CAS: 108-09-8; 2-Amino-4-Methylpentane

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4-methyl-pent-3-en-2-one bis-(1,3-dimethyl-butylidene)-hydrazine 4-methyl-pent-3-en-2-one oxime 4-methyl-pentan-2-one oxime N-ethyl-1,3-dimethylbutylamine (1,3-dimethyl-butyl)-(1,3-dimethyl-butyliden)-amine cyclohexyl-(1,3-dimethyl-butyl)-amine

4-甲基-2-戊酮置于氨,氢气体系中,用 甲醇 用作溶剂,35.0 °C,1.4 Mpa 条件下,反应 13.0H,以87%的收率获得1,3-二甲基丁胺
参考文献:纳米粒子和钴单原子协同实现羰基化合物的低温还原胺化
标题:纳米粒子和钴单原子协同实现羰基化合物的低温还原胺化
摘要:羰基化合物的低温和选择性还原胺化是获得伯胺的一种非常有前景的方法.然而,在地球上丰富的金属基催化剂上有效地进行这条有吸引力的路线仍然是一个巨大的挑战.在此,我们设计了几种钴基催化剂(表示为 Co@c-n( X ),其中x代表热解温度)由金属有机骨架 Zif-67 在不同温度下的热解.非常有趣的是,所制备的 Co@c-N(800) 可以有效地催化各种醛/酮的还原胺化,在 35 oc 下以高收率合成相应的伯胺.除了非贵金属和温和的温度外,该催化剂的另一个独特优势是具有不同还原敏感性基团的底物可以选择性地转化为伯胺,因为钴基催化剂在低温下对这些基团没有活性.系统分析表明,该催化剂由石墨烯包裹的 Co 纳米颗粒和原子分散的 Co-N X位点组成.Co颗粒促进了氢化步骤,而co-Nx位点充当酸性位点以激活中间体(席夫碱).金属co颗粒和co-N X位点的协同效应对于催化剂co@c-N(800)的优异
Doi:10.1039/d2Sc01596J

专利信息

专利号:WO-2017175233-A1
优先权日:2016-04-04
标 题:Process for large scale liquid phase synthesis of carbetocin and its novel intermediates
发明人：Mohammed Khalid Anwer; Mohammed Mohosin Layek
权利人:DAVULURI RAMAMOHAN RAO
摘要:A process for large scale liquid phase synthesis of Carbetocin is disclosed. Novel intermediates of formula (A), formula (B), and processes for their preparation are also disclosed.

专利号:US-3992436-A
优先权日:1976-01-02
标题:Synthesis of oxalate esters from carbon monoxide and carboxylic ortho esters
发明人：ZEHNER LEE R
权利人:ATLANTIC RICHFIELD CO
摘要:A process for the preparation of oxalate esters by the catalytic oxidative carbonylation of carboxylic ortho esters with carbon monoxide and oxygen-containing gas in the presence of a metal salt catalyst, an amine base and a catalytic amount of an alcohol. Preferably a catalytic amount of particular metal oxidizing salts is employed along with a catalytic amount of an acid or an amine salt compound. Alternatively various counterions and ligands of the metal salt catalysts may be employed.

专利号:US-4005131-A
优先权日:1976-01-02
标 题 :Synthesis of oxalate esters from carbon monoxide and acetals or ketals
发明人：ZEHNER LEE R
权利人:ATLANTIC RICHFIELD CO
摘要:A process for the preparation of oxalate esters by the catalytic oxidative carbonylation of acetals and ketals with carbon monoxide and oxygen-containing gas in the presence of a metal salt catalyst, an amine base and a catalytic amount of an alcohol. Preferably a catalytic amount of particular metal oxidizing salts is employed along with a catalytic amount of an acid or an amine salt compound. Alternatively various counterions and ligands of the metal salt catalysts may be employed.

专利号:US-4041068-A
优先权日:1976-06-29
标题:Synthesis of oxalate esters by catalytic oxidative carbonylation of borate esters
发明人：ZEHNER LEE R; ZAJACEK JOHN G
权利人:ATLANTIC RICHFIELD CO
摘要:A process for the preparation of oxalate esters by the catalytic oxidative carbonylation of orthoborate, metaborate and polyborate esters or mixtures thereof with carbon monoxide and oxygen or an oxygen-containing gas in the presence of a metal salt catalyst, an amine base and at least a catalytic amount of an alcohol. Preferably a catalytic amount of particular metal oxidizing salts are employed along with a catalytic amount of an amine salt compound which may be formed in situ by the addition of an acid. Alternatively various counterions and ligands of the metal salt catalysts may be employed.

专利号:US-4041067-A
优先权日:1976-07-21
标 题:Synthesis of oxalate esters by the oxidative carbonylation of amide acetals
发明人：ZEHNER LEE R; ZAJACEK JOHN G
权利人:ATLANTIC RICHFIELD CO
摘要:A process for the preparation of oxalate esters by the catalytic oxidative carbonylation of an amide acetal having the formula with carbon monoxide and oxygen or oxygen-containing gas in the presence of a metal salt catalyst, an amine base and a catalytic amount of an alcohol. Preferably a catalytic amount of particular oxidizing metal salts is employed along with a catalytic amount of an amine salt compound which may be formed in situ by the addition of an acid. Alternatively various counterions and ligands of the metal salt catalyst may be employed.

专利号:US-5565517-A
优先权日:1994-11-16
标题:Synthesis of organic polysulfide polymers
发明人：EFNER HOWARD F; SHAW JAMES E
权利人:PHILLIPS PETROLEUM CO
摘要:A process for preparing an organic polysulfide polymer, such as polyethylene trisulfide, is provided which comprises contacting a dimercaptan such as 1,2-ethanedithiol with elemental sulfur using a basic catalyst wherein the dimercaptan, elemental sulfur, and basic catalyst are each present in an effective amount to effect the preparation of the organic polysulfide polymer. A process for controlling the molecular weight of an organic polysulfide polymer is also provided which comprises contacting a mercaptan with a dimercaptan and sulfur, in the presence of a basic catalyst, under conditions sufficient to prepare an organic polysulfide polymer.