CAS: 2396-68-1; 4-Tert-Butylbenzenethiol

上下游产品

4-tert-butylbenzenesulfonyl chloride tert-butyl phenyl sulfide thiophenol isobutene S-(4-tert-butyl-phenyl ester)benzenethiosulfinic acid S-(4-tert-butyl-phenyl ester) 2-((4-tert-butylphenyl)thio)benzoic acid tert-butyl-phenylsulfanyl)-3-methyl-crotonaldehyde2-(4-tert-butyl-phenylsulfanyl)-3-methyl-crotonaldehyde tert-butyl-phenyl)-(2,4-dinitro-phenyl)-sulfide(4-tert-butyl-phenyl)-(2,4-dinitro-phenyl)-sulfide

对叔丁基苯磺酰氯置于硫酸,水,锌体系中,化学反应 5.0H,以85%的收率获得4-叔丁基苯硫酚
参考文献:四(2,3-噻吩并)-四氮杂卟啉及其四叔丁基衍生物及其mg(II),Al(III),Ga(III)和in(III)配合物的合成和光谱研究
标题:四(2,3-噻吩并)-四氮杂卟啉及其四叔丁基衍生物及其mg(II),Al(III),Ga(III)和in(III)配合物的合成和光谱研究
摘要:从容易获得的苯硫酚(phsh (1A),4-叔丁基-Phsh (1B))和草酰氯开始,我们制备了 2,3-噻吩醌 2A,B,然后将其依次转化为噻吩-2,3-二羧酸 4A,B 他们的酰亚胺 10A,B,二酰胺 9A,B,最后是噻茚-2,3-二甲腈 11A,B-具有四个 2,3-环化噻茚部分的新型四嗪系列的关键前体.游离碱 12A,B 是通过二腈 11A,B 在锂存在下在正戊醇中的环四聚获得的,而与丁醇镁 (II) 在正丁醇中的反应产生 Mg(II) 配合物 13A.通过二腈 11A,B 在熔体中与相应的 (羟基)乙酸盐.利乐(2,3-噻茚)四氮杂卟啉12A及其金属配合物13A-15A仅微溶于普通有机溶剂,其叔丁基取代衍生物12B,14B-16B的溶解度增强.对电子吸收光谱的研究表明,由于环化的角度类型(类似于在 1,2-萘酞菁中发现的)和负感应效应,四个噻吩碎片融合导致四氮杂 π-发色
Doi:10.1142/s1088424611002969

专利信息

专利号:US-8053161-B2
优先权日:2006-09-25
标 题 :Resist composition, resin for use in the resist composition, compound for use in the synthesis of the resin, and pattern-forming method using the resist composition
发明人：WADA KENJI; SAEGUSA HIROSHI
权利人:FUJIFILM CORP
摘要:A resist composition comprises: (A) a resin capable of increasing its solubility in an alkali developer by action of an acid; (B) a compound capable of generating an acid upon irradiation with actinic ray or radiation; (C) a resin having at least one of a fluorine atom and a silicon atom; and (D) a solvent, wherein the resin (C) has a degree of molecular weight dispersion of 1.3 or less and a weight average molecular weight of 1.0×10 4 or less.

专利号:EP-0609960-B1
优先权日:1989-09-15
标 题 :New N-heteroarylamide derivatives as inhibitors of acyl coenzyme A: cholestrol acyl transferase
发明人：MCCARTHY PETER A; HAMANAKA ERNEST S; WALKER FREDERICK J; CHANG GEORGE; TRUONG THIEN
权利人:PFIZER
摘要:Compounds of the formula the pharmaceutically acceptable salts thereof, wherein Q and R<1> are as defined below, and novel carboxylic acid and acid halide intermediates used in the synthesis of such compounds. The compounds of formula I are inhibitors of acyl coenzyme A: cholesterol acyltransferase (ACAT) and are useful as hypolipidemic and antiatherosclerosis agents.

专利号:US-9709891-B2
优先权日:2005-12-09
标 题:Positive resist composition, resin used for the positive resist composition, compound used for synthesis of the resin and pattern forming method using the positive resist composition
发明人：KANDA HIROMI; KANNA SHINICHI
权利人:FUJIFILM CORP
摘要:A positive resist composition comprises: (A) a resin of which solubility in an alkali developer increases under an action of an acid; (B) a compound capable of generating an acid upon irradiation with actinic rays or radiation; (C) a resin having at least one of a fluorine atom and a silicon atom; and (D) a solvent; and a pattern forming method using the positive resist composition.

专利号:US-5656634-A
优先权日:1991-03-21
标题 :N-aryl and N-heteroarylamide and urea derivatives as inhibitors of acyl coenzyme A: cholesterol acyl transferase (ACAT)
发明人：CHANG GEORGE; HAMANAKA ERNEST S; MCCARTHY PETER A; TRUONG THIEN V; WALKER FREDERICK J
权利人:PFIZER
摘要:Compounds of the formula ##STR1## the pharmaceutically acceptable salts thereof, wherein Q and R 1 are as defined below, and novel carboxylic acid and acid halide intermediates used in the synthesis of such compounds. The compounds of formula I are inhibitors of acyl coenzyme A: cholesterol acyltransferase (ACAT) and are useful as hypolipidemic and antiatherosclerosis agents.

专利号:US-4490532-A
优先权日:1980-07-28
标 题 :Synthesis of 2-[1-(2,5-dimethylphenyl)ethylsulfonyl]pyridine-1-oxide herbicide and intermediates therefor
发明人：HARRIS JOHN W
权利人:UNIROYAL LTD
摘要:Hydrogen chloride is passed into p-xylene and acetaldehyde to form bis-1-chloroethyl ether; the latter is converted to 2-(1-chloroethyl)-1,4-dimethylbenzene by the action of sulfuric acid and hydrogen chloride. Alkali metal hydrogen sulfide in aqueous methanol or ethanol converts the 2-(1-chloroethyl)-1,4-dimethylbenzene to alpha,2,5-trimethylbenzenemethanethiol; the sodium salt of the latter reacted with 2-chloropyridine-1-oxide yields 2-[1-(2,5-dimethylphenyl)ethylthio]pyridine-1-oxide which is then oxidized with hydrogen peroxide and alkali metal tungstate or tungstic acid to form 2-[1-(2,5-dimethylphenyl)ethylsulfonyl]pyridine-1-oxide.

专利号:EP-2104157-A1
优先权日:2006-12-29
标题 :Solution containing organic el material, method for synthesis of organic el material, compound synthesized by the synthesis method, method for formation of thin film of organic el material, thin film of organic el material, organic el element