CAS: 88-45-9; 2,5-Diaminobenzenesulfonic Acid

该化合物是一种芳香磺酸,其特点是附于苯环的两种氨基组(-NH2)和磺酸组(-SO3H),该化合物一般是白色到浅黄色晶状固体,在水中可溶解,在各种应用中有用,其熔点因纯度和形态不同而异,并因其形成金属盐类和复合物的能力而闻名. 2,5-二氨基苯硫酸主要用于染色工业,特别是合成氮染色物时使用,并用作分析化学中的试剂,用于检测硝酸.此外,该化合物在生产药品时和作为pH指标都有应用.由于存在氨基和全氟辛烷磺酸组,该化合物具有基本和酸性特性,因此在化学反应中具有多功能.在处理该化合物时,应采取安全防范措施,因为接触时可能对健康造成风险.

结构式图片

欧盟法规

REACH注册ECHA物质C&L通报REACH预注册

上下游产品

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合成工艺路线路线简述

  • 合成目标产物 2,5-Diaminobenzenesulfonic Acid 主要起始原料 4-Aminoazobenzene Hydrochloride
  • 96-75-3 = 88-45-9
    反应条件:1.1 Reagents: Iron,Hydrochloric Acid,Ammonium Chloride Solvents: Water; Rt -> 95 °C1.2 2 H,> 95 °C1.3 Reagents: Sodium Hydroxide Solvents: Water; Ph 10
    标题:2,5-Bis(Acetoacetamido)Benzenesulfonic Acid
    作者:Li,Fu-Gang; Et Al
    参考文献:Jingxi Yu Zhuanyong Huaxuepin 日期:2007 卷标:15(9) 页码:12-14]

    = 88-45-9
    反应条件:1.1 Reagents: Sulfuric Acid; 35 °C; 35 °C -> 145 °C; 7 H,145 °C; 145 °C -> 90 °C1.2 Reagents: Water; < 100 °C; 100 °C -> 137 °C; 3 H,135 - 137 °C
    标题:Synthesis Of 2,5-Diaminobenzenesulfonic Acid And Its Application In Dyestuffs
    作者:Yang,Hongde; Et Al
    参考文献:Ranliao Yu Ranse 日期:2011 卷标:48(2) 页码:41-44]

    88-45-9 = 88-45-9
    反应条件:1.1 Catalysts: Hydrogen Peroxide Solvents: Water,Ultravon Pl; 7 H,30 - 70 °C
    标题:Peroxidase-Catalysed Coloration Of Wool Fabrics
    作者:Netithammakorn,Nalinee; Et Al
    参考文献:Coloration Technology 日期:2021 卷标:137(2) 页码:93-107]

    61-73-4 = 88-45-9 + 98-89-5
    反应条件:1.1 Catalysts: 2815266-06-7; 1 Bar,273 K
    标题:Selective And Multicyclic Co2 Adsorption With Visible Light-Driven Photodegradation Of Organic Dyes In A Robust Metal-Organic Framework Embracing Heteroatom-Affixed Pores
    作者:Singh,Manpreet; Et Al
    参考文献:Inorganic Chemistry 日期:2022 卷标:61(28) 页码:10731-10742]

    533-30-2 = 88-45-9
    反应条件:1.1 Reagents: Sodium Hydroxide,Benzenesulfonamide,N-Bromo-,Sodium Salt (1:1) Catalysts: Chloro[2-[[(1H-Pyrrol-2-Yl-Kn)Methylene]Amino-Kn]Phenolato(2-)-Ko]Bis(Triphenylp... Solvents: Acetonitrile,Water; 260 Min,313 K
    标题:Development Of An Efficient Ruthenium Catalyzed Synthetic Process And Mechanism For The Facile Conversion Of Benzothiazoles To Orthanilic Acids
    作者:Jagadeesh,R. V.; Et Al
    参考文献:Journal Of Molecular Catalysis A: Chemical 日期:2010 卷标:328(1-2) 页码:99-107]

    96-75-3 = 88-45-9
    反应条件:1.1 Reagents: Hydrogen; 1 Mpa,Rt -> 90 °C; 1 Mpa,90 - 100 °C1.2 Reagents: Hydrogen Ion
    标题:Synthesis Of Tridiglycolamine 2,5-Diacetoacetylaminobenzene Sulfonate
    作者:Li,Fu-Gang; Et Al
    参考文献:Jingxi Yu Zhuanyong Huaxuepin 日期:2008 卷标:16 页码:30-31

