CAS: 13877-91-3; β-Ocimene

该化合物是一种高纯度单极碳氢化合物,主要用于香气配制,调味和特殊化学应用,其特有的木质,柑橘状芳香在香水和芳香中具有价值.作为基本油的天然成分,它也作为有机合成的中间体.高纯度(>90%)确保了性能的连贯性,减少了最终产品的可变性.其低粘度和挥发性便于纳入配方.此外,B-Ocimene在农业化学和制药研究中表现出作为生物活性化合物的潜力.产品通常作为一种清晰,无色的液体供应,具有稳定的储存特性,以便在推荐的条件下保持完整性.

结构式图片

相似化合物

13877-91-3 77898-97-6

欧盟法规

REACH注册ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

pyridine geranyl bromide (+)-α-pinene 2,6-dimethyl-hepta-1,5-diene(E,E)-2,6-dimethyl-2,4,6-°Ctatriene allo°Cimene 7-acetoxy-3,7-dimethyl-°Cta-1,3-diene 3,7-dimethyl°Cta-1,6-dien-3-ol

合成工艺路线路线简述

    2,6-二甲基庚-1,5-二烯置于potassium Tert-Butylate,三乙胺体系中,用 四氢呋喃,二氯甲烷,叔丁醇 用作溶剂,化学反应生成罗勒烯
    参考文献:.Alpha.-Haloalkanesulfonyl Bromides In Organic Synthesis. 5. Versatile Reagents For The Synthesis Of Conjugated Polyenes,Enones,And 1,3-Oxathiole 1,1-Dioxides
    标题:.Alpha.-Haloalkanesulfonyl Bromides In Organic Synthesis. 5. Versatile Reagents For The Synthesis Of Conjugated Polyenes,Enones,And 1,3-Oxathiole 1,1-Dioxides
    摘要:
    Doi:10.1021/ja00275A051

    海关参考信息

    专利信息


    专利号:US-9988349-B2
    优先权日:2014-01-03
    标 题:Direct stereospecific synthesis of unprotected aziridines from olefins
    发明人:ESS DANIEL HALSELL; FALCK JOHN RUSSELL; JAT JAWAHAR LAL; KURTI LASZLO
    权利人:ESS DANIEL HALSELL; FALCK JOHN RUSSELL; JAT JAWAHAR LAL; KURTI LASZLO
    摘要:A method for the direct stereospecific conversion of structurally diverse mono-, di-, tri- and tetra-substituted olefins to N—H, N-alkyl, N-cycloalkyl, or N-aralkyl aziridines using a hydroxylamine amination agent with transition metal catalyst. The method is operationally simple (i.e., one-pot), scalable and fast at ambient temperature.

    专利号:US-2013122562-A1
    优先权日:2011-08-04
    标 题:Production of isoprene, isoprenoid precursors, and isoprenoids using acetoacetyl-coa synthase
    发明人:ALDOR ILANA S; BECK ZACHARY Q; MILLER MICHAEL C; PERES CAROLINE M
    权利人:ALDOR ILANA S; BECK ZACHARY Q; MILLER MICHAEL C; PERES CAROLINE M; DANISCO US INC
    摘要:This invention relates to a recombinant microorganism capable of producing isoprene and isoprene production with the use of such recombinant microorganism with good efficiency. In this invention, the acetoacetyl-CoA synthase gene encoding an enzyme capable of synthesizing acetoacetyl-CoA from malonyl-CoA and acetyl-CoA and one or more genes involved in isoprene biosynthesis that enables synthesis of isoprene from acetoacetyl-CoA are introduced into a host microorganism.

