专利号:US-9763452-B2 优先权日:2012-06-11 标 题 :Synthesis of MOFs 发明人:MORRIS RUSSELL EDWARD; WHEATLEY PAUL STEWART; WARRENDER STEWART; DUNCAN MORVEN 权利人:UNIV COURT UNIV ST ANDREWS; UNIVERISTY COURT OF THE UNIV OF ST ANDREWS 摘要:The present invention relates to the synthesis of a variety of metal organic frameworks (MOFs) using low temperature and solvents which are considered to be not particularly harmful to the environment. There is also provided novel MOFs which may be made by the desired processes.
专利号:US-2022297083-A1 优先权日:2019-08-27 标 题 :Continuous Synthesis Of Porous Coordination Polymers In Supercritical Carbon Dioxide 发明人:RASMUSSEN ELIZABETH G; KRAMLICH JOHN C; NOVOSSELOV IGOR V 权利人:UNIV WASHINGTON 摘要:This disclosure relates generally relates to methods and systems useful for continuous synthesis of materials in super-critical carbon dioxide (sCO 2 ). More particularly, this disclosure relates to methods and systems useful for continuous synthesis of coordination polymers, such as metal-organic frameworks (MOFs) and/or covalent organic frameworks (COFs), in sCO 2 .
专利号:US-4895922-A 优先权日:1988-05-05 标 题 :Low temperature synthesis of polyesteramides 发明人:OGATA NAOYA 权利人:GOODYEAR TIRE & RUBBER 摘要:This invention disclosed a process for the synthesis of polyesteramides. By utilizing the phosphorus containing catalyst systems of the present invention, such polyesteramides can be synthesized at relatively low temperatures. The present invention specifically discloses a process for the synthesis of a polyesteramide which comprises polymerizing at least one diamine, at least one diol, and at least one dicarboxylic acid in the presence of (1) at least one acid acceptor; (2) at least one halogenated organic compound; and (3) at least one phosphorus containing compound selected from the group consisting of (a) triphenylphosphine, (b) triphenylphosphine oxide, (c) triphenylphosphine sulfide, (d) polymeric agents having pendant diphenylphosphine groups, (e) silicon-phosphorus compositions which contain at least one divalent oxygen atom which is bonded directly to a tetravalent silicon atom and a trivalent or pentavalent phosphorus atom; (f) compounds with the structural formula (C 6 H 5 ) 3 P=N-R, wherein R is a hydrogen atom or an alkyl group containing from 1 to 10 carbon atoms; and (g) compounds with the structural formula (C 6 H 5 )PR 1 R 2 wherein R 1 and R 2 can be the same or different, wherein R 1 is selected from the group consisting of alkyl groups containing from 1 to 10 carbon atoms and phenyl groups, and wherein R 2 is an alkyl group containing from 1 to 10 carbon atoms.
专利号:US-12146136-B2 优先权日:2020-03-26 标题:Synthesis of modified oligonucleotides with increased stability 发明人:KHVOROVA ANASTASIA; ROUX LOÃ?C MAURICE RENÉ JEAN; YAMADA KEN 权利人:UNIV MASSACHUSETTS 摘要:This disclosure relates to the synthesis of novel modified oligonucleotides. The synthesis of novel phosphoramidites are also provided.
专利号:US-12263464-B2 优先权日:2018-03-14 标题 :Method for in-situ synthesis of metal organic frameworks (MOFs), covalent organic frameworks (COFs) and zeolite imidazolate frameworks (ZIFs), and applications thereof 发明人:PAHWA DEEPAK; PAHWA VARUN; CHOUDHARY ANIL KUMAR; SONIA; JHA VIVEK KUMAR; CHAUHAN ANJALI; YADAV ANNU 权利人:DESICCANT ROTORS INTERNATIONAL PRIVATE LTD 摘要:The present invention relates to a method for the in situ synthesis of of MOFs (metal organic frameworks), COFs (covalent organic frameworks), and ZIFs (Zeolitic imidazolate framework), onto and within different types of porous substrates, and their applications. The present invention provides a unique and easy to utilize method by which a number of MOFs, COFs and ZIFs can be synthesized directly onto and within a porous substrate with high performance efficiency ensuring higher grammage in formation of adsorbent product onto and within the substrate.
专利号:US-4923839-A 优先权日:1987-02-05 标题:Low temperature synthesis of condensation polymers 发明人:OGATA NAOYA 权利人:GOODYEAR TIRE & RUBBER 摘要:Condensation polymers of high molecular weight, such as polyesters, polyureas, and polyamides, are usually prepared at temperatures of 200° C. or greater. However, by utilizing the catalyst systems of the present invention, condensation polymers can be synthesized at much lower temperatures. The polycondensation catalyst systems of the present invention are particularly useful for synthesizing aliphatic polyesters, such as polyethylene terephthalate, from dicarboxylic acids and aliphatic glycols. The present invention more specifically discloses a process for the synthesis of an aliphatic polyester comprising polymerizing at least one dicarboxylic acid with at least one aliphatic glycol in the presence of (1) at least one phosphorus containing compound which contains at least one trivalent or pentavalent phosphorus atom which is bonded directly to at least one phenyl group, (2) an acid acceptor, and (3) at least one halogenated organic compound. It is preferred to utilize a polymeric agent having bound acid acceptor groups as the acid acceptor in the process of the present invention.
1. Lian, W., Upadhyaya, P., Rhodes, C.A., et al. Screening bicyclic peptide libraries for protein-protein interaction inhibitors: Discovery of a tumor necrosis factor-α antagonist. Journal of the American Chemical Society 135(32), 11990-11995 (2013).
合成参考文献
参考文献:10.1107/s160053681101436x 摘要:Sun L, Qiu TR, Deng H. catena-Poly[[octaaquabis(μ4-benzene-1,3,5-tricarboxylato)trizinc] tetrahydrate]. Acta Crystallogr E Struct Rep Online. 2011 Apr 22;67(5):m630–1. doi: 10.1107/s160053681101436x. 参考文献:10.1107/s1600536811015844 摘要:Maniam P, Stock N. Poly[(μ3-benzene-1,3,5-tricarboxylato-κ3O1:O3:O5)(μ2-2-methylimidazolato-κ2N:N′)tris(2-methylimidazole-κN)dizinc(II)]. Acta Crystallogr E Struct Rep Online. 2011 May 07;67(6):m669–70. doi: 10.1107/s1600536811015844. 参考文献:10.1107/s1600536811019507 摘要:Liu Y, Li Y, Wang X, Yang E. Diaquabis[5-(2-pyridylmethyl)tetrazolato-κ2N1,N5]zinc(II). Acta Crystallogr E Struct Rep Online. 2011 May 28;67(6):m803. doi: 10.1107/s1600536811019507. 参考文献:10.1107/s1600536811019519 摘要:Mei C, Li K, Shan W. Diaqua(5-carboxybenzene-1,3-dicarboxylato-κO1)(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)zinc. Acta Crystallogr E Struct Rep Online. 2011 May 28;67(6):m804. doi: 10.1107/s1600536811019519. 参考文献:10.1002/asia.201100431 摘要:Liu J, Zhang X, Wang D, Wang JY, Pei J, Stang PJ, Wan LJ. Shape-persistent two-component 2D networks with atomic-size tunability. Chem Asian J. 2011 Sep 05;6(9):2426–30. doi: 10.1002/asia.201100431.