氢氰酸 反应生成二氨基马来腈 参考文献:Bedel,Comptes Rendus Hebdomadaires Des Seances De L'Academie Des Sciences,1923,Vol. 176,P. 168 标题:Bedel,Comptes Rendus Hebdomadaires Des Seances De L'Academie Des Sciences,1923,Vol. 176,P. 168
专利号:US-2018208775-A1 优先权日:2014-06-23 标 题:New aromatic macrocyclic metal complex dyes and the synthesis thereof with active nano metal powders 发明人:OLGUN UGURSOY; YILDIZ SALIH ZEKI 权利人:OLGUN UGURSOY; YILDIZ SALIH ZEKI 摘要:The present invention relates to a new type of inorganic coordination compound dyes having advanced technology optical, electronic and medical characteristics and relates to production of these dyes by means of new synthesis methods. The present invention relates to dyes which are metal (M: Li, Na, K, Mg, Ca, Sr, Ba, Ti, Zr, V, Cr, Mo, Mn, Re, Fe, Ru, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, B, Al, Ga, In, Si, Ge, Sn, Pb, Sb, Bi, Se, Te) complexes of aromatic macrocyclic compounds of the type Phtalocyanine (Pc), Naphtalocyanine (Nc), Porphyrazine (Pz), Porphyrin (Pr), sub-Phtalocyanine (subPc), sub-Naphtalocyanine (subNc), sub-Porphyrazine (subPz), sub-Porphyrine (subPr), and relates to the synthesis of these complexes and derivatives. The subject matter dyes can be used in solar cell photovoltaic (PV) panels, in OLEDS which are organic structured light emitting diodes, in polymers, in textile and in photodynamic therapy PDT applications. Moreover, industrial applications are possible which depend on strong fluorescence characteristics.
专利号:US-3948895-A 优先权日:1971-09-28 标题 :Synthesis of 3,5-diaminopyrazinoic acid from 3,5-diamino-2,6-dicyanopyrazine and intermediates 发明人:DONALD DENNIS S 权利人:DU PONT 摘要:An improved method for the preparation of 3,5-diaminopyrazinoic acid (which is useful for the manufacture of diuretics) is described. New compounds obtained in the process include 3,5-diamino-2,6-dicarbamoylpyrazine; 3.5-diamino-6-carbamoylpyrazinoic acid and 3,5-diamino-6-carbamoylpyrazine. The latter compounds are also useful as curing agents for epoxy resins.
专利号:US-3808225-A 优先权日:1970-12-09 标 题:Process for the preparation of 4(5)-cyanoimidazole-5(4)-carboxyamide by reacting diaminomaleonitrile with formic acid 发明人:ASAI N 权利人:SAGAMI CHEM RES 摘要:AN IMPROVED PROCESS FOR THE PREPARATION OF 4(5)-CYANOIMIDAZOLE-5(4)-CARBOXYAMIDE OF THE FORMULA 4-(NC-),5-(NH2-CO-)IMIDAZOLE WHICH IS USEFUL AS A PRECUSOR FOR THE SYNTHESIS OF VARIOUS COMPOUNDS COMPRISING REACTING DIAMINOMALEONITRILE OF THE FORMULA NC-C(-NH2)=C(-NH2)-CN WITH FORMIC ACID IN AN AROMATIC SOLVENT IS DISCLOSED.
专利号:US-3868386-A 优先权日:1973-03-14 标 题 :Process for the preparation of 4-carboxamido-5-cyano-2-imidazolone 发明人:SANCHEZ ROBERT A; FULLER WILLIAM D 权利人:SANCHEZ ROBERT A; FULLER WILLIAM D 摘要:This invention relates to the synthesis of a unique compound, 4carboxamido-5-cyano-2-imidazolone (may also be called 2-oxo-4cyano-5-imidazolinecarbonamide and by other names) from hydrogen cyanide or from diaminomaleonitrile.
专利号:US-7112671-B2 优先权日:2000-08-30 标 题 :Non-symmetric tripyrranes in the synthesis of novel macrocycles 发明人:MODY TARAK D; GALANTER JOSHUA 权利人:PHARMACYCLICS INC 摘要:The present invention provides certain non-symmetric tripyrranes; that is, tripyrranes that do not contain a mirror plane of symmetry perpendicular to the plane containing the tripyrrane. Further, the invention includes texaphyrin compounds and sapphyrin compounds, as well as other polypyrrolic macrocycles, prepared using tripyrranes of Formula I as a precursor. These macrocycles are characterized by a tripyrrolic portion of the macrocyclic ring having substituents that cause the heterocycle to lack a plane of symmetry perpendicular to the plane of the macrocycle.
专利号:US-3629318-A 优先权日:1970-03-18 标题:Synthesis of diaminomaleonitrile from hydrogen cyanide as catalyzed by cyanogen or diiminosuccinonitrile 发明人:WEBSTER OWEN WRIGHT 权利人:DU PONT 摘要:BASE-CATALYZED TETRAMERIZATION OF HYDROGEN CYANIDE TO DIAMINOMALEONITRILE ACHIEVED BY CATALYZING THE SAME WITH A BASIC CATALYST AND A COCATALYST, CYANOGEN AND/OR DIIMINOSUCCINONITRILE.
[参考文献]: Ahmad Shaabani, Et Al. A Novel Synthesis Of Highly Substituted Imidazo[参考文献]: C N Matthews, Et Al. Hydrogen Cyanide Polymers On Comets. Adv Space Res. 1992;12(4):21-32. [参考文献]: Gulay Bayramoglu, Et Al. Study Of Polyethyleneimine- And Amidoxime-Functionalized Hybrid Biomass Of Spirulina (Arthrospira) Platensis For Adsorption Of Uranium (Vi) Ion. Environ Sci Pollut Res Int. 2015 Nov;22(22):17998-8010. [参考文献]: Hong Deng, Et Al. Synthesis Of New Copper Cyanide Complexes Via The Transformation Of Organonitrile To Inorganic Cyanide. Inorg Chem. 2008 Jul 7;47(13):5866-72. [参考文献]: J P Ferris, Et Al. Hcn And Chemical Evolution: The Possible Role Of Cyano Compounds In Prebiotic Synthesis. Tetrahedron. 1984;40(7):1093-120.
合成参考文献
摘要:Sato, N., Science of Synthesis Knowledge Updates, (2011) 4, 261.