专利号:US-10611864-B2 优先权日:2015-09-22 标 题:Synthesis of substituted amidobenzoate compounds, the compounds obtained and the use thereof as phthalate free internal electron donor for polymerization of olefins 发明人:ZUIDEVELD MARTIN ALEXANDER; SAINANI JAIPRAKASH BRIJLAL; AL-HUMAIDAN OSAMAH; PADMANABHAN SUDHAKAR R; SHINGE PRASHANT SUKUMAR; SHETTY SHARANKUMAR G; SHAIKH ABBAS-ALLI GHUDUBHAI 权利人:SABIC GLOBAL TECHNOLOGIES BV 摘要:The present invention relates to a compound according to Formula (I) wherein R 1 is a hydrocarbyl group selected from the group consisting of alkyl, alkenyl, aryl, aralkyl, and alkylaryl groups, and one or more combinations thereof; wherein R 2 is a hydrogen atom, an aryl group or an alkyl group; and wherein R 3 , R 4 , R 5 and R 6 , are the same or different and are each independently a hydrogen atom, a halogen atom, a cyano group, an amino group, a hydrocarbyl group selected from the group consisting of alkyl, alkenyl, aryl, aralkyl, and alkylaryl groups or an alkoxy group, and one or more combinations thereof as internal electron donor and to a process for the synthesis of a compound according to Formula (I), wherein R 1 is a hydrocarbyl group selected from the group consisting of alkyl, alkenyl, aryl, aralkyl, alkoxycarbonyl and alkylaryl groups, and one or more combinations thereof; wherein R 2 is a hydrogen atom or an alkyl group; wherein R 3 , R 4 , R 5 and R 6 , are the same or different and are each independently selected from a group consisting of a hydrogen atom; a hydrocarbyl, preferably, said process comprising the step of reacting a compound according to Formula (II) [R 1 —C(â•?O)Cl] with a compound according to Formula (III) to obtain the compound according to Formula (I) and to the use of these compounds as internal donor in Ziegler-Natta catalysis of lefins.
专利号:US-7884125-B2 优先权日:2008-04-30 标 题:Straightforward entry to 7-azabicyclo[2.2.1]heptane-1-carbonitriles and subsequent synthesis of epibatidine analogues 发明人:STEVENS CHRISTIAN; HEUGEBAERT THOMAS 权利人:UNIV GENT 摘要:The present invention relates to a group of substituted-7-azabicyclo-[2.2.1]heptyl derivatives with biological activity. The present invention also relates to synthetic methods for producing said substituted-7-azabicyclo-[2.2.1]heptyl derivatives. The present invention also relates to certain intermediates for producing such substituted-7-azabicyclo-[2.2.1]heptyl derivatives, as well as a synthetic method for producing such intermediates. The present invention also relates to pharmaceutical compositions comprising such substituted-7-azabicyclo-[2.2.1]heptyl derivatives, as well as their use as medicaments for the treatment of diseases mediated by a Nicotinic Acetylcholine Receptor or a receptor being a member of the Neurotransmitter-gated Ion Channel Superfamily, such as pain, Alzheimer's disease, Parkinson's disease, schizophrenia, epilepsy and nicotine addiction.
专利号:US-6693058-B1 优先权日:1997-01-28 标 题 :Ziegler-natta catalyst for narrow to broad MWD of polyoefins, method of making, method of using, and polyolefins made therewith 发明人:GRAY STEVEN D; COFFY TIM J 权利人:FINA TECHNOLOGY 摘要:A new synthesis of a Ziegler-Natta catalyst uses a multi-step preparation that includes treating a magnesium dialkoxide compound with halogenating/titanating agents, and an organoaluminum preactivating agent. The catalyst may be used in the polymerization of olefins, particularly ethylene, to control the molecular weight distribution and the fluff morphology of the resulting polyolefins.
专利号:WO-2020257627-A1 优先权日:2019-06-20 标题:Synthesis of long-chain branched polypropylene using heterogenous ziegler-natta catalysts 发明人:CHUNG TZE-CHIANG; UZAWA TSUTOMU; GOTO KEISUKE; UOZUMI TOSHIYA; SUGANO TOSHIHIKO 权利人:PENN STATE RES FOUND 摘要:A process for preparing long-chain branched isotactic polypropylene (LCB-PP) is provided. The process includes copolymerizing propylene with an asymmetric diene of formula I using a heterogeneous iso-specific MgCl 2 -supported Ziegler-Natta catalyst. The copolymerization results in an isotactic polypropylene-styrene (PP-St) copolymer of formula II. The process includes pelletizing the PP-co-BSt copolymer in an extruder to produce the LCB-PP. n is an integer from 1 to 4, x is an integer between 500 and 10,000, and y is an integer between 1 and 10.
专利号:US-6916895-B2 优先权日:1997-01-28 标 题 :Ziegler-Natta catalyst for tuning MWD of polyolefin, method of making, method of using, and polyolefins made therewith 发明人:GRAY STEVEN D; COFFY TIM J 权利人:FINA TECHNOLOGY 摘要:A new synthesis of a Ziegler-Natta catalyst uses a multi-step preparation that includes treating a magnesium dialkoxide compound with halogenating/titanating agents, an organoaluminum preactivating agent, and a heat treatment. The catalyst may be used in the polymerization of olefins, particularly ethylene, to control the molecular weight distribution of the resulting polyolefins.
专利号:US-5521263-A 优先权日:1994-10-18 标 题:Catalysts and synthesis of high molecular weight amorphous polyolefins and recovery thereof 发明人:SEEGER HORST K; HOLLIDAY ROBERT E 权利人:EASTMAN CHEM CO 摘要:A process for the production of amorphous polyolefins is disclosed. The process entails contacting the olefin monomer, in an unreactive hydrocarbon solvent, with a catalyst in a recirculated, stirred reactor thereby producing amorphous polyolefin. The reactor is capable of recirculating contents that are very viscous.
参考标题:Synthesis Of Hydrosilanes Via Lewis-Base-Catalysed Reduction Of Alkoxy Silanes With Nabh4 作者:Keiya Aoyagi,Yu Ohmori,Koya Inomata,Kazuhiro Matsumoto,Shigeru Shimada,Kazuhiko Sato,Yumiko Nakajima 摘要:Hydrosilanes Were Synthesized By Reduction Of Alkoxy Silanes With Bh3 In The Presence Of Hexamethylphosphoric Triamide (Hmpa) As A Lewis-Base Catalyst. The Reaction Was Also Achieved Using An Inexpensive And Easily Handled Hydride Source Nabh4, Which Reacted With Etbr As A Sacrificial Reagent To Form Bh3In Situ.