以 Not Given 用作溶剂,化学反应生成硫酰氟 参考文献:40.与钒,铌和五氟化钽的化学反应 标题:40.与钒,铌和五氟化钽的化学反应 摘要: Doi:10.1039/jr9580000190
专利信息
专利号:US-2021053913-A1 优先权日:2019-08-22 标题 :Process for the Synthesis of Fluorinated Conductive Salts for Lithium Ion Batteries 发明人:ZHOU CHANGYUE; DU HONGJUN; WU WENTING 权利人:FUJIAN YONGJING TECH CO LTD 摘要:The invention relates to a new process for the synthesis of fluorinated conductive salts for lithium ion batteries (Li-ion batteries). The said fluorinated conductive lithium ion (Li-ion) battery salts of interest in the framework of the present inventions synthesis process, for example, are Li-ion salts such as LiFSI (lithium bis-(fluoromethanesulfonlyl) imide), LiTFSI (lithium bis-(trifluormethanesulfonlyl) imide), and LiTFSFI (lithium trifluoromethanesulfonylfluorosulfonyl imide), with the formulas as displayed in the Table I herein below. LiFSI, LiTFSI and LiFSTFSI are the most promising conducting salts for Lithium ion batteries and essential for future electromobility.
专利号:US-5072040-A 优先权日:1989-04-06 标 题:Process for synthesis of sulfonylimides 发明人:ARMAND MICHEL 权利人:CENTRE NAT RECH SCIENT; HYDRO QUEBEC 摘要:The invention relates to a process for the synthesis of sulfonylimides. n The process for the synthesis of sulfonylimides of the general formula M[RSO 2 ) 2 N] y , in which M represents a metal chosen from alkali metals, alkaline earth metals, rare earths, Al, Sc, Y and Th, R represents a monovalent radical chosen from linear or branched aliphatic radicals having 1 to 8 carbon atoms, alicyclic radicals having 3 to 8 carbon atoms, aryl radicals having 3 to 8 carbon atoms, and y is a number equal to the valence of M, is characterized in that an ionic nitride of the formula M 3 N y , in which M and y have the meaning given above, is reacted with a sulfonyl halide of the formula RSO 2 X, in which R has the meaning given above, and X is chosen from F or Cl, in an aprotic polar solvent.
专利号:US-2025188046-A1 优先权日:2023-12-08 标题:Ultrafast flow synthesis of functionalized sulfonyl fluorides and subsequent sufex connections via lithiated chemistry 发明人:KIM DONG-PYO; KANG JI-HO 权利人:POSTECH RES & BUSINESS DEV FOUND 摘要:Disclosed are ultrafast flow synthesis of functionalized sulfonyl fluorides and subsequent SuFEx connections via lithiated chemistry. In detail, a method of synthesizing an ortho-functionalized benzenesulfonyl fluoride derivative, the method comprises (a) reacting a benzenesulfonyl fluoride derivative represented by structural formula 1 with an organolithium represented by structural formula 2, thus synthesizing an intermediate represented by structural formula 3 in reaction scheme 1 and (b) reacting the intermediate with an electrophile, thus synthesizing a compound represented by structural formula 4 or a compound represented by structural formula 4′. The present disclosure enables the synthesis of several functionalized sulfonyl fluorides within a few seconds under mild temperature conditions in addition to the chemistry of Sulfonyl Fluoride Exchange (SuFEx), which is a next-generation click chemistry, so that sulfonyl fluoride, the main reactant of the SuFEx reaction, can be efficiently secured.
专利号:US-2024182439-A1 优先权日:2022-11-23 标题 :Method for catalytic synthesis of crude ethylene sulfate 发明人:REN FAN; WANG LIANG; SONG WENCHAO; Dai Rongming; LIANG LICHUN; Cui Xianmiao 权利人:Wuhan Oxiran Special Chemicals Company 摘要:In method for catalytic synthesis of crude ethylene sulfate, a sulfur trioxide solution is prepared by dissolving sulfur trioxide with a solution A, an ethylene oxide solution is prepared by mixing a solution B with ethylene oxide, a catalyst is added to the sulfur trioxide solution and mixing them to obtain a mixed solution C, the ethylene oxide solution and the mixed solution C are pre-cooled, and then introduced into a set of microchannel reactors for a real-time reaction to obtain a mixed solution containing crude ethylene sulfate, and then a post-treatment process is carried out to obtain crude ethylene sulfate. With the process, the reaction selectivity is good, and a microchannel reaction can accurately control the reaction energy level due to its rapid mixing and timely heat transfer, which greatly reduces the safety risk and effectively avoids the occurrence of side reactions.
专利号:US-5939304-A 优先权日:1997-06-05 标题:Method for synthesis of anhydrothrombin 发明人:SUZUKI TOYOAKI; HOSOKAWA KAZUYA; NAGATA MASANORI 权利人:FUJIMORI KOGYO CO 摘要:A method for a synthesis of anhydrothrombin is provided which features a short process, an easy procedure, and high yields. n The method comprises n (A) a step of causing an active serine residue site of thrombin to react with an inhibitor, n (B) a step of performing an alkali treatment at a pH of not less than 11, and n (C) a step of performing an operation of recovery, and carries out these steps sequentially in the order mentioned, and is characterized by causing at least the step of performing the operation of recovery to proceed in the presence of at least one compound selected from the group consisting of polyhydric alcohols and saccharides, and a salt or an amphoteric electrolyte.
专利号:US-9035013-B2 优先权日:2010-08-04 标 题 :Sulphur-containing triazine monomer that can be used for the synthesis of a polymer membrane for a fuel cell 发明人:FEDURCO MILAN 权利人:FEDURCO MILAN; MICHELIN & CIE; MICHELIN RECH TECH 摘要:A sulphur-containing triazine monomer is provided that can be used in the synthesis of a polymer membrane for a PEM-type fuel cell. The sulphur-containing triazine monomer has a structure corresponding to a formula (I): n nin which:n Tz represents a 1,3,5-triazine nucleus; X 1 and X 2 , which are identical or different, represent S, SO, or SO 2 ; Ar 1 , Ar 2 , Ar 4 and Ar 5 , which are identical or different, represent a substituted or unsubstituted phenylene group; Ar 3 represents a substituted or unsubstituted phenyl group; and Z 1 and Z 2 , which are identical or different, are selected from a group that includes halogens, hydroxyl, alkoxyl, thiol, carboxyl, carboxylates, amine, sulphonamide, acyl chlorides, sulphonyl chlorides, sulphonyl fluorides, isocyanates, and combinations thereof.
摘要:Giel, M.-C.; Smedley, C. J.; Moses, J. E., Science of Synthesis, (2021) , 442. 摘要:Giel, M.-C.; Smedley, C. J.; Moses, J. E., Science of Synthesis, (2021) , 451. 摘要:Giel, M.-C.; Smedley, C. J.; Moses, J. E., Science of Synthesis, (2021) , 447. 摘要:Archives des Maladies Professionnelles de Medecine du Travail et de Securite Sociale., 34(581), 1973 摘要:Agricultural Chemicals, Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revision, 3(15), 1976/1977