专利信息


专利号:US-8034895-B2
优先权日:2004-02-04
标题 :Conjugated thiophenes having conducting properties and synthesis of same
发明人:SKENE WILLIAM G
权利人:UNIV MONTREAL
摘要:The present invention relates to conjugated oligomers and polymers comprising aromatic thiophene cores. The conjugated materials are obtained by simple and efficient condensation of an aryl diamine and an aryl dialdehyde or a bifunctional aryl moiety comprising both an aldehyde and an amine. Condensation of the complementary moieties at temperatures ranging from ambient to refluxing temperatures in various solvents resulted in conjugated oligomers and polymers that can subsequently be cast into thin films. Oligomerization and polymerization can be done under mild conditions with removal of the resulting water bi-product responsible for shifting the equilibrium in favor of the conjugated products. The resulting conjugated compounds can be made conducting with dopants affording electrically conducting materials of either p-type or n-type conductors depending on the dopant selected.

专利号:US-4719053-A
优先权日:1980-08-01
标题 :Beta-chloroethylsulfonylmethyl-benzoic halides as intermediates
发明人:SCHLAEFER LUDWIG; HAEHNLE REINHARD
权利人:HOECHST AG
摘要:New beta -chloroethylsuflonylmethyl-benzoic acid halides which can serve as fibre-reactive anchors for thesynthesis of novel organic, water-soluble compounds, preferably dyestuffs, having fibre-reactive and fibre-finishing properties, such as preferably dyestuff properties, and containing, as a fibre-reactive group, one or two beta -chloroethylsufonylmethylbenzoic acid amide groups. For the synthesis of these novel fibre-finishing compounds, said new beta -chloroethylsulfonylmethyl-benzoic acid halide compounds are reacted with an organic, water-soluble compound having fibre-finishing properties and continuing one or two amino groups. Also precursors of the fibre-finishing, fibre-reactive compounds, containing said beta -chloroethylsulfonylmethyl-benzxoic acid amid grouping, can be employed for their synthesis. The novel fibre-finishing compounds can be applied onto suitable fibre materials, such as especially cellulose fibre material and natural or synthetic polyamide fibre materials, and fixed on these fibre materials in a manner similar to application and fixation methods usual in the technique for fibre-reactive compounds. The fibre-finished material, such as dyed material, shows very good wet fastnesses.

专利号:US-7511113-B2
优先权日:2002-04-26
标题:Oligomeric hydroxy arylether phthalonitiles and synthesis thereof
发明人:KELLER TEDDY M; DOMINGUEZ DAWN D
权利人:US NAVY
摘要:An aromatic ether oligomer or polyaromatic ether comprising the formula:n n O—Ar n ;n nwherein Ar is an independently selected divalent aromatic radical; formed by reacting a dihydroxyaromatic with a dihaloaromatic; and wherein the reaction is performed in the presence of a copper compound and cesium carbonate. The polyaromatic ether is formed when neither the dihydroxyaromatic nor the dihaloaromatic is present in an excess amount. The aromatic ether oligomer is formed by using an excess of either dihydroxyaromatic or dihaloaromatic. A phthalonitrile monomer comprising the formula:n n nformed by reacting a 3- or 4-nitrophthalonitrile with a hydroxy-terminated aromatic ether oligomer. A thermoset formed by curing the phthalonitrile monomer. Processes for forming all the above.

专利号:US-2007287842-A1
优先权日:2004-02-04
标题 :Conjugated Thiophenes Having Conducting Properties and Synthesis of Same

专利号:CA-2718534-A1
优先权日:2008-03-26
标题 :Process for the synthesis of ethynylcyclopropane

专利号:US-2012004386-A1
优先权日:2004-02-04
标题 :Conjugated thiophenes having conducting properties and synthesis of same
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主要参考文献

[参考文献]: Hristina Hadzhiyska, Et Al. Laccase-Assisted Dyeing Of Cotton. Biotechnol Lett. 2006 May;28(10):755-9.
[参考文献]: Tzanko Tzanov, Et Al. Effect Of Some Process Parameters In Enzymatic Dyeing Of Wool. Appl Biochem Biotechnol. 2003 Oct;111(1):1-13.

合成参考文献


参考文献:10.1002/cssc.201500755
摘要:Peng Y, Hu Z, Gao Y, Yuan D, Kang Z, Qian Y, Yan N, Zhao D. Synthesis of a Sulfonated Two-Dimensional Covalent Organic Framework as an Efficient Solid Acid Catalyst for Biobased Chemical Conversion. ChemSusChem. 2015 Oct 12;8(19):3208–12. doi: 10.1002/cssc.201500755.
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