CAS: 14024-61-4; Palladium(Ii) 2,4-Pentanedionate

该化合物是一个协调化合物,以铬形式,以丙烯酮(又称2,4-丙烯酰胺);该化合物一般是黄色至橙色晶状固体,可溶于乙醇,丙酮和氯仿等有机溶剂,但一般在水中无法溶解;其特征是,它能够作为各种催化工艺的前体,特别是在有机合成和聚合反应中发挥作用;丙烯酸酯以其热稳定性著称,可在加热时溶解,释放金属;该化合物常常用于制备纳米粒子,并因其有利的电子特性,在交叉反应中作为催化剂,如铃木和赫克反应;在处理该化合物时,应注意安全防范措施,因为如果浸泡或吸入,可能会对健康造成危害,应使用适当的防护设备.

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    专利信息


    专利号:US-7615169-B2
    优先权日:2004-09-20
    标题 :Method for synthesis of colloidal nanoparticles
    发明人:STROUSE GEOFFREY FIELDING; GERBEC JEFFREY A; MAGANA DONNY
    权利人:UNIV CALIFORNIA
    摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

    专利号:WO-2025119975-A1
    优先权日:2023-12-04
    标 题:A method for synthesis of harmine
    发明人:HETT ROBERT; GRAB HANUSCH; LAGOUTTE ROMAN
    权利人:RECONNECT LABS AG
    摘要:The invention relates to a method of synthesis of a compound of formula (I), harmine, according to the method comprising a step of transforming the compound of formula (II), into the compound of formula (I). The invention further relates to a compound of formula (II), which is an intermediate in synthesis of harmine according to the present invention.

    专利号:US-7927516-B2
    优先权日:2004-09-20
    标题 :Method for synthesis of colloidal nanoparticles
    发明人:STROUSE GEOFFREY F; GERBEC JEFFREY A; MAGANA DONNY
    权利人:UNIV CALIFORNIA
    摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

    专利号:US-2025101006-A1
    优先权日:2022-01-31
    标题:Process for the synthesis of pyrazolyl derivatives useful as anti-cancer agents
    发明人:BAENZIGER MARKUS; GALLOU FABRICE; GUO FENGFENG; HÄNGGI RUDOLF; HAN ENJIAN; JORDINE GUIDO; LI JIALIANG; LIU WEIPENG; MIAO BUKEYAN; RONG SHAOFENG; SANTANDREA ERNESTO; SCHIRNER PAUL BERND; SHEN XIAODONG; WANG CAN; ZHANG HAO
    权利人:NOVARTIS AG
    摘要:The invention provides a novel process, novel process steps and novel intermediates useful in the synthesis of pharmaceutically active compounds, especially KRAS G12C inhibitors. The present invention provides a direct enantioselective chemical manufacturing method of making Compound A, or a pharmaceutically acceptable hydrate or solvent thereof: (I). The invention provides a process for preparing Intermediate B6* comprising reacting Intermediate B4* with Intermediate B5* in an atroposelective coupling reaction, using a chiral catalyst.

    专利号:US-10173993-B2
    优先权日:2015-12-09
    标题 :Process for the synthesis of sulfones and sulfonamides
    发明人:VON WOLFF NIKLAS; CHAR JOËLLE; CANTAT THIBAULT
    权利人:COMMISSARIAT ENERGIE ATOMIQUE
    摘要:A one pot single step process is described for the synthesis of a compound, including a labeled compound, containing a sulfonyl functional group comprising the step of mixing together a silane, an SO 2 source, an electrophilic compound, an activating compound and optionally a metal catalyst. A process for producing tracers from a labeled sulfonyl containing compound prepared by the described process is also included.

    专利号:US-11198684-B2
    优先权日:2017-07-28
    标 题 :Intermediates useful for the synthesis of a selective inhibitor against protein kinase and processes for preparing the same
    发明人:OH SANG-HO; KHOO JA-HEOUK; LIM JONG-CHUL; LEE DOO-BYUNG; LEE JUNG-AE; LEE JUN-SUP; JU HYUN; SHIN WOO-SEOB; JEON SANG-SEOL
    权利人:YUHAN CORP
    摘要:The present invention provides intermediates useful for the synthesis of an aminopyrimidine derivative or pharmaceutically acceptable salt thereof having a selective inhibitory activity against protein kinases, especially against the protein kinases for mutant epidermal growth factor receptors; and processes for preparing the same. And also, the present invention provides novel intermediates useful for said process and processes for preparing the same.
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    合成参考文献


    摘要:L794: Wikipedia. Palladium. Last Updated 14 June 2009.
    摘要:L798: International Programme on Chemical Safety (IPCS) INCHEM (2002). Environmental Health Criteria for Palladium.
    摘要:A21: Smith DR, Kahng MW, Quintanilla-Vega B, Fowler BA: High-affinity renal lead-binding proteins in environmentally-exposed humans. Chem Biol Interact. 1998 Aug 14;115(1):39-52.
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