专利号:US-4472568-A 优先权日:1981-11-12 标 题:Process for the preparation of polyamines from N-monoaryl-N',N'-dialkyl urea compounds and their use for the synthesis of polyurethanes 发明人:RASSHOFER WERNER; GROEGLER GERHARD 权利人:BAYER AG 摘要:This invention relates to an improved process for the preparation of aromatic polyamines containing urethane and/or biuret and/or urea and/or isocyanurate groups and preferably also ether groups by the hydrolysis of poly-N-monoaryl-N',N'-dialkyl urea compounds (1-aryl-3,3-dialkyl ureas). The ureas are obtained by the reaction of secondary aliphatic, cycloaliphatic or saturated heterocyclic amines with divalent to tetravalent isocyanate compounds containing isocyanate end groups attached to aromatic residues. The ureas correspond to the general formula: wherein R1, R2 denote alkyl or cycloalkyl groups, or together form a ring and A denotes a divalent to tetravalent residue attached to the ureas by aromatic groups. Hydrolysis is carried out in the presence of water and up to two equivalents of a base containing hydroxide ions and/or up to two equivalents of a compound containing tertiary amino groups, optionally in the presence of solvents. The use of the polyamines obtained by this process for the synthesis of polyurethanes is also described.
专利号:US-12145127-B2 优先权日:2017-03-23 标 题 :Porous co-polymeric gel compositions, porous carbon compositions, and methods for synthesis thereof 发明人:LEVENTIS NICHOLAS; SOTIRIOU-LEVENTIS CHARIKLIA; SAEED MALIK ADNAN 权利人:ASPEN AEROGELS INC 摘要:The present invention discloses novel porous polymeric compositions comprising random copolymers of amides, imides, ureas, and carbamic-anhydrides, useful for the synthesis of monolithic bimodal microporous/macroporous carbon aerogels. It also discloses methods for producing said microporous/macroporous carbon aerogels by the reaction of a polyisocyanate compound and a polycarboxylic acid compound, followed by pyrolytic carbonization, and by reactive etching with CO2 at elevated temperatures. Also disclosed are methods for using the microporous/macroporous carbon aerogels in the selective capture and sequestration of carbon dioxide.
专利号:US-7351781-B2 优先权日:2001-04-24 标题 :Synthesis of vinyl polymers by controlled radical polymerization 发明人:WHITE DANIELA; O'DWYER JAMES B 权利人:PPG IND OHIO INC 摘要:A controlled free radical polymerization process, which includes the steps of: adding a monofunctional iniferter compound to an oxygen-free solvent; heating the solution to a temperature sufficient to allow the iniferter compound to form two carbon centered radical residues; adding a first monomer composition comprising one or more monomers to the solution containing the radical containing residues; polymerizing the first monomer composition to form a quasi-living polymer; and optionally polymerizing a second monomer composition comprising one or more monomers, which are different than the first monomer composition. The resulting non-random copolymer having the general formula:n nφ-[-A p -B s -] t -φn nwhere A and B are different compositions of ethylenically unsaturated monomers; p is an integer from 1 to 1,000; s is an integer from 0 to 1,000; t is an integer from 1 to 100; and φ is a residue from the iniferter.
专利号:US-2021238374-A1 优先权日:2020-02-04 标 题 :Templated synthesis of nanovoided polymers 发明人:YE SHENG; LANDIG RENATE EVA KLEMENTINE; DIEST KENNETH ALEXANDER; OUDERKIRK ANDREW JOHN; BOWMAN CHARLES ROBERT; BOWMAN ROBERT G; HENDRICKSON WILLIAM ARTHUR; RUEB CHRISTOPHER J; PURVIS II LAFE JOSEPH; SUN WENMO; LI RYAN; YAROSHCHUK OLEG; RAO TINGLING; BOROMAND ARMAN; ZHAO CHURNING; Khaleghimeybodi Morteza 权利人:FACEBOOK TECH LLC 摘要:A method of forming a voided polymer includes forming a polymerizable composition containing a polymer precursor and a solid templating agent, forming a coating of the polymerizable composition, processing the coating to form a cured polymer material having a solid phase in a plurality of defined regions, and removing at least a portion of the solid phase from the cured polymer material to form a voided polymer layer.
专利号:US-4348536-A 优先权日:1975-05-28 标 题 :Odorless catalysts for the synthesis of polyurethanes 发明人:BLAHAK JOHANNES; HUEBNER HANS; KOSTER JOHANNES; MEINERS HANS J; THOMAS HEINZ 权利人:BAYER AG 摘要:The instant invention is directed to novel compounds and the use thereof in producing polyurethane resins. The compounds generally correspond to the following formula: wherein n is an integer of from 1 to 5, R is a C1-C5 alkyl group Y is a C1-C5 alkyl group or a and Z is a where n=0 or 1, X is -O- or and R' is an aliphatic group having from 1 to 15 carbon atoms and may contain ester, ether, or amide groups or tertiary nitrogen and, when m=0, R' may be a hydrogen atom.
专利号:WO-2024216794-A1 优先权日:2023-04-17 标 题:Implantable material and synthesis method therefor and prosthetic heart valve 发明人:WANG LICHAO; WEI XING; KUANG DAJUN 权利人:VENUS MEDTECH HANGZHOU INC 摘要:The present application discloses an implantable material and a synthesis method therefor and a prosthetic heart valve. The implantable material uses polyurethane, the molecular chain structure of polyurethane comprises a soft segment and a hard segment, and a functional branched chain is grafted onto the hard segment; the solubility parameter of the functional branched chain is 6-8. According to the present application, by introducing the functional branched chain into the hard segment, the compatibility between the hard segment and the soft segment is improved and the stress transfer points between the hard segment and the soft segment are increased, so that the prepared implantable polymer material has excellent mechanical properties.
参考文献:10.1007/978-94-024-0893-5_20 摘要:Alger M. T. 2017. In: Polymer Science Dictionary. 参考文献:10.1007/978-94-017-2504-0_14 摘要:Saunders KJ. Polyurethanes. 1973. In: Organic Polymer Chemistry. 参考文献:10.1007/978-3-030-27322-4_67 摘要:Steiner SA, Aegerter MA, Koebel MM, Leventis N. Glossary of Aerogel Terminology. 2023. In: Springer Handbooks. 参考文献:10.1007/978-3-031-41077-2_6 摘要:Goyal N, Sachdeva D, Sujit U. Synthesis, Functionalization Strategies and Application of Different Types of Cyclodextrin-Based Nanosponges for Water Treatment. 2023. In: Nanosponges for Environmental Remediation. 参考文献:10.1007/978-3-030-27322-4_44 摘要:Leventis N, Sotiriou-Leventis C, Donthula S. Interpenetrating Phenolic/Oxide Networks and Carbothermal Synthesis of Metallic and Carbide Aerogels. 2023. In: Springer Handbooks.