专利号:US-9512250-B2 优先权日:2012-02-23 标 题 :Manganese catalyzed photopolymerization of fluorinated monomers 发明人:ASANDEI ALEXANDRU D 权利人:UNIV CONNECTICUT 摘要:The disclosure discloses initiating systems for the radical polymerization of alkenes, and especially fluorine substituted alkenes. The polymerization is catalyzed by a metal carbonyl, preferably manganese carbonyl. The polymerization is initiated directly from alkyl halides at room temperature under visible white light. The polymers also allow the synthesis of block copolymers. The process comprises polymerizing at least one alkene monomer in the presence of a halide radical initiator, carbonyl catalyst and a solvent, under reaction conditions and for a time sufficient to polymerize the at least one alkene monomer to form a polymer. The present disclosure provides a method for living polymerization of alkene monomers which provides a high level of macromolecular control over the polymerization process and which leads to uniform and controllable polymeric products. This disclosure also provides a method for activating any halide (Cl, Br, I) chain ends of such polymers for the synthesis of block copolymerizations.
专利号:US-9505687-B2 优先权日:2015-02-27 标 题 :Synthesis of diiodoperfluoro-C3 to C7-alkanes 发明人:HUNG MING HONG; MARCHIONE ALEXANDER ANTHONY; MORKEN PETER A 权利人:CHEMOURS CO FC LLC 摘要:The present invention is the process comprising forming a stable mixture comprising I(CF 2 ) n I, wherein n is at least 3 and at least one of I(CF 2 ) n I, wherein n is 1 or 2, as a contaminant in said mixture and heating said mixture to a temperature of at least 220° C. to reduce the amount of said contaminant to be no greater than 1% when said contaminant is ICF 2 I (n=1) and no greater than 0.1% when said contaminant is ICF 2 CF 2 I (n=2).
专利号:US-2016251285-A1 优先权日:2015-02-27 标 题:Synthesis of diiodoperfluoro-c3 to c7-alkanes
专利号:US-4833274-A 优先权日:1985-04-04 标题:Perfluoroalkanes and haloperfluoroalkanes, their percursors and process for their synthesis 发明人:CAPORICCIO GERARDO; BARGIGIA GIANANGELO; TONELLI CLAUDIO; TORTELLI VITO 权利人:AUSIMONT SPA 摘要:New perfluoroalkanes and haloperfluoroalkanes, having low melting point and high thermal and chemical stability, constituted by preferably branched perfluorinated and haloperfluorinated chains, obtained by starting from precursors containing two halogen atoms equal to or different from each other, one of them necessarily being an iodine atom, which are reacted with C3F6 and possibly subsequently halogenated with either fluorine or chlorine or bromine.
专利号:EP-3271318-B1 优先权日:2015-02-27 标题 :Synthesis of diiodoperfluoro-c3 to c7-alkanes
专利号:EP-3271318-A1 优先权日:2015-02-27 标 题:Synthesis of diiodoperfluoro-c3 to c7-alkanes
参考文献:10.1021/ja710267u 摘要:Lee JH, Kim TK, Kim J, Kong Q, Cammarata M, Lorenc M, Wulff M, Ihee H. Capturing transient structures in the elimination reaction of haloalkane in solution by transient X-ray diffraction. J Am Chem Soc. 2008 May 07;130(18):5834–5. doi: 10.1021/ja710267u. 摘要:S14 | KEMIPFAS | PFAS Highly Fluorinated Substances List from KEMI | DOI:10.5281/zenodo.2621524 摘要:S89 | PRORISKPFAS | List of PFAS Compiled from NORMAN SusDat | DOI:10.5281/zenodo.5769582