENTRE NAT RECH SCIENT
摘要:The invention relates to compounds having the general formula (I), the method of preparation thereof and the use thereof in organic radical synthesis. The invention also relates to compounds having the formula (II), the method of preparation thereof and a method for preparing compounds having the formula (VIII).

专利号:US-8987504-B2
优先权日:2010-06-18
标题 :Aminohydroxylation of alkenes
发明人：MEE SIMON PETER HAROLD; LUXENBURGER ANDREAS; HARRIS LAWRENCE DANIEL
权利人:MEE SIMON PETER HAROLD; LUXENBURGER ANDREAS; HARRIS LAWRENCE DANIEL; VICTORIA LINK LTD
摘要:The invention relates to a process for the aminohydroxylation of alkenes using N-oxycarbamate reagents, e.g. N-acyloxycarbamate, N-alkyloxycarbonyloxycarbamate and N-aralkoxycarbonyloxycarbamate reagents. The invention particularly relates to an intermolecular aminohydroxylation reaction that can be carried out in the absence of added base. The invention also relates to novel N-oxycarbamate reagents that are stable crystalline materials. The process of the invention is useful in the synthesis of compounds having a vicinal amino alcohol moiety, such as biologically active compounds.

专利号:US-3597510-A
优先权日:1968-05-15
标题:Preparation of allylphosphonic acid and esters and salts thereof
发明人：POLLAK PETER I; SLATES HARRY L
权利人:MERCK & CO INC
摘要:PROPENYLPHOSPHONIC ACID AND ESTERS AND SALTS THEREOF ARE PREPARED BY TRANSITIONAL METAL CATALYIZED DOUBLE BOND ISOMERIZATION OF THE CORRESPONDING ALKYLPHOSPHONIC ACID OR ALLYLPHOSPHONATE. THESE COMPOUNDS ARE USEFUL INTERMEDIATES IN THE SYNTHESIS OF ANTIBIOTICALLY ACTIVE ($)(CIS-1,2-EPOXYPROPYL) PHOSPHONIC ACID AND ITS SALTS.

专利号:US-2008306281-A1
优先权日:2002-09-11
标题 :Novel compounds comprising a thiocarbonyl-sulfanyl group which can be used for the radical synthesis of alpha-perfluoroalkylamine compounds

专利号:US-7423161-B2
优先权日:2002-09-11
标 题 :Compounds comprising a thiocarbonyl-sulfanyl group, which can be used for the radical synthesis of-α-perfluoroalkylamines