CAS: 1220616-44-3; (2S,3R,4S,5R,6R)-5-Hydroxy-6-(Hydroxymethyl)-3,4-Bis(((2S,3R,4S,5S,6R)-3,4,5-Trihydroxy-6-(Hydroxymethyl)Tetrahydro-2H-Pyran-2-yl)Oxy)Tetrahydro-2H-Pyran-2-Yl (4R,4As,6Ar,9S,11Ar,11Bs)-9-(((2S,3R,4S,5R,6R)-5-Hydroxy-6-(Hydroxymethyl)-3,4-Bis(((2S,3R,4S,5S,6R)-3,4,5-Trihydroxy-6-(Hydroxymethyl)Tetrahydro-2H-Pyran-2-yl)Oxy)Tetrahydro-2H-Pyran-2-yl)Oxy)-4,11B-Dimethyl-8-Methylenetetradecahydro-6A,9-Methanocyclohepta[a]Naphthalene-4-Carboxylate

该化合物是来自Stevia rebaudiana 植物叶叶子的高密度,非热量甜食器. 作为石灰石,它表现出超甜的威力 --比sucrosse甜约200-350倍 --同时保持清洁的,类似糖的口味,与其他食用提取物相比,它苦度或后期味都最低. Reb M 具有热度和pH-稳定性,因此适合广泛的食品和饮料应用. 它的低糖性影响和非致癌性能与饮食和健康意识配方相一致. 该化合物通常通过酶生物转化或发酵产生,确保工业用途的可缩放性和纯度. 关键市场的监管批准进一步支持其商业可行性.

英文名称(2S,3R,4S,5R,6R)-5-Hydroxy-6-(Hydroxymethyl)-3,4-Bis(((2S,3R,4S,5S,6R)-3,4,5-Trihydroxy-6-(Hydroxymethyl)Tetrahydro-2H-Pyran-2-yl)Oxy)Tetrahydro-2H-Pyran-2-Yl (4R,4As,6Ar,9S,11Ar,11Bs)-9-(((2S,3R,4S,5R,6R)-5-Hydroxy-6-(Hydroxymethyl)-3,4-Bis(((2S,3R,4S,5S,6R)-3,4,5-Trihydroxy-6-(Hydroxymethyl)Tetrahydro-2H-Pyran-2-yl)Oxy)Tetrahydro-2H-Pyran-2-yl)Oxy)-4,11B-Dimethyl-8-Methylenetetradecahydro-6A,9-Methanocyclohepta[a]Naphthalene-4-Carboxylate
中文名称瑞鲍迪甙M
IUPAC名称(2S,3R,4S,5R,6R)-5-hydroxy-6-(hydroxymethyl)-3,4-bis(((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)tetrahydro-2H-pyran-2-yl (4R,4aS,6aR,9S,11aR,11bS)-9-(((2S,3R,4S,5R,6R)-5-hydroxy-6-(hydroxymethyl)-3,4-bis(((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)tetrahydro-2H-pyran-2-yl)oxy)-4,11b-dimethyl-8-methylenetetradecahydro-6a,9-methanocyclohepta[a]naphthalene-4-carboxylate
其它别名Reb M; Fqa8Xmc4Xj; Reb-M; Beta-D-Glucopyranosyl-(1->2)-[beta-D-Glucopyranosyl-(1->3)]-1-O-(13Alpha-{[beta-D-Glucopyranosyl-(1->2)-[beta-D-Glucopyranosyl-(1->3)]-Beta-D-Glucopyranosyl]Oxy}-18-Oxo-5Beta,8Alpha,9Beta,10Alpha-Kaur-1
CAS编号1220616-44-3
MFCD编号:MFCD31916341
FDA UNII编号:FQA8XMC4XJ
分子式:C56H90O33
分子量:1291.3
产品CID: 315116
产品分类食品添加剂 → 甜味剂

相似结构搜索
InChIKey: GSGVXNMGMKBGQU-SWXNTNRLSA-N
GSGVXNMGMKBGQU-UVTQADMRNA-N…
计算化学: 氢键受体数33.0氢键供体数20.0可旋转键数19.0

MSDS等安全信息

警示词Warning
危险描述H302-H315-H319-H335
防范说明P261-P305+P351+P338
WGK Germany3.0

上下游产品

UDP-glucose rebaudioside A rebaudioside DD-glucose

合成工艺路线路线简述

在 Potassium Carbonate体系中,用甲醇用作溶剂,以58%的收率获得瑞鲍迪甙m
参考文献:Novel Process For The Preparation Of Rebaudioside D And Other Related Naturally occurring Sweetners
标题:Novel Process For The Preparation Of Rebaudioside D And Other Related Naturally occurring Sweetners
摘要:提供了一种制备雷巴甙d(rd)和其他相关天然甜味剂的新工艺.Rd是一种天然甜味剂,可以减少史蒂维奥甙的苦涩余味.该工艺适用于商业生产,使用易获得的天然产品和无毒试剂.

海关参考信息

2901210000-乙烯
2901220000-丙烯
2905122000-异丙醇
2905143000-叔丁醇
💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
详情请参考：📖 海关编码查询和海关进出口税则

专利信息

专利号:WO-2024042405-A1
优先权日:2022-08-26
标题:Compositions and methods for the synthesis of bio-based polymers
发明人：OLIVEIRA ANA; CAPÃŠTO ANA PAULA; PINTADO MANUELA
权利人:AMYRIS BIO PRODUCTS PORTUGAL UNIPESSOAL LTDA; UNIV CATOLICA PORTUGUESA
摘要:The present disclosure provides compositions and methods for the synthesis of bio-based polymers (e.g., polyurethanes and polyesters) from secondary materials produced during a fermentation process. The disclosure also features intermediates produced during these processes, as well as compositions containing the same.

专利号:US-10533205-B1
优先权日:2013-10-09
标题:Kaurenoic acid glycoside precursors and methods of synthesis
发明人：ZIPP BRANDON
权利人:VITALITY BIOPHARMA INC
摘要:Ent-kaurenoic acid glycoside precursor compositions and synthesis methods are provided. The KA-19-monoside, KA-19-bioside and KA-19-trioside precursors can be used as starting materials for a variety of kaurenoic acid based reactions. The precursors provide alternative synthesis pathways for steviol glycosides to the natural pathway based on Steviol biosynthesis. The alternative synthesis pathways using the precursors also circumvent the rate limiting step of the natural Steviol biosynthesis pathway. The precursors can be used individually or in combination to produce a mixture or individual steviol glycosides such as Rebaudioside A, Rebaudioside D or Rebaudioside M. Control over the precursor quantities and composition allows control over the composition of the resulting steviol glycosides that are finally produced.

专利号:US-2024287479-A1
优先权日:2021-08-23
标题 :Glycosyltransferase mutant, and method for catalytic synthesis of rebaudioside m using glycosyltransferase mutant

专利号:EP-4365285-A1
优先权日:2021-08-23
标题:Glycosyltransferase mutant and method for catalytic synthesis of rebaudioside m by means of using same

专利号:WO-2023024828-A1
优先权日:2021-08-23
标题 :Glycosyltransferase mutant and method for catalytic synthesis of rebaudioside m by means of using same

专利号:CN-113186141-B
优先权日:2021-04-08
标题:A kind of method of efficient synthesis of rebaudioside M by one-pot method