CAS: 814-29-9; Tri-N-Butylphosphineoxide

该化合物是一种有机磷化合物,配有公式(C4H993PO),广泛用作过渡性金属催化稳定剂和溶剂提炼工艺的提取剂,因为它与金属离子有很强的亲近性.TBPO在有机溶剂中表现出很高的热稳定性和溶性,适合化学和材料科学协调的应用.其电子施放特性提高了交叉反应的催化效率,而其对氧化的耐抗力则确保了一致性.TBPO还被用于合成先进材料,包括纳米粒子和聚合物,需要准确控制再活性.

英文名称Tri-N-Butylphosphineoxide
中文名称三丁基氧化膦
IUPAC名称tributylphosphine oxide
其它别名W58Cdf8S4H; Tributylphosphine Oxide, 95%; Wln: Op4&4&4; Oseltamivir Phosphate Impurity H [ep Impurity]; 1-(Dibutylphosphoryl)Butane; Tris(1-Butyl)Phosphine Oxide; Tri-N-Butylpho
CAS编号814-29-9
MFCD编号:MFCD00002082
EINECS号:212-394-3
FDA UNII编号:W58CDF8S4H
分子式:C12H27OP
分子量:218.32
产品CID: 1807868
产品分类有机原料 → 有机膦化合物

相似结构搜索
产品信息参考
InChIKey: MNZAKDODWSQONA-UHFFFAOYSA-N
InChI=1S/C12H27OP/c1-4-7-10-14(13,11-8-5-2)12-9-6-3/h4-12H2,1-3H3…
计算化学: 氢键受体数1.0氢键供体数0.0可旋转键数9.0

MSDS等安全信息

GHS象形图
GHS符号GHS07 & GHS05;
注释: Exclamation mark & Corrosion
危险类别急性毒性类别4(吸入)
急性毒性类别4(经皮)
急性毒性类别4(经口)
皮肤腐蚀类别1B
特定目标器官毒性 - 单次接触类别3
严重眼损伤类别1
皮肤腐蚀类别1C
警示词Danger(危险)
危险描述H332 |吸入有害.
H312 |皮肤接触有害.
H302 |吞咽有害.
H314 |造成严重皮肤灼伤和眼损伤.
H335 |可能引起呼吸道刺激.
H318 |造成严重眼损伤.
防范说明P260-P280-P301+P312-P303+P361+P353-P304+P340+P310-P305+P351+P338
危险等级8
UN编号UN 1759 8/PG 2
危险品标志C
包装等级II
安全声明26-27-28-36/37/39-45
危险类别码20/21/22-34
WGK Germany3

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

n-butyl magnesium bromide tributylphosphine 1-bromo-butane dibutylphosphine oxidedi-n-butylphosphine P,P,P-Tributyl-N-(p-nitrophenylsulfonyl)-phoshinimid bis-[1-(dibutyl-phosphinoyl)-butyl]-phenyl-phosphane tributylphosphine

合成工艺路线路线简述

3084-50-2 = 814-29-9
反应条件:1.1 Reagents: Trifluoroacetic Anhydride Solvents: Dichloromethane
标题:Efficient Oxygenation Of Thiophosphoryl And Selenophosphoryl Groups Using Trifluoroacetic Anhydride
作者:Helinski,Jan; Et Al
参考文献:Tetrahedron Letters 日期:1990 卷标:31(28) 页码:4081-4]

3084-50-2 = 814-29-9
反应条件:1.1 Reagents: Dimethyldioxirane Solvents: Acetone,Dichloromethane
标题:Dimethyldioxirane Conversion Of Phosphine Sulfides And Phosphorothioates Into Their Corresponding Oxygen Analogs
作者:Sanchez-Baeza,Francisco; Et Al
参考文献:Tetrahedron Letters 日期:1990 卷标:31(23) 页码:3359-62]

998-40-3 = 814-29-9
反应条件:1.1 Reagents: Hydrogen Peroxide Solvents: Dichloromethane,Water; 20 °C; 3 H,20 °C
标题:The Trityl-Cation Mediated Phosphine Oxides Reduction
作者:Laye,Claire; Et Al
参考文献:Advanced Synthesis & Catalysis 日期:2021 卷标:363(12) 页码:3035-3043]

