CAS: 79-05-0; Propionamide

• 英文名称Propionamide
• 中文名称丙酰胺
• IUPAC名称propionamide
• 其它别名Propanamide; Propylamide
• CAS编号79-05-0
• MFCD编号:MFCD00008039
• EINECS号:201-172-1
• FDA UNII编号:QK07G0HP47
• 分子式:C3H7NO
• 分子量:73.09
• 产品CID: 1784264
• 产品分类有机原料→分子砌块→脂肪链类化合物

• 相似结构搜索
• 产品信息参考;;
• InChIKey: QLNJFJADRCOGBJ-UHFFFAOYSA-N
• InChI=1S/C3H7NO/c1-2-3(4)5/h2H2,1H3,(H2,4,5)…
• 计算化学: 氢键受体数1.0氢键供体数1.0可旋转键数1.0

相似化合物

物理性质

• 熔点79°C
• 沸点213°C at 760 mmHg
• 闪点213°C
• 密度1.010 g/cm3
• pKa:16.60±0.40(预测)
• PSA:43.09
• LogP:-0.1183
• 折射率1.409
• 蒸汽压0.04 mmHg
• 溶解性可溶于水
• 外观形态白色至微黄色结晶性粉末
• 储存条件Store at room temperature
• 产品应用用于有机合成.
• 性质描述白色片状结晶.熔点79°C,沸点222.2°C,相对密度1.0335,折光率1.4160(110°C).溶于水,乙醇,乙醚和氯仿.能随水蒸气挥发.

MSDS等安全信息

• GHS象形图
• GHS符号GHS07;
  注释: Exclamation mark
• 危险类别严重眼刺激 类别2
  急性毒性 类别4(经口)
• 警示词Warning(警告)
• 危险描述H319 |造成严重眼刺激.
  H302 |吞咽有害.
• 防范说明P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
• UN编号NONH for all modes of transport
• 危险品标志Xn
• 安全声明S24/25
• 危险类别码R22
• WGK Germany3

欧盟法规

上下游产品

合成工艺路线路线简述

• 合成目标产物 Propionamide 主要起始原料 Propionyl Chloride
• 79-06-1 = 79-05-0
  反应条件:1.1 Reagents: Hydrogen Catalysts: Nickel Boride (Resin Bound) Solvents: Methanol
  标题:An Excellent Nickel Boride Catalyst For The Selective Hydrogenation Of Olefins
  作者:Choi,Jaesung; Yoon,Nung Min
  参考文献:Synthesis 日期:1996 卷标:(5) 页码:597-599]
  
  = 79-05-0
  反应条件:1.1 Reagents: Sodium Bicarbonate,Hydroxyamine Hydrochloride Catalysts: 2761983-03-1 Solvents: Water; 2 H,313 K
  标题:Mechanochemical Synthesis Of Half-Sandwich Iridium/rhodium Complexes With 8-Hydroxyquinoline Derivatives Ligands
  作者:Jia,Wei-Guo; Li,Xiao-Dong; Zhi,Xue-Ting; Zhong,Rui
  参考文献:Applied Organometallic Chemistry 日期:2022 卷标:36(4)]
  
  79-06-1 = 79-05-0
  反应条件:1.1 Reagents: Hydrogen Catalysts: Phosphine,Tris(4-Ethenylphenyl)-,Polymer With 1,3,5-Tribromobenzene (Post-Treated With Pd Nanoparticles) Solvents: Ethanol; 1 H,1 Atm,Rt
  标题:Palladium/phosphorus-Doped Porous Organic Polymer As Recyclable Chemoselective And Efficient Hydrogenation Catalyst Under Ambient Conditions
  作者:Ding,Zong-Cang; Li,Cun-Yao; Chen,Jun-Jia; Zeng,Jia-Hao; Tang,Hai-Tao; Et Al
  参考文献:Advanced Synthesis & Catalysis 日期:2017 卷标:359(13) 页码:2280-2287]
  
  = 79-05-0
  反应条件:1.1 Reagents: Water Catalysts: [2,6-Bis(Diphenylmethyl)-4-Methylbenzenamine]Dichloro[(1,2,3,4,5,6-η)-1-Methyl-4...; 4 H,Rt
  标题:Water-Soluble Superbulky (η6-P-Cymene) Ruthenium(Ii) Amine: An Active Catalyst In The Oxidative Homocoupling Of Arylboronic Acids And The Hydration Of Organonitriles
  作者:Nirmala,Muthukumaran; Adinarayana,Mannem; Ramesh,Karupnaswamy; Maruthupandi,Mannarsamy; Vaddamanu,Moulali; Et Al
  参考文献:New Journal Of Chemistry 日期:2018 卷标:42(18) 页码:15221-15230]
  
