CAS: 90-87-9; (1,1-Dimethoxypropan-2-yl)Benzene

• 英文名称(1,1-Dimethoxypropan-2-yl)Benzene
• 中文名称(1,1-二甲氧基丙-2-基)苯
• IUPAC名称(1,1-dimethoxypropan-2-yl)benzene
• 其它别名(2,2-Dimethoxy-1-Methylethyl)Benzene #; (1,1-Dimethoxypropan-2-yl)Benzene; Cas-90-87-9; Benzene, (2,2-Dimethoxy-1-Methylethyl)-; H41Wgl6C12; Hydrotropic Aldehyde Dimethyl Acetal; Akos0
• CAS编号90-87-9
• MFCD编号:MFCD00008860
• EINECS号:202-022-8
• FDA UNII编号:H41WGL6C12
• 分子式:C11H16O2
• 分子量:180.25
• 产品CID: 1942696
• 产品分类有机原料→分子砌块→芳环类化合物→苯类化合物

• 相似结构搜索
• InChIKey: UFOUDYPOSJJEDJ-UHFFFAOYNA-N
• InChI=1/C11H16O2/c1-9(11(12-2)13-3)10-7-5-4-6-8-10/h4-9,11H,1-3H3…
• 计算化学: 氢键受体数2.0氢键供体数0.0可旋转键数4.0

相似化合物

物理性质

• 沸点226.4 °C at 760 mmHg
• 闪点92.2 °C
• 密度0.971g/cm3
• PSA:18.46
• LogP:2.409
• 折射率1.484
• 蒸汽压30.1Pa at 24°C
• 溶解性Almost insoluble in water, soluble in alcohol oils.
• 外观形态无色液体
• 产品应用β-苯丙醛二甲缩醛(90-87-9)的用途:本品是一种香料.主要用以配制蘑菇,香辛料,坚果等型香精.
• 性质描述β-苯丙醛二甲缩醛(90-87-9)的性状:1.无色至微黄色液体.具有蘑菇似香气.2.溶于乙醇和乙醚,几不溶于水.沸点241°C.毒性:GRAS(FEMA).

MSDS等安全信息

• GHS象形图
• GHS符号GHS07;
  注释: Exclamation mark
• 危险类别急性毒性 类别4(经口)
  特定目标器官毒性 - 单次接触 类别3
  皮肤腐蚀/刺激 类别2
  严重眼刺激 类别2
• 警示词Warning(警告)
• 危险描述H302 |吞咽有害.
  H335 |可能引起呼吸道刺激.
  H315 |造成皮肤刺激.
  H319 |造成严重眼刺激.
• 防范说明P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
• 危险品标志Xi
• 安全声明26-36/37/39
• 危险类别码36/37/38
• WGK Germany2

欧盟法规

上下游产品

合成工艺路线路线简述

• 93-53-8 = 90-87-9
  反应条件:1.1 Solvents: Carbon Tetrachloride
  标题:Process And Zeolite Catalysts For The Regioselective Acetalization And Transacetalization Of Aldehydes In The Manufacture Of Acetals
  参考文献:Spain]
  
  637-50-3 = 90-87-9
  反应条件:1.1 Catalysts: Ammonium Iodide; 1 Min,Rt1.2 Reagents: Potassium Peroxymonosulfate Sulfate (2Khso5.Khso4.K2So4); 30 °C; 4.85 H,30 °C
  标题:Hypoiodous Acid-Catalyzed Regioselective Geminal Addition Of Methanol To Vinylarenes: Synthesis Of Anti-Markovnikov Methyl Acetals
  作者:Peraka,Swamy; Mameda,Naresh; Marri,Mahender Reddy; Kodumuri,Srujana; Chevella,Durgaiah; Et Al
  参考文献:Rsc Advances 日期:2015 卷标:5(90) 页码:73732-73736]
  
  = 90-87-9
  反应条件:1.1 Reagents: Ozone Solvents: Methanol,Dichloromethane; 10 Min,-78 °C1.2 Reagents: Dimethyl Sulfide; -78 °C1.3 Reagents: Sulfuric Acid Magnesium Salt (1:1) Catalysts: P-Toluenesulfonic Acid; -78 °C; -78 °C -> Rt; Overnight,Rt
  标题:Two-Way Homologation Of Aliphatic Aldehydes: Both One-Carbon Shortening And Lengthening Via The Same Intermediate
  作者:Yoo,Jae Won; Seo,Youngran; Park,Jong Beom; Kim,Young Gyu
  参考文献:Tetrahedron 日期:2020 卷标:76(6)]
  
