CAS: 105-05-5; 1,4-Diethylbenzene

该化合物是一种芳烃,其特征是,在1和4个位置的苯环上存在两个乙基组,其分子式为C10H14,其分子重量约为134.22克/摩尔.该化合物在室内温度上是一种无色液体,具有甜味,芳香味,在水中不溶解,但在乙醇和乙醚等有机溶剂中可溶解. 1,4-二乙基苯主要用作各种化学品合成的中间体,也可用作工业用途的溶剂.该化合物具有中等挥发性,可易燃,需要小心处理和储存.该化合物的化学再活性包括典型的芳香化合物的电益替代反应.安全数据表明,该化合物可能会对皮肤和眼睛产生刺激,长期接触可能会对健康产生影响,同时强调在与该物质打交道时必须使用适当的个人防护设备.

结构式图片

欧盟法规

REACH注册ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

CAS号937-30-4 对乙基苯乙酮 | CAS号1009-61-6 1,4-二乙酰苯 | CAS号71-43-2 苯 | CAS号54509-73-8 ethene | CAS号100-41-4 乙苯 | CAS号64-17-5 乙醇 | CAS号64-67-5 硫酸二乙酯 | CAS号100-12-9 对乙基硝基苯 | CAS号25309-65-3 4-乙基苯甲腈 | CAS号619-64-7 对乙基苯甲酸 | CAS号40787-48-2 1,4-二溴-2,5-二乙基苯 | CAS号937-30-4 对乙基苯乙酮 | CAS号1009-61-6 1,4-二乙酰苯 | CAS号33967-18-9 1-(4-ethylbenze... | CAS号61750-19-4 1-ethyl-4-(1-hy... | CAS号6781-43-7 1-[4-(1-hydroxy... | CAS号619-64-7 对乙基苯甲酸 | CAS号586-89-0 4-乙酰基苯甲酸

合成工艺路线路线简述

    对乙基苯甲酸置于盐酸,Amalgamated Zinc,Thorium Dioxide体系中,化学反应生成1,4-二乙基苯
    参考文献:Birch Et Al.,Journal Of The American Chemical Society,1949,Vol. 71,P. 1362,1366
    标题:Birch Et Al.,Journal Of The American Chemical Society,1949,Vol. 71,P. 1362,1366

    海关参考信息

    专利信息


    专利号:US-8975358-B2
    优先权日:2010-07-23
    标题 :Compositions and methods for synthesis of organic-silica hybrid materials
    发明人:SHEA KENNETH J; HU LI-CHIH
    权利人:SHEA KENNETH J; HU LI-CHIH; UNIV CALIFORNIA
    摘要:The present invention relates to compositions and methods for synthesis of organic-silica hybrid microparticles and nanoparticles. In particular, the present invention provides compositions and methods for particle size control during synthesis of organic-silica hybrid microparticles and nanoparticles.

    专利号:US-4940803-A
    优先权日:1988-05-23
    标题:Process for synthesis of 1R,2R,5R-2-hydroxy-6-oxo-7-oxabicyclo[3.2.1]-octane
    发明人:MILLS SANDER G; VOLANTE RALPH P; SHINKAI ICHIRO
    权利人:MERCK & CO INC
    摘要:A process is described for the synthesis of hydroxy lactone 3, being 1R, 2R, 5R-2-hydroxy-6-oxo-7-oxabicyclo[3.2.1]-octane, in optically pure form, which is useful as an intermediate in the synthesis of the C 20 -C 34 chain of the macrolide structure for the immunosuppressant FK-506. This compound is also useful as a precursor for producing an ultraviolet radiation absorber.

    专利号:US-2003162992-A1
    优先权日:2001-12-14
    标 题 :Preparation of intermediates useful in the synthesis of antiviral nucleosides
    发明人:WATANABE KYOICHI A; DU JINFA
    摘要:The present invention is an efficient process for the manufacture of α-acyloxyacetaldehyde, a key intermediate in the synthesis of 1,3-oxathiolane and 1,3-dioxolane nucleosides.

    专利号:US-5239023-A
    优先权日:1990-10-24
    标 题 :Process for the synthesis of crystallizable 3,4-polyisoprene and isoprene-butadiene copolymers having high vinyl contents
    发明人:HSU WEN-LIANG; HALASA ADEL F
    权利人:GOODYEAR TIRE & RUBBER
    摘要:Crystallizable 3,4-polyisoprene and isoprene-butadiene copolymers having high vinyl contents can be synthesized in organic solvents to quantitative yields after short polymerization times by utilizing the catalyst systems of this invention. The 3,4-polyisoprene made utilizing this catalyst system is strain crystallizable and can be employed in tire treads which provide improved traction and improved cut growth resistance. This invention specifically discloses a process for the synthesis of 3,4-polyisoprene which comprises polymerizing isoprene monomer in an organic solvent at a temperature which is within the range of about -10 DEG C. to about 100 DEG C. in the presence of a catalyst system which is comprised of (a) an organoiron compound which is soluble in the organic solvent, wherein the iron in the organoiron compound is in the +3 oxidation state, (b) a partially hydrolyzed organoaluminum compound which was prepared by adding a protonic compound selected from the group consisting of water, alcohols and carboxylic acids to the organoaluminum compound, and (c) a chelating aromatic amine; wherein the molar ratio of the chelating amine to the organoiron compound is within the range of about 0.1:1 to about 1:1, wherein the molar ratio of the organoaluminum compound to the organoiron compound is within the range of about 5:1 to about 200:1, and wherein the molar ratio of the protonic compound to the organoaluminum compound is within the range of about 0.001:1 to about 0.2:1.

