56-81-5 = 111-29-5 + 1191-25-9 + 627-98-5 + 626-89-1 + 2508-29-4 + 13325-10-5 + 629-11-8 反应条件:1.1 Reagents: Calcium Pantothenate,Mops,Disodium Phosphate,Ferrous Sulfate,Ammonium Sulfate,Ammonium Chloride Catalysts: Acetyl Coenzyme A Acetyltransferase,Acyl Coenzyme A Dehydrogenase,3-Hydroxyacyl Coenzyme A Dehydrogenase,Alcohol Dehydrogenase,Fatty Acyl Coenzyme A Reductase (Aldehyde-Forming) Solvents: Water; 37 °C 标题:Production Of Functionalized Carboxylic Acids And Alcohols By Reverse Fatty Acid Oxidation In Metabolically Engineered Microorganisms 参考文献:United States]
= 111-29-5 反应条件:1.1 Reagents: Methanesulfonic Acid,1,1,1-Trifluoro-,Cerium(4+) Salt (4:1) Solvents: Acetonitrile; 2 H,Rt 标题:Deprotection Of Tert-Butyldimethylsilyl Ethers Promoted By Cerium(Iv) Triflate 作者:Bartoli,Giuseppe; Et Al 参考文献:Tetrahedron Letters 日期:2002 卷标:43(34) 页码:5945-5947]
= 111-29-5 + 930-68-7 + 96-41-3 + 6243-10-3 + 4645-15-2 + 177738-29-3 + 959026-72-3 + 6222-35-1 + 931-17-9 + 629-11-8 反应条件:1.1 157 - 158 °C 标题:Intensification Of Cyclohexanone Purification Stage From Impurities In Caprolactam Production Using Phase Transfer Catalysis 作者:Martynenko,E. A.; Glazko,I. L.; Levanova,S. V.; Portnova,Yu. V. 参考文献:Russian Journal Of Applied Chemistry 日期:2014 卷标:87(7) 页码:899-903]
= 111-29-5 + 6920-22-5 + 107-21-1 + 87-99-0 + 56-81-5 + 87-78-5 反应条件:1.1 Catalysts: Nickel; 26 H,11.4 Mpa,190 °C; 8 Mpa1.2 Reagents: Water; Cooled 标题:Optimisation Of The Processing Conditions Of Hydrolytic Hydrogenation Of Cellulose Using Carbon Nanofiber Supported Ni Catalysts 作者:Frecha,E.; Remon,J.; Torres,D.; Suelves,I.; Pinilla,J. L. 参考文献:Catalysis Today 日期:2023 卷标:423]
= 111-29-5 反应条件:1.1 Solvents: Methanol 标题:Selective Deprotection Of Triethylsilyl Group In The Presence Of Tert-Butyldimethylsilyl Group With Mcm-41/meoh Heterogeneous System 作者:Itoh,Akichika; Et Al 参考文献:Synlett 日期:1999 卷标:(3) 页码:357-359]
= 111-29-5 反应条件:1.1 Reagents: Hydrogen Catalysts: Palladium Dihydroxide Solvents: Methanol 标题:The Selective Distinction Of Diethylisopropylsilyl Ether In Hydrogenolysis 作者:Toshima,Kazunobu; Et Al 参考文献:Tetrahedron Letters 日期:1990 卷标:31(46) 页码:6697-8]
= 111-29-5 反应条件:1.1 Reagents: Acetic Acid,Water Solvents: Tetrahydrofuran 标题:The Diethylisopropylsilyl Group: A New Protecting Group For Alcohols 作者:Toshima,Kazunobu; Et Al 参考文献:Tetrahedron Letters 日期:1989 卷标:30(46) 页码:6413-16]
= 111-29-5 反应条件:1.1 Reagents: Methanesulfonic Acid,1,1,1-Trifluoro-,Cerium(4+) Salt (4:1) Solvents: Acetonitrile; 1 H,Rt 标题:Deprotection Of Tert-Butyldimethylsilyl Ethers Promoted By Cerium(Iv) Triflate 作者:Bartoli,Giuseppe; Et Al 参考文献:Tetrahedron Letters 日期:2002 卷标:43(34) 页码:5945-5947]
= 111-29-5 反应条件:1.1 Reagents: Imidazole Solvents: Dichloromethane2.1 Reagents: Acetic Acid,Water Solvents: Tetrahydrofuran 标题:The Diethylisopropylsilyl Group: A New Protecting Group For Alcohols 作者:Toshima,Kazunobu; Et Al 参考文献:Tetrahedron Letters 日期:1989 卷标:30(46) 页码:6413-16
糠醇置于trans-Decalin,氢气体系中,用 异丙醇 用作溶剂,149.84 °C,2.0 Mpa 条件下,反应 24.0H,以41.9%的收率获得1,5-戊二醇 参考文献:Ni-Y2O3复合催化剂上糠醇的氢解反应合成1,5-戊二醇 标题:Ni-Y2O3复合催化剂上糠醇的氢解反应合成1,5-戊二醇 摘要:在ni中添加y 2 O 3形成了一种复合催化剂,该催化剂在糠醇在2.0 Mpa H 2和423 K的氢解中选择性地产生1,5-戊二醇而不是1,2-戊二醇.显然,1,5-戊二醇在ni 0-Y 2 O 3边界上产生.该报告重点介绍了由糠醇合成1,5-戊二醇时ni-Y 2 O 3的性质,催化性能和反应路线. Doi:10.1002/cctc.201700066
专利号:WO-9900440-A1 优先权日:1997-06-26 标 题:Synthesis of a dendritic polyalcohol 发明人:IHRE HENRIK; HULT ANDERS 权利人:PERSTORP AB; IHRE HENRIK; HULT ANDERS 摘要:A process for a double stage convergent synthesis of a polymeric polyalcohol substantially and preferably built up from polyester units and composed of a monomeric or polymeric core to which at least one hyperbranched dendritic branch (dendron) consisting of a number of branching generations is added. The branching generations comprise a polymeric or monomeric branching chain extender having three reactive functions of which two are hydroxyl groups and one is a carboxyl group. The two hydroxyl groups of the branching chain extender is in a first step ketal protected by reacting said two hydroxyl groups with a ketal. A second step includes protection of the carboxyl group of said branching chain extender. The ketal protected branching chain extender and the carboxyl protected chain extender are then employed for repeated addition in a number of step yielding a predetermined number of branching generations. The thus synthesized dendron is finally added to a core having reactive hydroxyl or epoxide groups and the ketal protected hydroxyl groups are optionally deprotected.