  93-53-8 = 90-87-9
  反应条件:1.1 Catalysts: [4-[1-(4-Carboxyphenyl)-2,2,2-Trifluoro-1-(Trifluoromethyl)Ethyl]Benzoato(2-)-Ko... Solvents: Carbon Tetrachloride; 24 H,60 - 70 °C
  标题:An Indium Layered Mof As Recyclable Lewis Acid Catalyst
  作者:Gandara,F.; Gomez-Lor,B.; Gutierrez-Puebla,E.; Iglesias,M.; Monge,M. A.; Et Al
  参考文献:Chemistry Of Materials 日期:2008 卷标:20(1) 页码:72-76]
  
  637-50-3 = 90-87-9 [标题:Reaction Conditions
  标题:Product Class 6: Acyclic And Semicyclic O/o Acetals
  作者:Von Angerer,S.; Warriner,S. L.
  参考文献:Science Of Synthesis 日期:2007 卷标:29 页码:303-406]
  
  = 90-87-9
  反应条件:1.1 Reagents: Hydrogen Catalysts: Dicarbonylrhodium Acetylacetonate,1-Butyl-3-Methylimidazolium Tetrafluoroborate,Benzeneacetic Acid,α-Amino-4-(Diphenylphosphino)-,Tetrafluoroborate(1-) (1:1) Solvents: Methanol; 2 H,5 Mpa,80 °C
  标题:Highly Effective Tandem Hydroformylation-Acetalization Of Olefins Using A Long-Life Bronsted Acid-Rh Bifunctional Catalyst In Ionic Liquid-Alcohol Systems
  作者:Jin,Xin; Zhao,Kun; Cui,Feifei; Kong,Fangfang; Liu,Qiangqiang
  参考文献:Green Chemistry 日期:2013 卷标:15(11) 页码:3236-3242]
  
  93-53-8 = 90-87-9
  反应条件:1.1 Catalysts: Pyridinium,3,5-Bis(Methoxycarbonyl)-1-(Phenylmethyl)-,Bromide (1:1) Solvents: Methanol; 25 H,Rt1.2 Reagents: Phenylhydrazine Hydrochloride
  标题:Unexpected Catalysis: Aprotic Pyridinium Ions As Active And Recyclable Bronsted Acid Catalysts In Protic Media
  作者:Procuranti,Barbara; Connon,Stephen J.
  参考文献:Organic Letters 日期:2008 卷标:10(21) 页码:4935-4938]
  
  93-53-8 = 90-87-9
  反应条件:1.1 Catalysts: Sulfurous Acid (Silica Supported) Solvents: Methanol; 20 H,25 °C
  标题:So3H-Functionalized Silica For Acetalization Of Carbonyl Compounds With Methanol And Tetrahydropyranylation Of Alcohols
  作者:Shimizu,Ken-Ichi; Hayashi,Eidai; Hatamachi,Tsuyoshi; Kodama,Tatsuya; Kitayama,Yoshie
  参考文献:Tetrahedron Letters 日期:2004 卷标:45(26) 页码:5135-5138]
  
  90944-40-4 = 90-87-9
  反应条件:1.1 Reagents: Boron Trifluoride Etherate,Bis(Pyridine)Iodonium Tetrafluoroborate Solvents: Dichloromethane; 15 Min,Rt1.2 Reagents: Sodium Thiosulfate Solvents: Water; Rt
  标题:Ipy2Bf4-Mediated Rearrangements Of 1,2-Difunctionalized Compounds And Olefins
  作者:Fananas,Francisco J.; Alvarez-Perez,Monica; Rodriguez,Felix
  参考文献:Chemistry - A European Journal 日期:2005 卷标:11(20) 页码:5938-5944]
  
  93-53-8 = 90-87-9
  反应条件:1.1 Reagents: Sulfuric Acid
  标题:A Simple And Efficient Conversion Of Aldehyde Acetals Into Esters
  作者:Sugai,Saburo; Kodama,Takashi; Akaboshi,Sanya; Ikegami,Shiro
  参考文献:Chemical & Pharmaceutical Bulletin 日期:1984 卷标:32(1) 页码:99-105]
  
