专利号:US-4801744-A 优先权日:1985-03-01 标 题 :Catalytic synthesis of urea from carbon monoxide and amine compound 发明人:HERMAN JEAN-JACQUES; LECLOUX ANDRE 权利人:SOLVAY 摘要:Process for the catalytic synthesis of nitrogen-containing organic compounds, comprising the reaction of carbon monoxide with at least one amino compound in a reaction mixture containing a catalyst based on selenium and a substituted pyridine. The process is particularly suitable for the synthesis of ureas and of their polymers.
专利号:WO-2023152730-A1 优先权日:2022-02-14 标题 :Amine-borane adducts in the synthesis of polyester and its copolymers using cyclic esters and compositions thereof 发明人:FENG XIAOSHUANG; LIU JINGJING; GNANOU YVES 权利人:UNIV KING ABDULLAH SCI & TECH 摘要:Embodiments of the present disclosure provide for the process of synthesis of polyester and its copolymers through (co)polymerization of cyclic esters and with other oxygenated monomers using amine-borane adduct. Embodiments of the present disclosure further describe the controlled anionic ring-opening polymerization of the cyclic compounds. Embodiments of the present disclosure also describe the polymerization of cyclic compounds using the synergistic effect of amines and thioureas. Embodiments of the present disclosure also describe compositions of polymers formed by the said process.
专利号:US-5919969-A 优先权日:1996-06-05 标 题 :Synthesis of yellow couplers 发明人:CRAWLEY MICHAEL W 权利人:EASTMAN KODAK CO 摘要:The invention provides a method of synthesis of a image-dye forming coupler of formula (I) wherein X is a substituent linked to the coupler by an atom of oxygen, sulfur or nitrogen R1 is an alkyl or aryl group, R2 is a hydrogen atom or an alkyl group; R3 to R7 are the same or different and selected from a hydrogen atom and substituent groups; which method comprises the reaction of a compound of formula (II) wherein R and R1 are the same or different and are as defined above for R1 and X is as defined above with a compound of formula (III) wherein R2 to R7 are as defined above, in the presence of an inert organic solvent.
专利号:US-9809565-B2 优先权日:2013-07-05 标 题 :Formation of chiral 4-chromanones using chiral pyrrolidines in the presence of ureas or thioureas 发明人:LETINOIS ULLA; NETSCHER THOMAS; ACKERMANN STEPHAN 权利人:DSM IP ASSETS BV 摘要:The present invention relates to a synthesis of chromanones or chromanes in a stereospecific matter in view of the 2-position in the chromanone or chromane ring. It has been found that this synthesis is particularly possible in the presence of a chiral compound of formula of a specific type and of at least one urea or thiourea.
专利号:US-6664396-B1 优先权日:2002-06-27 标 题 :One step synthesis for quinacridone compounds 发明人:COSIMBESCU LELIA 权利人:EASTMAN KODAK CO 摘要:Disclosed is a process for forming a N,N'-diarylquinacridone compound comprising the step of reacting a N,N'-unsubstituted quinacridone compound with a haloaryl compound in the presence of a metal or metal compound to arylate the N and N' positions and form the corresponding N,N'-diarylquinacridone compound. The process is versatile and provides high yields and purity for the synthesis of N,N'-diarylquinacridone compounds.
专利号:US-7026481-B2 优先权日:2002-06-27 标题 :Synthesis for quinacridone compounds 发明人:COSIMBESCU LELIA; SHI JIANMIN 权利人:EASTMAN KODAK CO 摘要:Disclosed is a process for forming a N,N′-diarylquinacridone compound comprising the step of reacting a 1,4-dialkylcarboxylate-2,5-bis(N-arylamino) benzene with an iodoaryl compound to form the corresponding 2,5-bis(N-diarylamino) compound. The process is versatile and provides high yields and purity for the synthesis of N,N′-diarylquinacridone compounds.
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合成参考文献
摘要:Podlech, J., Science of Synthesis Knowledge Updates, (2018) 4, 125. 摘要:Podlech, J., Science of Synthesis Knowledge Updates, (2018) 4, 114. 摘要:Bartels, F.; Zimmer, R.; Christmann, M., Science of Synthesis Knowledge Updates, (2017) 3, 282. 摘要:Hawley, G.G. The Condensed Chemical Dictionary. 9th ed. New York: Van Nostrand Reinhold Co., 1977., p. 318