    专利号:US-8957260-B2
    优先权日:2011-02-07
    标题 :Process for the oxidation of mesitol
    发明人:WEYRAUCH JAN PHILIPP; WEIS MARTINE; TELES JOAQUIM HENRIQUE; EBEL KLAUS; DEGLMANN PETER
    权利人:WEIS MARTINE; TELES JOAQUIM HENRIQUE; EBEL KLAUS; DEGLMANN PETER; WEYRAUCH VIVIEN ELLINOR; WEYRAUCH GUNHILD; BASF SE
    摘要:The invention relates to a process for the oxidation of mesitol with singlet oxygen, which is released from hydrogen peroxide, this release taking place in the presence of a bismuth compound as catalyst. In the process, 2,4,6-trimethylquinol is formed in high yield and selectivity as product, which can be used in further reactions for the synthesis of vitamins and in particular of vitamin A and vitamin E.

    专利号:US-2022162188-A1
    优先权日:2019-01-15
    标 题:Isoprenoids and methods of making thereof
    发明人:WILLIAMS GAVIN; LUND SEAN; HALL RACHAEL
    权利人:UNIV NORTH CAROLINA STATE
    摘要:Disclosed are methods for preparing isoprenoid subunits, as well as methods of employing these isoprenoid subunits for the synthesis of isoprenoids. Also provided are isoprenoids prepared using the methods described herein.

    专利号:US-4467118-A
    优先权日:1982-03-03
    标题 :Process for the catalytic synthesis of conjugated dienes from dialkylallylamines
    发明人:CHALK ALAN J; MAGENNIS STEVEN A; WERTHEIMER VASILE S; NAIPAWER RICHARD E
    权利人:GIVAUDAN CORP
    摘要:There is disclosed a novel process for converting allylic amines, having a hydrogen bonded to a carbon δ to the amino group, to a diene in the presence of a zero valent palladium phosphine complex and a weak acid. The process has been used to make novel compositions containing 7-methoxy-3,7-dimethyloctadienes which are useful as odorants and flavorants.

    专利号:US-2022162180-A1
    优先权日:2020-11-24
    标题 :Cannabinol-o-acetate synthesis, compositions, and methods of use
    发明人:OPPERMAN ROBERT; BRISSETTE QUINCY ALEXANDER
    权利人:Marquette Analytica
    摘要:A cannabinol derivative, cannabinol-o-acetate, synthesis, compositions comprising the same, and methods of use.
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    主要参考文献

    [参考文献]: Ali Abdollahi, Et Al. Evaluation Of Essential Oils For Maintaining Postharvest Quality Of Thompson Seedless Table Grape. Nat Prod Res. 2012;26(1):77-83.
    [参考文献]: Bruno Marongiu, Et Al. Comparative Analysis Of The Oil And Supercritical Co2 Extract Of Ridolfia Segetum (L.) Moris. Nat Prod Res. 2007 May;21(5):412-7.
    [参考文献]: D M Suckling, Et Al. Volatiles From Apple Trees Infested With Light Brown Apple Moth Larvae Attract The Parasitoid Dolichogenidia Tasmanica. J Agric Food Chem. 2012 Sep 26;60(38):9562-6.
    [参考文献]: Daekyun Kim, Et Al. Rate Constants For The Gas-Phase Reactions Of Oh And O3 With β-Ocimene, β-Myrcene, And α- And β-Farnesene As A Function Of Temperature. J Phys Chem A. 2011 Feb 3;115(4):500-6.
    [参考文献]: Gen-Ichiro Arimura, Et Al. Effects Of Feeding Spodoptera Littoralis On Lima Bean Leaves: Iv. Diurnal And Nocturnal Damage Differentially Initiate Plant Volatile Emission. Plant Physiol. 2008 Mar;146(3):965-73.

    合成参考文献


    参考文献:10.1007/s10886-011-9993-5
    摘要:Gols R, Bullock JM, Dicke M, Bukovinszky T, Harvey JA. Smelling the Wood from the Trees: Non-Linear Parasitoid Responses to Volatile Attractants Produced by Wild and Cultivated Cabbage. Journal of Chemical Ecology. 2011 Jul 12;37(8):795. doi: 10.1007/s10886-011-9993-5.
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