  = 90-87-9
  反应条件:1.1 Catalysts: 2,6-Pyridinedicarboxylic Acid,Borate(1-),Tetrafluoro-,Iron(2+) (2:1),Hexahydrate Solvents: Methanol; 5 Min,Rt1.2 Reagents: Iodobenzene Diacetate; 1 Min,Rt1.3 Solvents: Methanol; 20 H,Rt
  标题:A Generalized Approach For Iron Catalyzed Chemo- And Regioselective Formation Of Anti-Markovnikov Acetals From Styrene Derivatives
  作者:Dutta Chowdhury,Abhishek; Kumar Lahiri,Goutam
  参考文献:Chemical Communications (Cambridge 日期:2012 卷标:48(28) 页码:3448-3450]
  
  93-53-8 = 90-87-9
  反应条件:1.1 Catalysts: Germanate (Ge9(Oh)2O194-),Tetrahydrogen,Compd. With 1,2-Ethanediamine (2:5),D... Solvents: Carbon Tetrachloride; 2 H,60 - 70 °C
  标题:Chiral Germanium Zeotype With Interconnected 8-,11-,And 11-Ring Channels. Catalytic Properties
  作者:Medina,M. E.; Iglesias,M.; Snejko,N.; Gutierrez-Puebla,E.; Monge,M. A.
  参考文献:Chemistry Of Materials 日期:2004 卷标:16(4) 页码:594-599]
  
  93-53-8 = 90-87-9
  反应条件:1.1 Catalysts: 3-Cyclobutene-1,2-Dione,3,4-Dihydroxy-,Scandium(3+) Salt (3:2); 12 H,60 °C
  标题:A New Scandium Metal Organic Framework Built Up From Octadecasil Zeolitic Cages As Heterogeneous Catalyst
  作者:Gandara,Felipe; Gomez-Lor,Berta; Iglesias,Marta; Snejko,Natalia; Gutierrez-Puebla,Enrique; Et Al
  参考文献:Chemical Communications (Cambridge 日期:2009 卷标:(17) 页码:2393-2395]
  
  93-53-8 = 90-87-9
  反应条件:1.1 Reagents: P-Toluenesulfonic Acid Solvents: Methanol; 1440 Min,333 K
  标题:Three-Step Synthesis Of 1,1-Dimethoxy-2-Phenylpropane
  作者:Hajek,Jan; Kacer,Petr; Cerveny,Libor
  参考文献:Research On Chemical Intermediates 日期:2002 卷标:28(6) 页码:551-559]
  
  93-53-8 = 90-87-9 [标题:Reaction Conditions
  标题:Novel Delaminated Zeolites Are More Active Acid Catalysts Than Conventional Zeolites And Mesoporous Al/mcm-41 For The Synthesis Of Fine Chemicals
  作者:Climent,Maria J.; Corma,Avelino; Fomes,Vicente; Garcia,Hermenegildo; Iborra,Sara; Et Al
  参考文献:Studies In Surface Science And Catalysis 日期:2001 卷标:135 页码:3719-3726]
  
  = 90-87-9 + 30076-98-3
  反应条件:1.1 Reagents: Hydrogen Catalysts: Triphenyl Phosphite,Rhodium Trichloride Solvents: Methanol; 6 H,600 Psi,80 °C; 80 °C -> Rt
  标题:Rh(I) Or Rh(Iii) Supported On Mcm-41-Catalyzed Selective Hydroformylation-Acetalization Of Aryl Alkenes: Effect Of The Additives
  作者:El Ali,Bassam; Tijani,Jimoh; Fettouhi,Mohammed
  参考文献:Applied Catalysis 日期:2006 卷标:303(2) 页码:213-220

海关参考信息

• 2902600000-乙苯
  2902700000-异丙基苯
  2905121000-正丙醇
  2909199090-其他醚及其衍生物
• 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
• 详情请参考：📖 海关编码查询和海关进出口税则

其他信息查阅

• ➥ 象形图和危险代码
• ➥ 防范代码详解
• ➥ 危险代码说明
• ➥ Globally Harmonized System
• ➥ REACH监管