693-03-8 = 814-29-9
反应条件:1.1 Reagents: N-(Dichlorophosphinyl)Phosphorimidic Trichloride Solvents: Toluene,Tetrahydrofuran; 0.5 H,Rt; 48 H,Reflux
标题:The Reaction Of N-Dichlorophosphoryl-P,P,P-Trichlorophosphazene With Alkyl Grignard Reagents
作者:Aslan,F.; Et Al
参考文献:Heteroatom Chemistry 日期:2003 卷标:14(5) 页码:413-416]

= 814-29-9
反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Benzene,Water; 5 H,Rt
标题:Some Reacting Peculiarities Of Hydroxy Aminoderivatives Of Bisphosphonium Salts
作者:Ovakimyan,M. Zh.; Et Al
参考文献:Hayastani Kimiakan Handes 日期:2013 卷标:66(1) 页码:63-75]

21473-75-6 = 814-29-9 [标题:Reaction Conditions
标题:Formation Of Iodides And Esters From Alcohols And Tributyldiiodophosphorane And Diiodotriphenylphosphorane
作者:Haynes,Richard K.; Et Al
参考文献:Australian Journal Of Chemistry 日期:1982 卷标:35(3) 页码:517-24]

= 814-29-9 [标题:Reaction Conditions
标题:Photoreaction Of The Adduct Between (η5-Cyclopentadienyl)(1,2-Dicyano-1,2-Ethylenedithiolato)Cobalt(Iii) And Tributylphosphine. Oxygenation Of Coordinated Phosphine By Singlet Oxygen
作者:Hatano,Hiroshi; Et Al
参考文献:Chemistry Letters 日期:1990 卷标:(7) 页码:1089-92]

4233-13-0 = 814-29-9
反应条件:1.1 Reagents: Sodium Solvents: 1,4-Dioxane; 48 H,60 °C1.2 0.5 H,25 °C2.1 Reagents: Sodium Solvents: 1,4-Dioxane; 24 H,60 °C2.2 0.5 H,25 °C
标题:Selective C-P(O) Bond Cleavage Of Organophosphine Oxides By Sodium
作者:Zhang,Jian-Qiu; Et Al
参考文献:Journal Of Organic Chemistry 日期:2020 卷标:85(21) 页码:14166-14173]

199917-57-2 + 79-31-2 = 814-29-9 + 97-72-3 + 106937-41-1
反应条件:1.1 Solvents: Benzene
标题:Dehydration Induced By Intramolecular Redox Character Of A Stable Allylidenetributylphosphorane
作者:Kawamura,Yasuhiko; Et Al
参考文献:Tetrahedron Letters 日期:1997 卷标:38(45) 页码:7893-7896]

3084-50-2 = 814-29-9
反应条件:1.1 Reagents: Dimethyldioxirane Solvents: Acetone,Dichloromethane
标题:Dioxirane Oxidations Of Compounds Other Than Alkenes
作者:Adam,Waldemar; Et Al
参考文献:Organic Reactions (Hoboken 日期:2007 卷标:69 页码:1-346]

998-40-3 = 814-29-9
反应条件:1.1 Reagents: Molybdate(1-),(4-Aminobenzoato-Ko)Oxodiperoxy- (Polymer-Supported) Solvents: Dichloromethane
标题:Polymer Supported Anionic Peroxomolybdenum Complexes As New,Mild,Efficient And Versatile Oxidants In Organic Synthesis
作者:Tamami,Bahman; Et Al
参考文献:European Polymer Journal 日期:1999 卷标:35(8) 页码:1445-1450]

998-40-3 = 814-29-9
反应条件:1.1 Reagents: Potassium Tungstate (K2Wo4) (Amberlyst A-26 Bound) Solvents: 1,2-Dichloroethane
标题:Preparation And Applications Of A Polymer Supported Peroxotungstate Complex As A Novel Polymeric Oxidizing Agent
作者:Tamami,Bahman; Et Al
参考文献:Reactive & Functional Polymers 日期:2002 卷标:50(2) 页码:101-106]

