CAS: 4488-40-8; 4-Methyl-1-Naphthoic Acid

该化合物是一种氯化萘衍生物,在1号站位上有一个箱状酸功能组,在4号站位上有一个甲基替代组,该化合物是有机合成的多种中间体,特别是在制药,农用化学品和特殊化学品的制作方面,其僵硬的芳香结构和功能组使它适合金属-有机框架和液晶材料的应用.该甲基组提高了有机溶液的溶解性,有利于进一步的衍生.该物质具有高纯度,可用于研究和工业用途,确保合成途径的一贯性能.由于潜在的刺激特性,建议进行适当的处理.

结构式图片

相似化合物

33738-48-6 57322-44-8 36062-93-8

欧盟法规

ECHA物质C&L通报

上下游产品

4-甲基-1-萘醛 4-Methyl-1-Naphthaldehyde 33738-48-6
(1-甲基萘-4-基)甲醇 4-Methyl-1-Naphthylmethanol 57322-44-8
Acetic Acid-(4-Methyl-[1]Naphthylmethyl Ester) 49675-07-2
4-甲基-1-萘乙酮 1-Acetyl-4-Methylnaphthalene 28418-86-2
1,4-二甲基萘 1,4-Dimethylnaphthalene 571-58-4

合成工艺路线路线简述

    1,4-二甲基萘置于9,10-二氰基蒽,氧气体系中,用 乙腈 作为反应溶剂,化学反应生成 4-甲基-1-萘甲酸
    参考文献:Photooxygenations Par Transfert D'Electron Sensibilisees Par Le Dicyano-9,10 Anthracene. Role Du Solvant Et Formation D'Oxygene Singulet.
    标题:Photooxygenations Par Transfert D'Electron Sensibilisees Par Le Dicyano-9,10 Anthracene. Role Du Solvant Et Formation D'Oxygene Singulet.
    摘要:
    DOI:10.1016/s0040-4039(01)81182-5

    海关参考信息

    专利信息


    专利号:US-7943723-B2
    优先权日:2006-12-21
    标 题:Process for the synthesis of ethers of aromatic acids
    发明人:RITTER JOACHIM C
    权利人:DU PONT
    摘要:The inventions disclosed herein include processes for the preparation of an ether of an aromatic acid, processes for the preparation of products into which such an ether can be converted, the use of such processes, and the products obtained and obtainable by such processes. A key feature of the processes described is the use of a solvent comprising an alcohol ROH and an alcoholate RO − M + .

    专利号:US-8207374-B2
    优先权日:2006-12-21
    标 题:Process for the synthesis of ethers of aromatic acids
    发明人:RITTER JOACHIM C
    权利人:RITTER JOACHIM C; DU PONT
    摘要:Ethers of aromatic acids are produced from halogenated aromatic acids in a reaction mixture containing a copper (I) or copper (II) source and a diketone ligand that coordinates to copper.

    专利号:US-2011060118-A1
    优先权日:2009-09-02
    标 题:Process for the synthesis of fluorinated ethers of aromatic acids
    发明人:RITTER JOACHIM C; MOLOY KENNETH GENE; POLLINO JOEL M; MAHAJAN DU SURBHI
    权利人:DU PONT
    摘要:Fluorinated ethers of aromatic acids are produced from halogenated aromatic acids in a reaction mixture containing a copper (I) or copper (II) source and a Schiff base ligand that coordinates to copper. The fluorinated ethers of aromatic acids made using the process described herein can be applied to, e.g., fibers, yarns, carpets, garments, films, molded parts, paper and cardboard, stone, and tile to impart soil, water and oil resistance. By incorporating the fluorinated ethers of aromatic acids, or diesters thereof, into polymer backbones, more lasting soil, water and oil resistance, as well as improved flame retardance, can be achieved.

    专利号:US-7985825-B2
    优先权日:2006-12-21
    标 题 :Process for the synthesis of ethers of aromatic acids
    发明人:RITTER JOACHIM C
    权利人:DU PONT
    摘要:Ethers of aromatic acids are produced from halogenated aromatic acids in a reaction mixture containing a halogenated aromatic acid such as is described by the structure of Formula II n nwherein each X is independently Cl, Br or I; the reaction mixture further comprising;n (i) a polar protic solvent, a polar aprotic solvent or an alcoholic solvent containing the alcoholate RO-M+ (wherein M is Na or K), wherein the polar protic solvent, polar aprotic solvent or alcoholic solvent is either ROH or is a solvent that is less acidic than ROH; (ii) a copper (I) or copper (II) source; and (iii) an amino acid ligand that coordinates to copper, wherein the ligand comprises an amino acid in which the amine nitrogen and the carboxyl carbon are separated by no more than two carbon atoms.

