CAS: 2031-62-1; Diethoxy(Methyl)Silane

该化合物是一个有机硅化合物,其特点是硅结构,其中包括将硅原子粘合成两个环氧组和一个甲基组,该化合物一般是一种无色液体,其气味温和,以其反应性能而闻名,特别是在水解和凝聚反应中;甲基二氧基硅烷在有机溶剂中可溶解,并可以与水发生反应,形成硅醇组,从而形成硅氧网络;在各种应用中,包括涂层,密封剂和粘合剂,通常用作合剂,粘合剂和表面修饰剂;此外,该化合物在硅酮聚合物的生产中发挥作用,并能提高材料的机械特性和耐久性;安全考虑包括在通风良好的地区处理该物质,并使用适当的个人防护设备,因为接触皮肤或眼睛时可能会引起刺激.

结构式图片

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CAS号75-54-7 甲基二氯硅烷 | CAS号122-51-0 原甲酸三乙酯 | CAS号78-10-4 正硅酸乙酯 | CAS号1825-62-3 三甲基乙氧基硅烷 | CAS号64-17-5 乙醇 | CAS号1067-99-8 4-(diethoxymeth... | CAS号5507-44-8 甲基乙烯基二乙氧基硅烷 | CAS号146781-28-4 4-乙氧基甲基苯甲酸 | CAS号18043-74-8 1,2-双(甲基二乙氧基硅基)乙烷 | CAS号2031-67-6 三乙氧基甲基硅烷 | CAS号18001-60-0 1,1,3,3-四乙氧基-1,... | CAS号2897-60-1 3-缩水甘油醚氧基丙基甲基二乙氧基硅烷 | CAS号992-94-9 甲基硅烷 | CAS号539-30-0 苄基乙基醚 | CAS号688004-16-2 chloro-(3-chlor...

合成工艺路线路线简述

    2-(Diethoxy-Methyl-Silyl)-Propionitril置于co Catalyst 氢气体系中,化学反应生成甲基二乙氧基硅烷
    参考文献:Effect Of The Structure Of A Silicon-Containing Nitrile On The Course Of Its Catalytic Reduction
    标题:Effect Of The Structure Of A Silicon-Containing Nitrile On The Course Of Its Catalytic Reduction
    摘要:
    Doi:10.1007/bf00845748

    海关参考信息

    专利信息


    专利号:US-2013165350-A1
    优先权日:2011-12-22
    标 题:Surface linkers for array synthesis
    发明人:KUIMELIS ROBERT; MCGALL GLENN; PAO DEXTER; CHEN ZIHUI; AXELROD TREVOR
    权利人:KUIMELIS ROBERT; MCGALL GLENN; PAO DEXTER; CHEN ZIHUI; AXELROD TREVOR; AFFYMETRIX INC
    摘要:The present invention provide several methods of derivatizing a surface of a support with one or more linkers thus providing a suitable platform for synthesis of a polymer array, particular a nucleic acid array. Some methods derivatize a surface with a self-assembled monolayer (SAM) of a linker. The SAM confers advantages of hydrolytic stability, broad compatibility with synthesis and detection chemistries, and reduced emergence of latent functional groups during polymer array synthesis. Substrates can also be derivatized with multi-layers of SAMs providing greater hydrolytic stability. Substrates can also be derivatized by synthesizing a linker in situ on the substrate by atom transfer radical polymerization of functional and functional monomers. Appropriate selection of monomers reduces emergence of latent functional groups in subsequent array synthesis.

    专利号:US-11033507-B2
    优先权日:2013-12-19
    标 题 :Method of synthesis of silica vesicles and use thereof
    发明人:YU CHENGZHONG; MITTER NEENA; ZHANG JUN
    权利人:UNIV QUEENSLAND
    摘要:The invention relates, in part, to a method of producing silica vesicles including under controlled conditions to thereby heavily influence the morphology and characteristics of the vesicles. The vesicles are shown to be effective as delivery agents for chemical and biological agents. They are also shown to be useful in methods of treatment and as components of an immunogenic composition.

    专利号:US-6124418-A
    优先权日:1992-06-11
    标题 :Selective catalysts for the synthesis of epoxysilicone monomers and polymers
    发明人:CRIVELLO JAMES VINCENT; FAN MINGXIN
    权利人:GEN ELECTRIC
    摘要:The invention provides a method for making a curable epoxysilicone composition through the hydrosilation reaction between an ethylenically unsaturated epoxide and an SiH-containing silicone to produce an epoxysilicone product, and catalyzed by a quaternary ammonium, phosphonium or arsonium hexahaloplatinate which does not promote the oxirane ring-opening reaction of either the ethylenically unsaturated epoxide starting material or the epoxysilicone product. The invention also provides for a curable epoxysilicone composition made by the above method.