    专利号:US-5061765-A
    优先权日:1990-10-22
    标题:Process for the synthesis of a high vinyl isoprene-butadiene copolymer
    发明人:HSU WEN-LIANG; HALASA ADEL F
    权利人:GOODYEAR TIRE & RUBBER
    摘要:Isoprene-butadiene copolymers having high vinyl contents can be synthesized in organic solvents to high yields after short polymerization times by utilizing the process of this invention. The isoprene-butadiene copolymers made utilizing the process of this invention have a glass transition temperature which is within the range of about 0° C. to about -60° C. and can be employed in tire treads which provide improved traction and improved cut growth resistance. This invention specifically discloses a process for the synthesis of isoprene-butadiene copolymers having a high vinyl content which comprises copolymerizing isoprene monomer and butadiene monomer in an organic solvent at a temperature which is within the range of about -10° C. to about 100° C. in the presence of a catalyst system which is comprised of (a) an organoiron compound, (b) an organoaluminum compound, (c) a chelating aromatic amine, and (d) a protonic compound; wherein the molar ratio of the chelating amine to the organoiron compound is within the range of about 0.1:1 to about 1:1, wherein the molar ratio of the organoaluminum compound to the organoiron compound is within the range of about 5:1 to about 200:1, and wherein the molar ratio of the protonic compound to the organoaluminum compound is within the range of about 0.001:1 to about 0.2:1.

    专利号:US-5151398-A
    优先权日:1990-10-24
    标 题 :Catalyst for the synthesis of crystalline 3,4-polyisoprene
    发明人:HSU WEN-LIANG; HALASA ADEL F
    权利人:GOODYEAR TIRE & RUBBER
    摘要:Crystallizable 3,4-polyisoprene can be synthesized in organic solvents to quantitative yields after short polymerization times by utilizing the catalyst systems of this invention. The 3,4-polyisoprene made utilizing this catalyst system is strain crystallizable and can be employed in tire treads which provide improved traction and improved cut growth resistance. This invention specifically discloses a process for the synthesis of 3,4-polyisoprene which comprises polymerizing isoprene monomer in an organic solvent at a temperature which is within the range of about -10° C. to about 100° C. in the presence of a catalyst system which is comprised of (a) an organoiron compound, (b) an organoaluminum compound, (c) a chelating aromatic amine, and (d) a protonic compound; wherein the molar ratio of the chelating amine to the organoiron compound is within the range of about 0.1:1 to about 1:1, wherein the molar ratio of the organoaluminum compound to the organoiron compound is within the range of about 5:1 to about 200:1, and wherein the molar ratio of the protonic compound to the organoaluminum compound is within the range of about 0.001:1 to about 0.2:1.
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    主要参考文献

    参考标题:Inbr3-Catalyzed Reduction Of Ketones With A Hydrosilane: Deoxygenation Of Aromatic Ketones And Selective Synthesis Of Secondary Alcohols And Symmetrical Ethers From Aliphatic Ketones
    作者:Norio Sakai,Ken Nagasawa,Reiko Ikeda,Yumi Nakaike,Takeo Konakahara |发布日期:2011.6
    摘要:An Inbr3-Et3Sih Reducing System Was Developed To Selectively Convert Aliphatic Ketones To A Variety Of Secondary Alcohols In Moderate To Good Yields. An Initial Mixing Of Inbr3 And Phsih3 Was Followed By The Addition Of Aliphatic Ketones And A Solvent To Afford The Symmetrical Ether Derivatives.

    合成参考文献


    摘要:Davies, H. M. L.; Morton, D., Science of Synthesis: Stereoselective Synthesis, (2011) 3, 551.
    摘要:Singh, F. V.; Wirth, T., Science of Synthesis: Catalytic Oxidation in Organic Synthesis, (2017) 1, 54.
    摘要:Selt, M.; Waldvogel, S. R., Science of Synthesis: Special Topics, (2021) 1, 270.
    摘要:Sax, N.I. Dangerous Properties of Industrial Materials. 6th ed. New York, NY: Van Nostrand Reinhold, 1984., p. 1004
    摘要:IATA. Dangerous Goods Regulations. 40th Ed. Montreal, Canada and Geneva, Switzerland: International Air Transport Association, Dangerous Goods Regulations, 1999., p. 141
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