CAS: 989-38-8; 9-(2-(Ethoxycarbonyl)Phenyl)-3,6-Bis(Ethylamino)-2,7-Dimethylxanthylium Chloride

该化合物是一种属于罗哈胺家族的合成染色,其特点是有生机的粉色至红色,主要在各种应用中用作荧光色追踪器,包括生物成像,染色激光和pH指标.Rhodamiine 6G的化学配方为C28H31ClN2O3S,其分子重量约为479.08克/摩尔.该化合物具有很强的荧光特性,特别是在紫外线下,使其在荧光显微镜和流动细胞测量中具有价值.Rhodamine 6G在水和乙醇和乙醇等有机溶剂中是溶解的,但其溶解性可因pH而异.众所周知,在正常条件下,它具有稳定性,但当接触强酸或强碱时,它会降解.此外,Rhodam 6G在纺织工业中也有应用,作为生物污点,但因其潜在的毒性和环境影响而谨慎.

结构式图片

欧盟法规

统一分类与标签REACH注册ECHA物质ECHA物质工作场所安全标识要求C&L通报REACH预注册废弃物危险特性清单

合成工艺路线路线简述

    Alkaline Earth Salt Of/the/ Methylsulfuric Acid置于乙醇,硫酸体系中,化学反应生成 碱性红 1
    参考文献:了解单乙基邻甲苯胺和从中可获得的一些若丹明
    标题:了解单乙基邻甲苯胺和从中可获得的一些若丹明
    摘要:
    DOI:10.1002/hlca.193401701180

    海关参考信息

    专利信息


    专利号:US-2023235372-A1
    优先权日:2020-06-12
    标题:Ab-initio, template-independent synthesis of nucleic acids using thermostable enzymes
    发明人:RANDRIANJATOVO-GBALOU IRINA; SAID AHMED; RAHIER RENAUD
    权利人:SYNHELIX
    摘要:The invention relates to the field of nucleic acid synthesis or sequencing, more specifically to methods for ab-initio synthesis of nucleic acids, comprising contacting a nucleotide with a free 3′-hydroxyl group, with at least one nucleoside triphosphate, or a combination of nucleoside triphosphates, in the presence of an archaeal DNA primase or a functionally active fragment and/or variant thereof, thereby covalently binding said nucleoside triphosphate to the free 3′-hydroxyl group of the nucleotide. It also relates to isolated functionally active fragments of archaeal DNA primases which are capable of both ab-initio single-stranded nucleic acid synthesis activity and template-independent terminal nucleotidyl transferase activity.

    专利号:US-2012103789-A1
    优先权日:2010-10-28
    标题:Greener Synthesis of Nanoparticles Using Fine Tuned Hydrothermal Routes
    发明人:MAYE MATHEW
    权利人:MAYE MATHEW; UNIV SYRACUSE
    摘要:The synthesis of energy and sensor relevant nanomaterials that involves the colloidal synthesis of quantum dots (e.g. CdSe, CdS, ZnS, CdSe/ZnS) under well-controlled hydrothermal conditions (100-200 degrees C.) using simple inorganic precursors. The resulting nanomaterials are of high quality, and are easily processed depending upon application, and their synthesis is scalable. Scalability is provided by the use of a synthetic microwave reactor, which employs dielectric heating for the rapid and controllable heating.

    专利号:US-7927516-B2
    优先权日:2004-09-20
    标题 :Method for synthesis of colloidal nanoparticles
    发明人:STROUSE GEOFFREY F; GERBEC JEFFREY A; MAGANA DONNY
    权利人:UNIV CALIFORNIA
    摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

    专利号:US-2023235373-A1
    优先权日:2020-06-12
    标 题:Controlled template-independent synthesis of nucleic acids using thermostable enzymes
    发明人:RANDRIANJATOVO-GBALOU IRINA; SAID AHMED; RAHIER RENAUD
    权利人:SYNHELIX
    摘要:The invention relates to methods for template-independent synthesis of nucleic acids, comprising iteratively contacting an initiator sequence comprising a 3′-end nucleotide with a free 3′-hydroxyl group, with at least one nucleoside triphosphate, or a combination of nucleoside triphosphates, in the presence of an archaeal DNA primase or a functionally active fragment and/or variant thereof, thereby covalently binding said nucleoside triphosphate to the free 3-hydroxyl group of the 3-end nucleotide. It also relates to isolated functionally active fragments of archaeal DNA primases which are capable of template-independent terminal nucleotidyl transferase activity but are devoid of a template-independent primase activity.