  79-06-1 = 79-05-0
  反应条件:1.1 Reagents: Formic Acid Catalysts: Palladium Diacetate,1,1′-(9,9-Dimethyl-9H-Xanthene-4,5-Diyl)Bis[1,1-Diphenylphosphine] Solvents: Water; 20 H,90 °C
  标题:Facile Pd-Catalyzed Chemoselective Transfer Hydrogenation Of Olefins Using Formic Acid In Water
  作者:Liu,Tianxiang; Zeng,Yongming; Zhang,Hongxi; Wei,Ting; Wu,Xia; Et Al
  参考文献:Tetrahedron Letters 日期:2016 卷标:57(43) 页码:4845-4849]
  
  79-06-1 = 79-05-0
  反应条件:1.1 Reagents: Ammonium Formate Catalysts: Ruthenium(1+),Bis(Acetonitrile)(η5-2,4-Cyclopentadien-1-Yl)[tris(1-Methylethyl)... Solvents: Methanol; 4 H,60 °C
  标题:Transfer Hydrogenation Of Unsaturated Substrates By Half-Sandwich Ruthenium Catalysts Using Ammonium Formate As Reducing Reagent
  作者:Mai,Van Hung; Lee,San-Hwa; Nikonov,Georgii I.
  参考文献:Chemistryselect 日期:2017 卷标:2(25) 页码:7751-7757]
  
  79-06-1 = 79-05-0
  反应条件:1.1 Reagents: Formic Acid Catalysts: Palladium (Supported On Fibrous-Structured Silica Nanospheres) Solvents: Methanol,Water; 12 H,100 °C
  标题:Palladium Nanoparticles Supported On Fibrous-Structured Silica Nanospheres (Kcc-1): An Efficient And Selective Catalyst For The Transfer Hydrogenation Of Alkenes
  作者:Qureshi,Ziyauddin S.; Sarawade,Pradip B.; Albert,Matthias; D'Elia,Valerio; Hedhili,Mohamed N.; Et Al
  参考文献:Chemcatchem 日期:2015 卷标:7(4) 页码:635-642]
  
  = 79-05-0
  反应条件:1.1 Reagents: Aldoxime Catalysts: Cupric Chloride Solvents: Methanol; 4 H,65 °C
  标题:A Heterogeneous Catalytic Method For The Conversion Of Nitriles Into Amides Using Molecular Sieves Modified With Copper(Ii)
  作者:Kiss,Arpad; Hell,Zoltan
  参考文献:Tetrahedron Letters 日期:2011 卷标:52(45) 页码:6021-6023]
  
  79-06-1 = 79-05-0
  反应条件:1.1 Reagents: Hydrogen Catalysts: Palladium,Dichloro[1-[(Dimethylamino)Methyl]-2-[(4-Methylphenyl)Thio]Ferrocene-... Solvents: Acetone
  标题:Application Of Palladium Ferrocenyl Amine Sulfide Complexes In The Hydrogenation Of Carbon-Carbon Double And Triple Bonds
  作者:Ali,Hussein M.; Naiini,Ahmad A.; Brubaker,Carl H. Jr.
  参考文献:Journal Of Molecular Catalysis 日期:1992 卷标:77(2) 页码:125-34]
  
  79-06-1 = 79-05-0
  反应条件:1.1 Reagents: Hydrogen Solvents: Ethanol; 1 H,2 Mpa,100 °C
  标题:Reactivity And Mechanism Investigation Of Selective Hydrogenation Of 2,3,5-Trimethylbenzoquinone On In Situ Generated Metallic Cobalt
  作者:Su,Diefeng; Wei,Zhongzhe; Mao,Shanjun; Wang,Jing; Li,Yi; Et Al
  参考文献:Catalysis Science & Technology 日期:2016 卷标:6(12) 页码:4503-4510]
  
  79-06-1 = 79-05-0
  反应条件:1.1 Reagents: Hydrogen Catalysts: Palladium,Carbon Solvents: Ethanol; 0.5 H,1 Bar,30 °C
  标题:Highly Efficient And Chemoselective Hydrogenation Of α,β-Unsaturated Carbonyls Over Pd/n-Doped Hierarchically Porous Carbon
  作者:Wei,Zhongzhe; Gong,Yutong; Xiong,Tianyi; Zhang,Pengfei; Li,Haoran; Et Al
  参考文献:Catalysis Science & Technology 日期:2015 卷标:5(1) 页码:397-404]
  
  = 79-05-0
  反应条件:1.1 Catalysts: Manganese Oxide (Mno2) Solvents: Water; 15 Min,100 Psi,70 °C
  标题:Mild And Selective Heterogeneous Catalytic Hydration Of Nitriles To Amides By Flowing Through Manganese Dioxide
  作者:Battilocchio,Claudio; Hawkins,Joel M.; Ley,Steven V.
  参考文献:Organic Letters 日期:2014 卷标:16(4) 页码:1060-1063]
  
