CAS: 80806-68-4; 1H,1H,2H,2H,3H,3H-Tridecafluoro-1-Nonanol

相似化合物

27854-30-4 1651-41-8 647-42-7

上下游产品

4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl acetate 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluoro-9-iodononane 2-Iodo-4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl acetate n-perfluorohexyl iodide 4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl acetate 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluoro-9-iodononane 4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononanoic acid toluene-4-sulfonic acid 4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-nonyl ester

4,4,5,5,6,6,7,7,8,8,9,9,9-十三氟壬基乙酸酯置于氢氧化钾体系中,用 乙醇,水 作为反应溶剂,化学反应 3.0H,以92.6%的收率获得产物3-(全氟正己基)丙醇
参考文献:Effect Of A Perfluoroalkyl Group On The Elimination And Substitution Reactions Of Two Homologous Series Of Perfluoroalkyl-Substituted Iodoalkanes
标题:Effect Of A Perfluoroalkyl Group On The Elimination And Substitution Reactions Of Two Homologous Series Of Perfluoroalkyl-Substituted Iodoalkanes
摘要:
DOI:10.1021/jo00187A012

专利信息

专利号:US-6909010-B2
优先权日:2001-04-11
标题:Facile synthesis of symmetric esters of alkylenebisphosphonic acids
发明人：HERLINGER ALBERT W; STEPINSKI DOMINIQUE C
权利人:UNIV LOYOLA CHICAGO
摘要:A facile synthesis of symmetric esters of C 1 -C 10 alkylenebisphopsphonic acids is disclosed in which a C 1 -C 10 alkylenebis(phosphonic dichloride) is reacted with an alcohol in the presence of a catalytic amount of 1H-tetrazole and a base in an aprotic solvent to form a first reaction mixture. The first reaction mixture is maintained for a time period sufficient to form a C 1 -C 10 alkylenebis(chloro ester phosphonate) that is reacted under basic conditions with an excess of a hydroxylated compound to form a second reaction mixture that is itself maintained for a time period sufficient to form a C 1 -C 10 alkylenebis(ester phosphonate) partial ester, homoleptic tetraester or mixed tetraester. The material so formed can be recovered or used as is.

专利号:US-2003060648-A1
优先权日:2001-04-11
标题 :Facile synthesis of symmetric esters of alkylenebisphosphonic acids

专利号:US-7858772-B2
优先权日:2006-12-22
标 题 :Compounds and methods for synthesis and purification of oligonucleotides
发明人：GUPTA AMAR; WILL STEPHEN
权利人:ROCHE MOLECULAR SYSTEMS INC
摘要:The present invention provides methods of extending nucleic acids and purifying target nucleic acids. The methods include the use of capping reagents to effect chain termination and provide a handle for purification via fluorous affinity methods.

专利号:US-2005234257-A1
优先权日:2001-04-11
标 题 :Facile synthesis of symmetric esters of alkylenebisphosphonic acids

专利号:WO-02085918-A1
优先权日:2001-04-11
标 题:A facile synthesis of symmetric esters of alkylenebisphosphonic acids

专利号:ES-2399363-T3
优先权日:2006-12-22
标 题 :Compounds and methods for the synthesis and purification of oligonucleotides