CAS: 1750-12-5; Ahmt

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硫脲置于一水合肼体系中,化学反应生成4-氨基-3-肼基-5-巯基-1,2,4-三氮唑
参考文献:3-苯基-1-(6-苯基-7H-[1,2,4]三唑并[3,4-B][1,3,4]噻二嗪-3-基)的高效一锅快速合成-1H-Pyrazol-5-Amines 通过多组分方法
标题:3-苯基-1-(6-苯基-7H-[1,2,4]三唑并[3,4-B][1,3,4]噻二嗪-3-基)的高效一锅快速合成-1H-Pyrazol-5-Amines 通过多组分方法
摘要:摘要 3-苯基-1-(6-苯基-7H-[1,2,4]三唑并[3,4-B][1,3,4]噻二嗪-3-基)-1H-吡唑的高效合成-5-胺是通过一种简单的,原子经济的,多组分的方法完成的.4-氨基-5-肼基-4H-1,2,4-三唑-3-硫醇与各种苯甲酰溴和苯甲酰乙腈在乙醇和催化量的乙酸中反应,得到标题化合物.新合成化合物的结构通过其分析和光谱(ir,1H-NMR,13C-NMR 和质谱)数据得到证实.图形概要
Doi:10.1080/00397911.2018.1537398

专利信息

专利号:US-4841045-A
优先权日:1985-03-12
标 题 :Synthesis of vinblastine and vincristine type compounds
发明人：KUEHNE MARTIN
权利人:UNIV VERMONT
摘要:A new process for the stereospecific synthesis of alkaloids of the vinblastine and vincristine type including the synthesis of vinblastine and vincristine as well novel alkaloids which are active as anti-tumor agents.

专利号:US-4897477-A
优先权日:1985-03-12
标题:Synthesis of vinblastine and vincristine type compounds
发明人：KUEHNE MARTIN
权利人:UNIV VERMONT
摘要:A new process for the stereospecific synthesis of alkaloids of the vinblastine and vincristine type including the synthesis of vinblastine and vincristine as well novel alkaloids which are active as anti-tumor agents.

专利号:US-10655153-B2
优先权日:2017-03-14
标 题 :Chemoenzymatic synthesis of peptide beta-lactones and beta-hydroxy acids
发明人：WENCEWICZ TIMOTHY A; SCHAFFER JASON E; RECK MARGARET R
权利人:WENCEWICZ TIMOTHY A; SCHAFFER JASON E; RECK MARGARET R; UNIV WASHINGTON
摘要:Methods of producing peptide beta-lactones and beta-hydroxy acids are disclosed that include contacting a beta-hydroxy-alpha-amino acid, an aryl carrier protein (ObiD), and ATP with a non-ribosomal protein synthetase. A continuous flow reactor is disclosed that includes an elongate conduit with at least one region that includes a first region with a non-ribosomal protein synthetase immobilized to a substrate. The non-ribosomal protein synthetase of the continuous flow reactor is configured to contact a flow of a reaction mixture that includes a beta-hydroxy-alpha-amino acid and an aryl carrier protein. The non-ribosomal protein synthetase is further configured to release a peptide beta-lactone into the flow of the reaction mixture.

专利号:US-2025043324-A1
优先权日:2021-07-28
标 题:A low-cost, thermostable, lyophilized, cell-free protein synthesis platform
发明人：JEWETT MICHAEL CHRISTOPHER; WARFEL KATHERINE F
权利人:UNIV NORTHWESTERN
摘要:The present disclosure relates to stable, cost-effective, cell-free systems, compositions, methods, and kits for bio-manufacturing proteins. The systems, methods, and kits allow for cell-free bio-manufacturing of desired products in cell-free conditions, wherein the system can be stably stored or transported, in lyophilized form, at temperatures up to 50° C. for several weeks prior to use.

专利号:US-10006033-B2
优先权日:2013-03-14
标题 :Recombinant microorganisms having a methanol elongation cycle (MEC)
发明人：LIAO JAMES C; BOGORAD IGOR
权利人:UNIV CALIFORNIA
摘要:Provided are microorganisms that catalyze the synthesis of chemicals and biochemicals from a methanol, methane and/or formaldehyde. Also provided are methods of generating such organisms and methods of synthesizing chemicals and biochemicals using such organisms.

专利号:US-2018265905-A1
优先权日:2017-03-14
标 题:Chemoenzymatic synthesis of peptide beta-lactones and beta-hydroxy acids