  79-06-1 = 79-05-0
  反应条件:1.1 Reagents: Hydrogen Solvents: Methanol; 29 Bar,30 °C
  标题:Large Centimeter-Sized Macroporous Ferritin Gels As Versatile Nanoreactors
  作者:Kumari,Sushma; Kulkarni,Amol; Kumaraswamy,Guruswamy; Sen Gupta,Sayam
  参考文献:Chemistry Of Materials 日期:2013 卷标:25(23) 页码:4813-4819]
  
  = 79-05-0
  反应条件:1.1 Catalysts: Ruthenium(1+),Dichloro[(1,2,3,4,5,6-η)-1-Methyl-4-(1-Methylethyl)Benzene][1-[3-... (Supported On Silica-Coated Nanoferrite) Solvents: Water; 2 H,100 - 120 Psi,150 °C
  标题:Chemistry By Nanocatalysis: First Example Of A Solid-Supported Rapta Complex For Organic Reactions In Aqueous Medium
  作者:Garcia-Garrido,Sergio E.; Francos,Javier; Cadierno,Victorio; Basset,Jean-Marie; Polshettiwar,Vivek
  参考文献:Chemsuschem 日期:2011 卷标:4(1) 页码:104-111]
  
  = 79-05-0
  反应条件:1.1 Reagents: Niobium Pentachloride Solvents: Dichloromethane; Rt1.2 Reagents: Ammonia; 0.5 H,Rt; Rt -> 50 °C; 1 H,40 - 50 °C
  标题:Niobium Pentachloride Promoted Conversion Of Carboxylic Acids To Carboxamides: Synthesis Of The 4-Aryl-1,2,3,4-Tetrahydroisoquinoline Alkaloid Structures
  作者:Nery,Marcelo S.; Ribeiro,Renata P.; Lopes,Claudio C.; Lopes,Rosangela S. C.
  参考文献:Synthesis 日期:2003 卷标:(2) 页码:272-276]
  
  = 79-05-0
  反应条件:1.1 Reagents: Potassium Bicarbonate,Hydroxyamine Hydrochloride Catalysts: Cobalt Oxide (Co3O4),Copper Solvents: Acetonitrile,Water; 1 Mpa,Rt; 6 H,140 °C
  标题:Kinetic Analysis Of Consecutive/parallel Transformation Of Furfural To Biomass-Based Primary Amide By Using A "Concentration-Time" Integral
  作者:Yang,Shengwen; Chen,Jinzhu
  参考文献:Acs Catalysis 日期:2023 卷标:13(1) 页码:113-131]
  
  79-06-1 = 79-05-0
  反应条件:1.1 Reagents: Sodium Borohydride Catalysts: Cuprous Chloride Solvents: Ethanol; Rt; 30 H,Rt1.2 Reagents: Hydrochloric Acid Solvents: Water; Ph 5 - 6,Rt
  标题:Selective Reduction Of α,β-Unsaturated Amides With Nabh4-Cucl/etoh
  作者:Li,Jian-Ping; Zhang,Yong-Xia; Su,Ling-Yun; Meng,Ge; Guo,Hai-Ming
  参考文献:Henan Shifan Daxue Xuebao 日期:2012 卷标:40(2) 页码:101-103]
  
  120157-99-5 = 79-05-0
  反应条件:1.1 Reagents: Trifluoroacetic Acid Solvents: Dichloromethane
  标题:A New Method For The Synthesis Of Amides From Amines: Ruthenium Tetroxide Oxidation Of N-Protected Alkylamines
  作者:Tanaka,Kenichi; Yoshifuji,Shigeyuki; Nitta,Yoshihiro
  参考文献:Chemical & Pharmaceutical Bulletin 日期:1988 卷标:36(8) 页码:3125-9]
  
  = 79-05-0
  反应条件:1.1 Catalysts: Tricyclohexylphosphine,Bis[(1,2,5,6-η)-1,5-Cyclooctadiene]Di-μ-Methoxydirhodium Solvents: Toluene,Tetrahydrofuran; 15 Min,25 °C1.2 Solvents: Isopropanol,Water; 24 H,25 °C
  标题:Rhi-Catalyzed Hydration Of Organonitriles Under Ambient Conditions
  作者:Goto,Akihiro; Endo,Kohei; Saito,Susumu
  参考文献:Angewandte Chemie 日期:2008 卷标:47(19) 页码:3607-3609

海关参考信息

• 2912110000-甲醛
  2912120000-乙醛
  2901100000-饱和无环烃
• 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
• 详情请参考：📖 海关编码查询和海关进出口税则

专利信息

其他信息查阅

• ➥ 象形图和危险代码
• ➥ 防范代码详解
• ➥ 危险代码说明
• ➥ Globally Harmonized System
• ➥ REACH监管