10557-66-1 = 814-29-9
反应条件:1.1 Reagents: Sodium Solvents: 1,4-Dioxane; 24 H,60 °C1.2 0.5 H,25 °C
标题:Selective C-P(O) Bond Cleavage Of Organophosphine Oxides By Sodium
作者:Zhang,Jian-Qiu; Et Al
参考文献:Journal Of Organic Chemistry 日期:2020 卷标:85(21) 页码:14166-14173]

17921-92-5 = 814-29-9
反应条件:1.1 Solvents: Methanol; 16 H,Reflux
标题:Syntheses And Reactions Of The Bis-Boryl Oxide O(Bpin)2 (Pin = O2C2Me4)
作者:Hawkeswood,Sarah; Et Al
参考文献:Dalton Transactions 日期:2005 卷标:(12) 页码:2182-2187]

17921-92-5 = 814-29-9 [标题:Reaction Conditions
标题:Product Class 13: Triakylphosphine Oxides,Sulfides,Selenides,Tellurides,And Imides
作者:Kilah,N. L.; Et Al
参考文献:Science Of Synthesis 日期:2009 卷标:42 页码:595-632]

4963-91-1 = 814-29-9
反应条件:1.1 Solvents: Tetrahydrofuran,Hexane; 24 H,-78 °C -> Rt1.2 Reagents: Ammonium Chloride Solvents: Water; Rt
标题:Aryl Group - A Leaving Group In Arylphosphine Oxides
作者:Stankevic,Marek; Et Al
参考文献:Tetrahedron 日期:2016 卷标:72(6) 页码:810-824]

693-03-8 = 814-29-9
反应条件:1.1 Reagents: Phosphorus Oxychloride Solvents: Diethyl Ether; 0 °C1.2 Solvents: Methanol; 0 °C1.3 Reagents: Permanganic Acid (Hmno4),Potassium Salt (1:1) Solvents: Dichloromethane,Water
标题:Preparation Of Tri-N-Alkyl[32P]Phosphine Oxide For Latent Treatment Of Hepatic Tumors
作者:Choi,Kang-Hyuk; Et Al
参考文献:Journal Of The Korean Chemical Society 日期:2005 卷标:49(2) 页码:161-166]

15754-54-8 = 814-29-9
反应条件:1.1 Reagents: Potassium Hydroxide Solvents: Dimethyl Sulfoxide,Water1.2 -
标题:A Simple Synthesis And Some Synthetic Applications Of Substituted Phosphide And Phosphinite Anions
作者:Tsvetkov,E. N.; Et Al
参考文献:Synthesis 日期:1986 卷标:(3) 页码:198-208]

= 814-29-9
反应条件:1.1 Catalysts: Benzoic Acid Solvents: Tetrahydrofuran
标题:The Mechanism Of The Mitsunobu Reaction. Iii. The Use Of Tributylphosphine
作者:Camp,David; Et Al
参考文献:Australian Journal Of Chemistry 日期:1992 卷标:45(1) 页码:47-55]

2240-41-7 = 814-29-9
反应条件:1.1 Reagents: Sodium Solvents: 1,4-Dioxane; 24 H,60 °C1.2 0.5 H,25 °C2.1 Reagents: Sodium Solvents: 1,4-Dioxane; 24 H,60 °C2.2 0.5 H,25 °C
标题:Selective C-P(O) Bond Cleavage Of Organophosphine Oxides By Sodium
作者:Zhang,Jian-Qiu; Et Al
参考文献:Journal Of Organic Chemistry 日期:2020 卷标:85(21) 页码:14166-14173]