专利号:US-5352670-A 优先权日:1991-06-10 标题:Methods for the enzymatic synthesis of alpha-sialylated oligosaccharide glycosides 发明人:VENOT ANDRE P; UNGER FRANK M; KASHEM MOHAMMED A; BIRD PAUL; MAZID M ABDUL 权利人:ALBERTA RES COUNCIL 摘要:Disclosed are methods for the enzymatic synthesis of alpha-sialylated oligosaccharide glycosides. Specifically, in the disclosed methods, sialyltransferase is activated to transfer an analogue of sialic acid, employed as its CMP-nucleotide derivative, to an oligosaccharide glycoside. The analogue of sialic acid and the oligosaccharide employed in this method are selected to be compatible with the sialyltransferase employed.
专利号:WO-2024003243-A1 优先权日:2022-06-29 标 题 :Process for the synthesis of poly-4-hydroxybutyrate 发明人:SCHAUB THOMAS; BRUCHMANN BERND; RODEWALD DIETER; NICOLAS MATHIEU; FALCONNET ALBAN 权利人:BASF SE; UNIV HEIDELBERG RUPRECHT KARLS 摘要:Described are a process for the synthesis of poly-4-hydroxybutyrate, the use of a kit comprising (i) one or more bases comprising an alkaline metal cation and (ii) one or more alcohols in said process and to poly-4-hydroxybutyrate obtainable by said process.
专利号:WO-2018186744-A1 优先权日:2017-04-05 标 题 :Synthesis and use of carbohydrate-based linear polyesters 发明人:PICCHIONI FRANCESCO; GAVRILA IONELA 权利人:UNIV GRONINGEN 摘要:The invention relates to the field of polymer chemistry, more in particular to the synthesis of novel biobased linear polymers and their applications, among others as rheology modifiers or thickeners in waterborne formulations. Provided is a method for providing a linear carbohydrate-based polyester, comprising (i) reacting a bicyclic acetalized galactaric acid derivative (Galx) with a diol in the presence of a suitable catalyst to obtain a Galx -based polyester; and (ii) subjecting said Galx -based polyester to a hydrolytic deacetalisation reaction to convert at least part of the diacetal moieties to chhydroxide moieties.
专利号:US-6291620-B1 优先权日:1994-11-09 标 题:Polymer synthesis 发明人:MOAD GRAEME; MOAD CATHERINE LOUISE; KRSTINA JULIA; RIZZARDO EZIO; DARLING THOMAS ROBERT; BERGE CHARLES THOMAS 权利人:DU PONT; COMMW SCIENT IND RES ORG 摘要:Process for the synthesis of block polymers, homopolymers and copolymers of narrow polydispersity having formula (1) by contacting selected vinyl monomer(s), vinyl-terminated compound(s) and free radicals in which effective control of production of polymer is achieved by controlling the mole ratio of vinyl monomer(s), vinyl-terminated compound(s) and free radicals relative to one another; and polymers produced thereby
专利号:US-6211329-B1 优先权日:1997-06-26 标题:Process for preparation of a dendritic polyol 发明人:REHNBERG NICOLA; PETTERSSON BO; ANNBY ULF; MALMBERG MATS 权利人:PERSTORP AB 摘要:A process for synthesis of a polymeric polyalcohol substantially and preferably built up form polyester units and composed of a monomeric or polymeric initiator molecule to which at least one dentritic branch (dendron) consisting of a number of branching generations is added. The branching generations comprise a polymericor monomeric branching chain extender having three reactive functions of which two are hydroxyl groups. The two hydroxyl groups of the ranching chain extender is acetal protected by reaction between said two hydroxyl groups and an acetal-forming carbonyl compound, preferably an aldehyde. The acetal protected branching chain extender is then employed for addition to the initiator molecule of a first branching generation followed by an optional deprotection of the hydroxyl groups by decomposition of acetals and for addition in repeated steps of further branching generations. Additions of branching generations individually employ an acetal protected branching chain extender synthesized from the same or a different branching chain extender and/or acetal-forming carbonyl compound and addition of a branching generation is optionally followed by addition of a spacing generation.
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合成参考文献
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