    专利号:US-5272233-A
    优先权日:1992-07-17
    标题 :Platinum-based catalysts for the polymerization of vinyl ether monomers and polymers
    发明人:CRIVELLO JAMES V; FAN MINGXIN
    权利人:GEN ELECTRIC
    摘要:The present invention relates to a curable polyvinyl ether composition created using a novel catalyst system for the synthesis of polyethers from vinyl ether monomers or polymers. This catalyst system comprises a platinum complex catalyst and silicon hydride cocatalyst. The invention also relates to a method of producing polyethers from vinyl ether monomers or polymers using the above-mentioned catalyst system.

    专利号:US-6642403-B2
    优先权日:2001-11-07
    标 题:Silicon-based blocking agents suitable for fluorous phase synthesis
    发明人:ARKLES BARRY C; PAN YOULIN; LARSON GERALD L
    权利人:GELEST INC
    摘要:This invention relates to a series of fluoroalkylsilane compounds of formula I. n These compounds are silylation reagents which enhance the solubility of the silylated products in fluorocarbon solvents for preferred use in fluorous phase synthesis. Use of these compounds protects fragile hydrogen groups and also provides for the straightforward separation of the ultimate reaction products though fluorous phase extraction. This invention also relates to a two-step process for making compounds of formula I. The process comprises reacting an alkyldialkoxysilane with a perfluoroalkyl-substituted silane to produce a perfluoroalkyl-substituted dialkylsiloxyalkylsilane intermediate; and reacting the intermediate with halogen.

    专利号:US-7402648-B2
    优先权日:2004-11-05
    标 题 :Method for producing cyclic organic silicon compound and organic silicon resin having alcoholic hydroxyl group
    发明人:KOMURO KATSUHIKO; SUZUKI HIROSHI
    权利人:TOAGOSEI CO LTD
    摘要:The object of the present invention is to provide a production method wherein synthesis of a cyclic organic silicon compound similar to oxa-silacyclopentanes is completed in a single-step reaction. It is also to provide an organic silicon resin having an alcoholic hydroxyl group, which is capable of easily controlling its construction and is longitudinally stable. n The means for solving is to produce the cyclic organic silicon compound represented by the formula (3) below by reacting an olefin represented by the formula (1) below and an alkoxysilane represented by the formula (2) below in the presence of a catalyst comprising a transition metal. n n(In the formula, Z is alkenyl group having carbon atoms from 2 to 5 where the terminal carbon atom forms a Câ•?C bond, R is methyl group or hydrogen atom, and Me is methyl group.)n n n(In the formula, R 1 is alkyl group or alkoxyl group, having carbon atoms from 1 to 3, and R 2 is alkyl group having carbon atoms from 1 to 3.)n n n(In the formula, Z′ is alkylene group having carbon atoms from 2 to 5.)n n And it is an organic silicon resin having an alcoholic hydroxyl group obtained by performing hydrolysis and condensation of a cyclic organic silicon compound represented by the formula (3) above, or of a mixture of this and a polyfunctional alkoxyilane.
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    主要参考文献

    参考标题:Neutral Dinuclear Copper(I)-Nhc Complexes: Synthesis And Application In The Hydrosilylation Of Ketones
    作者:Michael Trose,Faïma Lazreg,Tao Chang,Fady Nahra,David B. Cordes,Alexandra M. Z. Slawin,Catherine S. J. Cazin |发布日期:2017.1.6
    摘要:The Synthesis Of A Class Of Highly Stable Neutral Dinuclear Cu(I)-Nhc Complexes Using 1,2,4-Triazole As A Bridging Ligand Is Described. Various Nhcs Were Used To Generate A Library Of [cu(μ-Trz)(Nhc)]2 Complexes. Interestingly, [cu(μ-Trz)(Ipr)]2 Was Found To Be Highly Active In The Hydrosilylation Of Ketones, Without The Need For An External Base Or Any Other Additive. A Wide Range Of Aryl And Alkyl

    合成参考文献


    摘要:Taylor, R. E.; Diène, C. R.; Daly, E. M., Science of Synthesis, (2009) 46, 584.
    摘要:Clark, R. W.; Wiskur, S. L., Science of Synthesis Knowledge Updates, (2015) 1, 16.
    摘要:Clark, R. W.; Wiskur, S. L., Science of Synthesis Knowledge Updates, (2015) 1, 30.
    摘要:Wu, X.-F., Science of Synthesis Knowledge Updates, (2014) 1, 328.
    摘要:Anderson, E. A.; Lim, D. S. W., Science of Synthesis Knowledge Updates, (2015) 1, 70.
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