3049-24-9 = 814-29-9
反应条件:1.1 Reagents: Sodium Solvents: 1,4-Dioxane; 24 H,60 °C1.2 0.5 H,25 °C2.1 Reagents: Sodium Solvents: 1,4-Dioxane; 24 H,60 °C2.2 0.5 H,25 °C
标题:Selective C-P(O) Bond Cleavage Of Organophosphine Oxides By Sodium
作者:Zhang,Jian-Qiu; Et Al
参考文献:Journal Of Organic Chemistry 日期:2020 卷标:85(21) 页码:14166-14173]

791-28-6 = 814-29-9
反应条件:1.1 Reagents: Potassium Solvents: Tetrahydrofuran; Overnight,25 °C1.2 0.5 H,25 °C2.1 Reagents: Sodium Solvents: 1,4-Dioxane; 24 H,60 °C2.2 0.5 H,25 °C
标题:Selective C-P(O) Bond Cleavage Of Organophosphine Oxides By Sodium
作者:Zhang,Jian-Qiu; Et Al
参考文献:Journal Of Organic Chemistry 日期:2020 卷标:85(21) 页码:14166-14173]

= 814-29-9
反应条件:1.1 Reagents: Triethylamine,Hydroxyamine Hydrochloride Solvents: Chloroform; -2 °C; 2 D,Rt2.1 Reagents: Sodium Hydroxide Solvents: Benzene,Water; 5 H,Rt
标题:Some Reacting Peculiarities Of Hydroxy Aminoderivatives Of Bisphosphonium Salts
作者:Ovakimyan,M. Zh.; Et Al
参考文献:Hayastani Kimiakan Handes 日期:2013 卷标:66(1) 页码:63-75]

2446-83-5 + 998-40-3 = 814-29-9
反应条件:1.1 Solvents: Tetrahydrofuran2.1 Solvents: Water
标题:The Mechanism Of The Mitsunobu Reaction. Iii. The Use Of Tributylphosphine
作者:Camp,David; Et Al
参考文献:Australian Journal Of Chemistry 日期:1992 卷标:45(1) 页码:47-55]

1706-92-9 = 814-29-9
反应条件:1.1 Reagents: Sodium Solvents: 1,4-Dioxane; 24 H,60 °C1.2 0.5 H,25 °C2.1 Reagents: Sodium Solvents: 1,4-Dioxane; 48 H,60 °C2.2 0.5 H,25 °C3.1 Reagents: Sodium Solvents: 1,4-Dioxane; 24 H,60 °C3.2 0.5 H,25 °C
标题:Selective C-P(O) Bond Cleavage Of Organophosphine Oxides By Sodium
作者:Zhang,Jian-Qiu; Et Al
参考文献:Journal Of Organic Chemistry 日期:2020 卷标:85(21) 页码:14166-14173]

1706-96-3 = 814-29-9
反应条件:1.1 Reagents: Sodium Solvents: 1,4-Dioxane; 24 H,60 °C1.2 0.5 H,25 °C2.1 Reagents: Sodium Solvents: 1,4-Dioxane; 48 H,60 °C2.2 0.5 H,25 °C3.1 Reagents: Sodium Solvents: 1,4-Dioxane; 24 H,60 °C3.2 0.5 H,25 °C
标题:Selective C-P(O) Bond Cleavage Of Organophosphine Oxides By Sodium
作者:Zhang,Jian-Qiu; Et Al
参考文献:Journal Of Organic Chemistry 日期:2020 卷标:85(21) 页码:14166-14173

三丁基膦置于polystyrene-Bound Diaryl Telluroxide体系中,用氯仿作为反应溶剂,化学反应 0.6H,以89%的收率获得产物三正丁基氧化磷
参考文献:聚合物负载的二芳基硒氧化物和碲氧化物作为温和的选择性氧化剂
标题:聚合物负载的二芳基硒氧化物和碲氧化物作为温和的选择性氧化剂
摘要:已经制备了聚苯乙烯结合的二芳基硒氧化物和碲氧化物,它们作为硫醇到二硫化物,膦到氧化膦,对苯二酚和邻苯二酚到对和邻苯醌以及硫酮到氧代化合物的温和氧化剂.碲氧化物在比硒氧化物更短的时间内或在更温和的条件下完成这些反应.此外,他们还影响了硫代酰胺与 1,2,4-噻二唑或腈的新型溶剂依赖性反应,包括硫脲.在非酸性溶剂中,脱硫反应生成腈优先于氧化二聚反应生成 1,2,4-噻二唑,但酸性溶剂(如乙酸)促进了后者的反应.
DOI:10.1246/bcsj.59.879

