合成目标产物 2,4,6,8-Tetramethylcyclotetrasiloxane 主要起始原料 Dichloromethylsilane And Water
(文献来源)合成步骤主要原料 Dichloromethylsilane 和 Water
1,3-Dichloro-1,3-Dimethyldisiloxane置于乙醚,水体系中,化学反应生成2,4,6,8-四甲基环四硅氧烷 参考文献:Sokolow,Zhurnal Obshchei Khimii,1959,Vol. 29,P. 258,261,263; Engl. Ausg. S. 262,265,266 标题:Sokolow,Zhurnal Obshchei Khimii,1959,Vol. 29,P. 258,261,263; Engl. Ausg. S. 262,265,266
专利信息
专利号:US-6495208-B1 优先权日:1999-09-09 标 题 :Near-room temperature CVD synthesis of organic polymer/oxide dielectric nanocomposites 发明人:DESU SESHU B; SENKEVICH JOHN J 权利人:VIRGINIA TECH INTELL PROP 摘要:Nanocomposite thin films with low dielectric constants are made by the simultaneous deposition of an oxide dielectric and an organic polymer at near room temperatures. Suitable oxides include SiO 2 , and suitable organic polymers include poly(chloro-para-xylylene). The two dielectric materials, when deposited, form nanocomposites characterized by nanometer-sized domains of dielectric material. The nanocomposite thin films of this invention are useful as dielectric layers for interlevel dielectric (ILD) and intermetal dielectric (IMD) dielectrics in the manufacture of semiconductor devices as well as for thin films for flat panel displays, food wraps, hybrid ceramics, glass, hard disk drives, and optical disk drives. Additionally, the invention comprises semiconductor devices and semiconductor chips made incorporating nanocomposites deposited by chemical vapor deposition.
专利号:US-11738328-B2 优先权日:2021-04-30 标题:Single-step synthesis of chemisorption fiber sorbents (CHEFS) for the capture of CO2 and removal of water contaminants 发明人:GRAY MCMAHAN L; SHI FAN; YI SHOULIANG; WILFONG WALTER CHRIS; WANG QIUMING 权利人:US ENERGY 摘要:One or more embodiments relates to method for generating CHEFS having the steps of generating the CHEFS from a dope. One or more embodiments relates to a method for generating CHEFS having amine functional groups having the steps of generating a dope containing a BIAS with amine groups, at least one polymer, and at least one solvent; and forming CHEFS from the dope, wherein the generated CHEFS have no more than 30% amine loss compared to the BIAS.
专利号:US-5247044-A 优先权日:1989-09-01 标题:Synthetic method for the synthesis of silicon polyether copolymers 发明人:CRIVELLO JAMES V; FAN MINGXIN 权利人:GEN ELECTRIC 摘要:The present invention is based on the discovery that various metal catalysts will catalyze the ring opening polymerization of epoxides to yield polyethers. The present invention therefore provides a method of making a polymeric product by ring-opening polymerization of heterocyclic epoxide monomer including the steps of preparing a mixture comprised of a catalyst; a Si--H containing compound; and at least one compound which is a heterocyclic epoxide containing monomer; and reacting the mixture at a temperature effective to promote ring-opening polymerization of the at least one compound to produce a polymeric product, preferably at room temperature. n The present invention additionally provides for the silicone-polyether compositions created by this method.
专利号:US-2010280189-A1 优先权日:2005-11-30 标 题 :Synthesis of cycloaliphatic substituted silane monomers and polysiloxanes for photo-curing 发明人:DWORAK DAVID P; SOUCEK MARK D 权利人:UNIV AKRON 摘要:The present invention generally relates to compositions including linear cycloaliphatic siloxane polymers, and the cyclic cycloaliphatic siloxane oligomers from which they are made. The present invention also generally relates to methods for making cycloaliphatic siloxane polymers, and the cyclic cycloaliphatic siloxane oligomers from which they are made. Some embodiments relate to cationic polymerization of methyl, cyclopentyl, and/or cyclohexyl substituted polysiloxanes. In some embodiments the cationic polymerization is a cationic ring-opening polymerization.
专利号:US-9751987-B2 优先权日:2013-08-23 标题:Catalyst for synthesis of siloxanes 发明人:SIVASUBRAMANIAN KARTHIKEYAN; ANDERSON PATRICIA PIKE; KHARE VIVEK 权利人:MOMENTIVE PERFORMANCE MAT INC 摘要:The present technology provides compositions, methods, and processes to form polysiloxanes. In one aspect, the present technology provides a process for the ring opening polymerization of a cyclosiloxane comprising contacting a cyclosiloxane with a N-trialkylsilyl-bis(perfluoroalkylsulfonyl)imide compound.
专利号:US-9246173-B2 优先权日:2012-11-16 标题 :Process for synthesis of hybrid siloxy derived resins and crosslinked networks therefrom 发明人:GERBEC JEFFREY A 权利人:MITSUBISHI CHEM CORP 摘要:A hybrid siloxy derived resin and a method of making them and a method of applying them as a benign passivant on electrochemical electrodes is provided. These resins are made by the process of reacting a silane and an alkaline, transition metal or metalloid alkoxide, in the presence of a lewis acid. The methods described do not require further purification steps; heat; or strong acid/base catalysis to initiate hydrolysis.
参考标题:Photo Lewis Acid Generators: Photorelease Of B(C6F5)3 And Applications To Catalysis 作者:Andrey Y. Khalimon,Bryan K. Shaw,Adam J. V. Marwitz,Warren E. Piers,James M. Blackwell,Masood Parvez 摘要:A Series Of Molecules Capable Of Releasing Of The Strong Organometallic Lewis Acid B(C6F5)3 Upon Exposure To 254 Nm Light Have Been Developed. These Photo Lewis Acid Generators (Phlags) Can Now Serve As Photoinitiators For Several Important B(C6F5)3-Catalyzed Reactions. Herein Is Described The Synthesis Of The Triphenylsulfonium And Diphenyliodonium Salts Of Carbamato- And Hydridoborates, Their Establishment