    专利号:US-10457560-B1
    优先权日:2007-12-07
    标 题 :Synthesis of mesoporous silica shapes using sodium silicate as a silica source
    发明人:SOKOLOV IGOR; NAIK SAJO P
    权利人:SOKOLOV IGOR; NAIK SAJO P; UNIV CLARKSON
    摘要:This invention describes the self-assembly of meso(nano)porous silica particles from inorganic an inexpensive silica precursor, sodium silicate. The particles have a well defined shape, high surface area, and high uniformity of the pore size, the properties that are typically found for high quality mesoporous material synthesized from organic silica precursors. The disclosure illustrates a synthesis of hard spheres, discoids, and a mixture comprising discoids, gyroids and fibers, termed as origami.

    专利号:US-10150160-B2
    优先权日:2014-12-04
    标题 :Universal one-pot and up-scalable synthesis of SERS encoded nanoparticles
    发明人:PAZOS PÉREZ NICOLÃ?S; MIR DE SIMÓN BERNAT
    权利人:MEDCOM ADVANCE S A; MEDCOM ADVANCE S A
    摘要:The universal one-pot and up-scalable synthesis of SERS encoded nanoparticles relies on the controlled co-absorption of mercaptoundecanoic acid (MUA) and the Raman code on the metallic surfaces of the nanoparticles. In contrast to most of the reported procedures which typically involve complex steps, the present method has demonstrated to be an easy and fast one-pot approach for the production of SERS-encoded nanoparticles. This versatile strategy allows for the SERS codification of particles with every molecule with affinity toward the metal surface, independently of its chemical nature, as exemplified here in the fabrication of 31 different encoded particles using the same standard procedure. In addition to the easiness of preparation, scalability to the liter regime, stability in aqueous solutions including PBS and chemical diversity, our SERS-encoded particles show considerably higher optical efficiency than those fabricated by using PEG or PVP polymers.
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    主要参考文献


    1: Lin H, Yue Y, Maidana DE, Bouzika P, Atik A, Matsumoto H, Miller JW, Vavvas DG. Drug Delivery Nanoparticles: Toxicity Comparison in Retinal Pigment Epithelium and Retinal Vascular Endothelial Cells. Semin Ophthalmol. 2016;31(1-2):1-9. doi: 10.3109/08820538.2015.1114865. Review.
    2: Sonmez M, Georgescu M, Alexandrescu L, Gurau D, Ficai A, Ficai D, Andronescu E. SYNTHESIS AND APPLICATIONS OF Fe3O4/SiO2 CORE-SHELL MATERIALS. Curr Pharm Des. 2015;21(37):5324-35. Review. doi: 10.1007/s10577-015-9473-9. Epub 2015 May 8. Review. doi: 10.1039/c4nr06283c. Review. Review. Polish. Review. Review. Review. Review. Review. Review. Review. Review. Review. Review. German. Review. German. Review. Review.

    合成参考文献


    参考文献:10.1007/s00775-005-0059-4
    摘要:Koehntop KD, Marimanikkuppam S, Ryle MJ, Hausinger RP, Que L. Self-hydroxylation of taurine/α-ketoglutarate dioxygenase: evidence for more than one oxygen activation mechanism. JBIC Journal of Biological Inorganic Chemistry. 2005 Dec 01;11(1):63–72. doi: 10.1007/s00775-005-0059-4.
    参考文献:10.2116/analsci.27.671
    摘要:Fukuyama M, Hibara A. Release of Encapsulated Content in Microdroplets. Analytical Sciences. 2011 Jul 10;27(7):671–2. doi: 10.2116/analsci.27.671.
    参考文献:10.1007/s11671-008-9139-z
    摘要:Zhu C, Wang P, Wang X, Li Y. Facile Phosphine-Free Synthesis of CdSe/ZnS Core/Shell Nanocrystals Without Precursor Injection. Nanoscale Research Letters. 2008 Jun 24;3(6):213. doi: 10.1007/s11671-008-9139-z.
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