3-羟基-2-三氟甲基丙酸置于phosphorus Pentoxide体系中,化学反应生成2-(三氟甲基)丙烯酸 参考文献:Buxton Et Al.,Journal Of The Chemical Society,1954,P. 366,370 标题:Buxton Et Al.,Journal Of The Chemical Society,1954,P. 366,370
专利号:US-8987370-B2 优先权日:2007-07-23 标题:Synthesis of modified tung oil as a reactive diluent 发明人:SOUCEK MARK D; WUTTICHAROENWONG KOSIN 权利人:SOUCEK MARK D; WUTTICHAROENWONG KOSIN; UNIV AKRON 摘要:The invention relates to the use of a conjugated seed oil modified with an activated vinyl monomer via a Deils-Alder reaction to generate a modified reactive diluent used to enhance the physical properties of coating systems. In one embodiment, a reactive diluent containing tung oil modified by the addition of an acrylate monomer is mixed with an auto-oxidative alkyd, a metal drier package, and a wetting agent to achieve cross-linked films exhibiting improved tensile strength, tensile modulus, cross-link density, and glass transition temperature, among other physical parameters.
专利号:WO-2024000920-A1 优先权日:2022-06-28 标题 :Method for preparing β-trifluoromethylenamine compound on basis of organic dye catalysis 发明人:CHEN XIAOYUN; TANG YISONG; ZHANG XIAOTONG; HUANG MINGYANG; QI GUANGJIE; XIANG XINRAN 权利人:UNIV JIANGSU SCIENCE & TECH 摘要:Disclosed in the present invention is a method for preparing a β-trifluoromethylenamine compound on the basis of organic dye catalysis. The present invention belongs to the technical fields of the synthesis of medicines, pesticide products and material intermediates. The β-trifluoromethylenamine compound has a structure as represented by formula (I). The preparation method of the present invention comprises: under the irradiation of environment-friendly, green and economic visible light, using a catalytic amount of a commercial organic dye Na2-Eosin Y as a photocatalyst, using CF3SO2Na which is cheap, easily available, stable and simple and convenient to operate as a trifluoromethyl source, using Na2CO3 as an additive, and using tert-butyl hydroperoxide as an initiator. The reaction has mild conditions and is insensitive to air and water, and the operation is simple and convenient, the reaction efficiency is high, and the target product is easy to purify. In addition, the present invention has a a wide reaction substrate range and good functional group tolerance, and most of the target product compounds can be obtained with good to significant yields.
专利号:US-9534062-B2 优先权日:2014-07-02 标 题:Synthesis of an acrylate polymer in flow reactor 发明人:HE MINGQIAN; HORN CLEMENS RUDOLF; HU JIEYU; JEAN PATRICK; NIU WEIJUN; SCHISSEL DAVID NEAL; WINNINGHAM MICHAEL JAMES 权利人:CORNING INC 摘要:An improved process for synthesizing acrylic polymers, which is highly controllable to achieve high molecular weight, high conversion rate, and low polydispersity involves continuously introducing initiator(s), acrylic monomer(s), and optionally other monomers capable of polymerizing with the acrylic monomer(s), into a microchannel of a microreactor having an integral micromixer and an integral heat exchanger.
专利号:US-2002001821-A1 优先权日:1994-02-10 标 题:Methods for direct synthesis of compounds having complementary structure to a desired molecular entity and use thereof
专利号:US-6127154-A 优先权日:1994-02-10 标题 :Methods for direct synthesis of compounds having complementary structure to a desired molecular entity and use thereof 发明人:MOSBACH KLAUS; CORMACK PETER A G; RAMSTROEM OLOF; HAUPT KARSTEN 摘要:Compounds which possess a complementary structure to a desired molecule, such as a biomolecule, in particular polymeric or oligomeric compounds, which are useful as in vivo or in vitro diagnostic and therapeutic agents are provided. Also, various methods for producing such compounds are provided. These polymeric or oligomeric compounds are useful in particular as antimicrobial agents, receptor, hormone or enzyme agonists and antagonists.
专利号:WO-2009014684-A2 优先权日:2007-07-23 标 题:Synthesis of modified tung oil as a reactive diluent
[参考文献]: Hüma Ylmaz, Et Al. Preconcentration Of Indapamide From Human Urine Using Molecularly Imprinted Solid-Phase Extraction. J Sep Sci. 2015 Sep;38(17):3090-5.
合成参考文献
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