海关参考信息

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专利信息

专利号:US-2023312617-A1
优先权日:2020-07-25
标题 :Process for synthesis of organosilicon compounds from halosilanes
发明人：DOLAI SUKANTA; BHAT SHREEDHAR; TARAFDAR GOURAV
权利人:MOMENTIVE PERFORMANCE MAT INC
摘要:A process for synthesis of an organosilicon compound is provided herein. Also, novel organosilicon compounds prepared by the present process is provided herein. The process comprises the reaction of a halosilane with an organofunctional alkyl halide in the presence of a metal catalyst, a promoter, and an optional co-catalyst. The process provides an efficient synthetic route to produce organosilicon compounds. The process also allows synthesis of organosilicon compounds with a plurality of different functional groups.

专利号:US-7615169-B2
优先权日:2004-09-20
标题 :Method for synthesis of colloidal nanoparticles
发明人：STROUSE GEOFFREY FIELDING; GERBEC JEFFREY A; MAGANA DONNY
权利人:UNIV CALIFORNIA
摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

专利号:US-7927516-B2
优先权日:2004-09-20
标题 :Method for synthesis of colloidal nanoparticles
发明人：STROUSE GEOFFREY F; GERBEC JEFFREY A; MAGANA DONNY
权利人:UNIV CALIFORNIA
摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

专利号:US-3742080-A
优先权日:1969-04-11
标题 :Rhodium based catalysts for the synthesis of 1,4-dienes
发明人：SU A
权利人:DU PONT
摘要:Improved catalysts are provided for the synthesis of 1,4-dienes from Alpha -monoolefins and conjugated dienes. The catalysts are rhodium (III) salts in combination with amides, phosphoramides, phosphine oxides, or water. The improved catalysts allow control of the trans-cis ratio of the 1,4-diene formed and are operable at useful rates in a wide range of solvent systems, both protonic and aprotic.

专利号:US-7465352-B2
优先权日:2004-07-23
标题:One-pot synthesis of high-quality metal chalcogenide nanocrystals without precursor injection
发明人：CAO YUNWEI CHARLES
权利人:UNIV FLORIDA
摘要:A method of homogeneously forming metal chalcogenide nanocrystals includes the steps combining a metal source, a chalcogenide source, and at least one solvent at a first temperature to form a liquid comprising assembly, and heating the assembly at a sufficient temperature to initiate nucleation to form a plurality of metal chalcogenide nanocrystals. The plurality of metal chalcogenide nanocrystals are then grown without injection of either the metal source or the chalcogenide source at a temperature at least equal to the sufficient temperature, wherein growth proceeds substantially without nucleation to form a plurality of monodisperse metal chalcogenide nanocrystals. An optional nucleation initiator can help control the final size of the monodisperse crystals. Such synthesis, without the need for precursor injection, is suitable for the industrial preparation of high-quality nanocrystals.

专利号:US-2006154380-A1
优先权日:2004-06-23
标题:Synthesis of ordered arrays from gold clusters
发明人：EGUSA SHUNJI; JIN RONGCHAO; SCHERER NORBERT F
权利人:EGUSA SHUNJI; JIN RONGCHAO; SCHERER NORBERT F
摘要:A nanocluster includes 1 to 7 metal atoms and has at least one ligand, which is associated with at least one of the metal atoms. A method of making a nanocluster consists of combining a nanoparticle, a ligand and a high boiling point solvent to provide a mixture and heating the mixture at a temperature of at least about 125Â° C. to form a nanocluster with 1 to 7 metal atoms. An ordered array of nanostructures includes a substrate and a plurality of nanostructures on the substrate, where the nanostructures are made by forming a solution of nanoclusters, depositing the solution on a substrate, and heating the substrate.