    专利号:US-2011060117-A1
    优先权日:2009-09-02
    标题:Process for the synthesis of fluorinated ethers of aromatic acids
    发明人:RITTER JOACHIM C; MOLOY KENNETH GENE; POLLINO JOEL M; MAHAJAN DU SURBHI
    权利人:DU PONT
    摘要:Fluorinated ethers of aromatic acids are produced from halogenated aromatic acids in a reaction mixture containing a copper (I) or copper (II) source and a diamine ligand that coordinates to copper. The fluorinated ethers of aromatic acids made using the process described herein can be applied to, e.g., fibers, yarns, carpets, garments, films, molded parts, paper and cardboard, stone, and tile to impart soil, water and oil resistance. By incorporating the fluorinated ethers of aromatic acids, or diesters thereof, into polymer backbones, more lasting soil, water and oil resistance, as well as improved flame retardance, can be achieved.

    专利号:US-2011060161-A1
    优先权日:2009-09-02
    标题 :Process for the synthesis of fluorinated ethers of aromatic acids
    发明人:RITTER JOACHIM C; MOLOY KENNETH GENE; POLLINO JOEL M; DU SURBHI MAHAJAN
    权利人:DU PONT
    摘要:Fluorinated ethers of aromatic acids are produced from halogenated aromatic acids in a reaction mixture containing a copper (I) or copper (II) source and a diketone ligand that coordinates to copper. The fluorinated ethers of aromatic acids made using the process described herein can be applied to, e.g., fibers, yarns, carpets, garments, films, molded parts, paper and cardboard, stone, and tile to impart soil, water and oil resistance. By incorporating the fluorinated ethers of aromatic acids, or diesters thereof, into polymer backbones, more lasting soil, water and oil resistance, as well as improved flame retardance, can be achieved.
    宁波英特格瑞生物科技有限公司
    ⚠️ 未注册 · 未认证企业
    ⚠️ 该商家尚未完成注册及企业认证,请用户仔细辨别,谨慎交易。
    数据来源于公开网络搜索,平台未作核实,请自行辨别。
    🏢敬请 企业认领
    🏬开设公司展台
    📢获取免费会员权益
    🎖️点亮专属注册企业标签
    📇展现公司完整信息 样本查看立即注册认领 →
    网址: http://www.integrity-bio.com
    企业联系电话:0574-86822786👤
    📞宁波英特格瑞生物科技有限公司 ⚠️参考联系方式
    联系人:石经理
    电话:0574-86822786
    手机:15824278467
    传真:0574-86821822
    邮箱:sales@integrity-bio.com
    通信地址: 宁波北仑区明州路731号长江国际A座1209室
    邮编: 315000
    🆔 联系时候可告知是从"百琢研"平台获取的信息.
    ⚠️ 声明: 该企业未认证、未认领,请自行辨别信息的真实性和可靠性。咨询或交易时请注意风险评估与信息核实,百琢研不参与任何交易。企业认领注册入口→

    地址:宁波北仑区明州路731号长江国际A座1209室
    ⚠️ 未注册 · 未认证企业
    注册入口 备注: 📌 数据来源说明:本展台内容基于各搜索引擎等公开数据整理,仅作展示用途。请用户自行辨别
    ✉️ 若企业需抹除展台内容或有异议, 请通过页面底部联系方式告知我们,我们会尽快处理。
    湖北澳格森化工有限公司
    ⚠️ 未注册 · 未认证企业
    ⚠️ 该商家尚未完成注册及企业认证,请用户仔细辨别,谨慎交易。
    数据来源于公开网络搜索,平台未作核实,请自行辨别。
    🏢敬请 企业认领
    🏬开设公司展台
    📢获取免费会员权益
    🎖️点亮专属注册企业标签
    📇展现公司完整信息 样本查看立即注册认领 →
    网址: http://www.orgsyn.com.cn
    企业联系电话:0724-8619888 13808670258👤
    📞湖北澳格森化工有限公司 ⚠️参考联系方式
    联系人:周先生
    电话:0724-8619888 13808670258
    手机:13808670258
    传真:0724-8619018
    邮箱:zhou@orgsyn.com.cn
    通信地址: 湖北省沙洋县经济开发区工业二路9#
    邮编:
    🆔 联系时候可告知是从"百琢研"平台获取的信息.
    ⚠️ 声明: 该企业未认证、未认领,请自行辨别信息的真实性和可靠性。咨询或交易时请注意风险评估与信息核实,百琢研不参与任何交易。企业认领注册入口→

    地址:湖北省沙洋县经济开发区工业二路9#
    ⚠️ 未注册 · 未认证企业
    注册入口 备注: 📌 数据来源说明:本展台内容基于各搜索引擎等公开数据整理,仅作展示用途。请用户自行辨别
    ✉️ 若企业需抹除展台内容或有异议, 请通过页面底部联系方式告知我们,我们会尽快处理。
    第 1 / 1 页
    现货

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    [参考文献]: Jincan Zhao, Et Al. Iron-Catalyzed Cross-Dehydrogenative Coupling Esterification Of Unactive C(Sp3)-H Bonds With Carboxylic Acids For The Synthesis Of α-Acyloxy Ethers. J Org Chem. 2014 May 2;79(9):3847-55.

    合成参考文献


    摘要:Vashchenko, B. V.; Grygorenko, O. O., Science of Synthesis Knowledge Updates, (2021) 3, 410.
    📝 需求与反馈
    尽可能描述清楚需求与问题信息
    ×

    通知